Wednesday, March 2, 2016

Caterina Sforza

Caterina Sforza, by Lorenzo di Credi
(now in the Museum of Forlì.)
Antonio Neri is remembered mostly for his book on glassmaking, L'Arte Vetraria. However, he considered himself first and foremost an alchemist. This interest can be traced to at least two generations before him; his father, Neri Neri, was an acclaimed physician – in fact, the personal physician to Grand Duke of Tuscany, Ferdinando I de’ Medici. Antonio's grandfather, Jacopo Neri, was a barber-surgeon. Both of these professions required an extensive knowledge of herbal distillation and other techniques which are shared by alchemists.

Antonio's benefactor, Don Antonio de' Medici, also followed a family passion for the chemical arts, in his case, traceable through an unbroken chain, to a female alchemist, his great-great-grandmother, Caterina Sforza, (c.1463–1509). After her death, over four hundred of her formulas were passed down to her son, Giovanni dalle Bande Nere, then to his son Grand Duke Cosimo I de' Medici, Grand Duke Francesco I, and finally to Don Antonio. 

Caterina was the illegitimate daughter of the Duke of Milan, Galeazzo Maria Sforza, but was still educated at court. At age fifteen, she was married to a nephew of Pope Sixtus. The pope granted her title of Countess of Forlì and Imola. After her territory was later taken and her husband murdered (by a faction of their own people), she escaped prison and retook the two cities. In 1495, when her second husband was assassinated, she launched a campaign which gutted the families of the murderers. Her third husband was Giovanni de' Medici, and their son, named after his father would become a brilliant military strategist, like his mother. His own son, Cosimo, would later become the first "Grand Duke" of Tuscany. 

Her chemical recipes were transcribed in 1525 by a captain in her son's army, Count Lucantonio Cuppano da Montefalco, and ultimately published as a book in 1893 (Passolini). Included are an assortment of formulas which range from cosmetics, to medical remedies, poisons and alchemical concoctions.
Researcher Jacqueline Spicer writes:
Lost among the romanticized military conquests is a thorough account [of] the project that occupied several years of her life—the manuscript of her alchemical and medical experiments and recipes titled Gli Experimenti de la Ex.ma S.r Caterina da Furlj Matre de lo inllux.mo S.r Giouanni de Medici, or Gli Experimenti. The text is an early example of what would later become the popular medical genre of "Books of Secrets", but is so early that it does not appear in most modern writing on such books. Furthermore, Gli Experimenti is unusual because it was written by a woman in an otherwise male dominated genre, and unique in that we know a great deal about the life of its author.[1]

Among the alchemical entries are "to convert pewter into silver of the finest quality and of standard alloy," a method "for giving to bars of brass a fine golden color" and another for "for multiplying silver." Also, there are ways described  to "make iron hard," "to dissolve pearls" and "to dissolve all metals." In the medicinal category, we find "for infirm lungs, an ointment is to be made of the blood of a hen, a duck, a pig, a goose, mixed with fresh butter and white wax." This was to be applied to the chest with a fox's skin.
Sandro Botticelli, Primavera (1498)
(detail - rightmost of the three graces)

Caterina Sforza was painted many times and often depicted as the Virgin Mary, a typical trope for the nobility at the time. She may have been immortalized  by Sandro Botticelli as the rightmost of the three graces in his Primavera and as the main subject in The Birth of Venus.[2] Reportedly, she was the subject of ballads and sonnets, although most have been lost. She is a topic of discussion in Niccolò Machiavelli's famous treatise The Prince. 

In the end she was captured, raped and imprisoned on the orders of Pope Alexander VI, who justified her incarceration, in the Vatican's  Sant'Angelo Castle, by claiming she tried to poison him. She survived the ordeal, but after release entered the convent of the Murate nuns in Florence, and died, in 1509, at the age of forty-seven. She was buried at the convent, in the same city where her future great-great-grandson, Don Antonio, along with Antonio Neri, would perform their own alchemical experiments and help usher in the age of  modern science.

[1]https://sites.eca.ed.ac.uk/renaissancecosmetics/cosmetics-recipes/caterina-sforzas-experimenti/ also see  http://edinburgh.academia.edu/JacquelineSpicer.
[2] Another possibility for the model of Venus was Simonetta Vespucci.
*This post first appeared here on 27 January 2014.

Monday, February 29, 2016

Antonio Neri's Birthday

Relief portrait of Antonio Neri,
artist unknown, La Specola Museum,
Florence.
Glassmaker Antonio Neri was born in Florence, Italy on 29 February 1576. Because he was a "leap year baby" we celebrate the actual day of his birth only every fourth year. From his baptismal record, we actually know the exact time of birth: "three hours and 25 minutes past sunset." In terms of current timekeeping conventions, sunset occurred on that particular Thursday at about 6:15 pm CET (local time), so the big event happened at 9:40 pm.

It might seem a bit odd to have such accurate records -- almost as if an astronomical event were being recorded. Actually, that is exactly what was being done; astrology of the sixteenth century drew a strong correspondence between 'macroscopic' events in the heavens and more earthly matters. To have an exact time of birth was seen as a way to gain greater insights into the events of ones personal life and to plan in a way that was more in harmony with the natural order of things.

Of all the days to be born, 29 February was considered among the least auspicious. A dire Northern Italian folk proverb states "An bisesti, o la mama o 'l bambi" predicting that, born on this day, a child or its mother was fated to die by year's end. Indeed, the Italian word naming the day, bisestile, had become a synonym for misfortune or calamity and is still the case for the French cognate bissêtre. Whatever stock the family put into ancient superstitions, happily this prophecy did not come true for Dianora or her fourth child Antonio.

Although his was a February birth, it was perhaps not as deep into winter as one might assume. Due to a discrepancy in the Julian calendar, which was in force then, the Spring equinox of Neri's birth year happened much earlier in the calendar than today, around 10 March, in fact. 

Infant mortality was not uncommon and for a child to die unbaptized only magnified a family's trauma. Church theologians had debated since the fourth century on the fate of the souls of such children. Most Catholic families baptized infants as soon as humanly possible, in Antonio's case the very next morning. Births occurring within Florence were officially registered at a central baptistery, San Giovanni, the ancient octagonal basilica standing directly in front of Florence's main Cathedral. 

The full baptistery record, in translation, for Antonio Neri reads:
Thursday, 1 March 1575:  Antonio Lodovico was born to Mr. Neri di Jacopo and Dianora di Francesco Parenti, residents of San Pier Maggiore parish. The time of birth was 29 February, at 3 hours 25 minutes past sunset. The godparents are Francesco di Girolamo Lenzoni and Ginevra di Federigo Sassetti.
The year is recorded as 1575 because in those days, Florentines celebrated the New Year on 25 March. Today we consider January, February and March to be part of the new year. 

Antonio joined a growing family that already contained siblings Lessandra, Jacopo and Francesco, and later would number ten children.  His father was thirty-six year-old Neri di Jacopo Neri, (Neri Neri to his friends) and his mother was twenty-one year-old Dianora Parenti. Neri Neri was a prominent doctor and later was appointed to be the personal physician to Grand Duke Ferdinando. Dianora was the daughter of Francesco Parenti, Michelangelo's lawyer. 

Tradition dictated that births were celebrated with a house party open to friends and neighbors. Thirty-four year-old Francesco Lenzoni, Antonio's godfather, would certainly have done his best to attend. His family included Florentine senators and Francesco himself would later become Tuscan ambassador to Spain. Godmother Ginevra Sassetti, in her late fifties, was also from a prominent family. Her nephew Filippo would send plant specimens back from India to be inspected by Neri Neri and their mutual friend Baccio Valori who would become director of the Laurentian Library in Florence.

Antonio Neri, would go on to learn the finer points of alchemy and glassmaking, developing new formulas and techniques that would be applied throughout Europe. In 1612, he published the world's first book entirely devoted to formulating glass, L'Arte Vetraria. It seems especially appropriate that we pause and raise a toast (in glass, of course) to his accomplishment and to the end of February, looking forward to warmer days ahead.

Friday, February 26, 2016

Friar Mauritio

Friar Mauritio,
Treasure of the world, f.19v (detail)
Antonio Neri, (1598-1600).
Shortly after ordination as a priest in the Catholic Church, Antonio Neri wrote a manuscript devoted to alchemy, which he called Treasure of the World (1598-1600). It was completed a couple of years before we find any reference to his glassmaking activities. Among the recipes, is one for the philosopher's stone, entitled "Fifth way to make the stone which is very secret." Neri explains that "Friar Mauritio" was a Dominican brother, held prisoner in "The Castle of Naples" by Gilbert Montpensier. There he learned the secret of transmuting mercury into gold. Ultimately, he was freed from his French captors and went on to use his secret to create great wealth. The recipe was passed down through his family, and ultimately fell into Neri's hands. He presents the full recipe, which takes many pages in the manuscript detailing complex alchemical manipulations.

Some background is in order here. In the year 1494, French King Charles VIII amassed a very large army (twenty-five thousand men), and with encouragement  from the duke of Milan, marched straight down the Italian peninsula with the intention of annexing the Spanish controlled Kingdom of Naples, which encompassed the entire lower portion of Italy. But by the time Charles marched into the capital city, his victory was already threatened; a "League" was forming to oppose him among the states of northern Italy. Charles set up an occupation government, quickly appointed Gilbert Montpensier as viceroy and judiciously headed back toward France, but not before having to fight through the League forces blocking his way. The city of Naples would be held by the French for only three months; the occupation government barely in control. Truth be told, it was not only Friar Mauritio who was confined, but the entire French contingent was more or less sequestered to several fortresses in the area, as they were greatly resented and resisted by the Neapolitan people. Soon the Spanish military was on the scene and systematically routed French forces, reclaiming all of the lost territory.

The most likely location of Mauritio's imprisonment was the foreboding Castel Nuovo, but there are other possibilities, among them Castel Sant'Elmo and Castel dell' Ovo. In the same years that Neri was writing about the Dominican Friar Mauritio's imprisonment, Dominican friar Tommaso Campanella was held and tortured in Naples, under suspicion of heresy and conspiracy against the Spanish rule of his native Calabria. His "heretical" views on astrology and departure from sanctioned Aristotelian doctrine earned him a cell at Castel Sant'Elmo. 


The ancient Castle dell' Ovo or "castle of the egg," is located along the bay of Naples. The name derives from a story about the Roman poet Virgil, who at one time was thought to be a great sorcerer. Supposedly, he had fortified the foundations of the castle with a magic "egg," which he concealed there. Legend warns that if the egg ever were to be disturbed or broken, the entire Castle would self-destruct, and a series of great calamities would befall the city.

The endeavor of history rightly demands strong attention to demonstrable facts. Unfortunately, folklore is often a casualty of that process, because, by its very nature it has little to contribute that can be vigorously verified. The identity of Neri’s Friar Mauritio and, for that matter, the existence of Virgil's egg in the foundations of a Naples castle, in all likelihood, will never be confirmed. But these stories have qualities that solid evidence often does not capture. Regardless of its factual content, folklore tells us about the hopes and fears of the people who repeat it; it is a taste of their culture. Folklore also emphasizes that the way we see history is very different from the way contemporaries saw it. We have no choice but to view events of the past through a lens of the present, just as Neri viewed it through the lens of his time. His view of the events was very much colored by legends about characters like Virgil and Friar Mauritio, but also by the promise of transmutation, and fear of the Inquisition.

* This post first appeared here on 12 March 2014.

Wednesday, February 24, 2016

Glass or Rock?

Rock crystal ewer, Egypt (1000-1050)
V&A Museum, #7904-1862
Today, a sharp distinction is made between glass and rock, but in the early seventeenth century, differences in the two materials were not so well defined. One was the product of nature and the other of art, but after that the lines begin to blur. Philosophers debated weather glass should be classified as artificial stone, and why not? It is a material that was actually made from crushed up rocks (quartz and calcined limestone) with the addition of plant salts. In a very accurate sense, it is a form of artificial rock. 

In his 1612 book L'Arte Vetraria, Florentine glassmaker Antonio Neri repeatedly illustrates the thinking that glass was an artificial form of rock. The very first part of the book concerns itself with cristallo glass, which was considered to be an imitation of natural rock crystal. He devotes a whole section to the imitation of the colorful stones variously known as chalcedony, jasper and oriental agate. About these he writes: 
It is often said, and it may well seem to be true, that art cannot match nature. However, experience in many things shows, and this is particularly true of colors in glass, that art not only challenges and matches nature, but by far exceeds and surpasses it. Why, if you did not see it for yourself, you would find it hard to believe the beauty and great variety of interplay seen in these particular chalcedonies.
Another entire section of the book is devoted to artificial gemstones: rubies, sapphires, emeralds, topaz, chrysolite; he even uses crushed natural gems to color his glass. He describes a "sky blue even more beautiful, from the garnets of Bohemia." 

An earlier 1540 book that Neri read closely was by Italian metallurgist Vannoccio Biringuccio, called De La Pirotechnia. This was the first book entirely devoted to mining and metal foundry practices. Biringuccio was from Siena, but was considered something of a folk hero in Neri’s nearby Florence because he oversaw the casting of iron cannons for the city's defense in the great siege of 1529–30. His book contains a short six-page chapter devoted to glass where he writes:
[I]t [glass] is one of the effects and real fruits of the art of fire, because every product found in the interior of the earth is either stone, metal or one of the semi-minerals. Glass is seen to resemble all of them, although in all respects it depends on art.
This is an observation that Neri echoes almost verbatim in the introduction of his own book, and in this light, it is not so difficult to see what connects glassmaking to alchemy. Neri was in the business of learning nature's secrets, and then using them to create new materials that were even better than the originals. These are aims quite familiar to any modern materials engineer. Neri and his contemporaries were successful up to a point. They were able to create artificial gems and other items that were impressive in color and clarity, yet they lacked some key properties of their natural counterparts, most notably hardness. 

Based on Neri's earliest known writing Treasure of the World, started in 1598, he was already familiar with mining practices before his glassmaking activities started and over a decade before he would write the book. He devotes this early manuscript to "all of alchemy, its furnaces, instruments and the mining of metals." Around 1600 he started work at Prince Don Antonio de' Medici's Casino di San Marco laboratory. Here, he may have had the opportunity to interact with characters such as Filippo Talducci (1543- c.1615), celebrated Florentine chemist and mining engineer, several of whose relatives worked at the Casino. In his 1613 manuscript Discorso, Neri strongly hints that he has personally been to more than one mine in connection with his alchemical activities. "I would not say this, had I myself not had the good fortune of being in such a mine from which, with much artifice, was extracted a small quantity of real gold liquor, which was the true golden seed. […] To this day I have never found another mine like it, and therefore suitable for this purpose."

Today, we hardly associate glass with the raw materials from which it is composed, just as we hardly ever think of metals in their unrefined state. Antonio Neri was more closely connected to the earth, by virtue of his profession, but also because daily life in the early seventeenth century was filled with such activity; refining raw materials into useful forms had a direct and immediate impact on quality of life. Although glass is now manufactured in highly automated facilities, far away from our daily lives, it is still essentially the same product that Neri made. The next time you come in contact with a piece of glass, to pour a drink or look through a window or read the text on a screen as you are probably doing right now, stop for a minute and think of it as Neri did four centuries ago, as artificial rock.

* This post first appeared here 17 Feb 2014.

Monday, February 22, 2016

Reticello

Reticello by Aaron Tate (detail),
Photo by David Lindes.
In fine art of the early twentieth century, ‘cubist’ painters and sculptors caused a sensation by pioneering a style that was fluid and emotional yet rigorously geometric. Earlier still, eighteenth century Baroque musicians thrilled audiences with ‘counterpoint’; music that was melodic and harmonious yet structured with an almost mathematical precision. The recurrence of similar themes in widely differing arts is perhaps not so surprising. When successful, these are themes that resonate deeply within us; they amplify what is common to our nature and remind us that we are in the world together. 

In sixteenth century Venice, a form of glasswork emerged that anticipated these juxtapositions to similar popular acclaim. In fact, the technique of ‘reticello’ went on to become an enduring trademark of Murano technical skill and artistry. To this day, well executed pieces of reticello glass are coveted by collectors and displayed with great pride. 

The form is characterized by a transparent glass base which is embedded with a network of crisscrossing threads of opaque glass, forming a lattice of diamond shaped pockets. Classically, white 'latimo' glass was used in a clear 'cristallo' base.The overall effect is reminiscent of fine lace or of fishing net, both of which are strongly evocative in Venetian culture. When executed in the classical technique of the island’s glassblowers, each diamond in the pattern contains a single bubble of trapped air, perfectly centered and uniformly sized. 

In general, the latticework theme in art traces to much earlier times. It is common in Hellenistic and Islamic art. To an extent it is a natural consequence of mosaic making. However the application of the pattern in glassblowing requires a completely different approach and a complex series of steps. First a ‘filigrana’ bubble is formed. To accomplish this, a series of pencil thin glass rods called ‘canes’ are laid side by side, touching each-other, in a pan ('piera' in Venetian, 'pietra'=stone in Italian) and partially fused together in the furnace.[1] Each cane is made of transparent glass with a core of opaque glass (a thread) running its entire length. Glass artist Emilio Santini writes:
On Murano, the "piera" is coated with a thin layer of clay from the laguna marshes. This is rich in salt and does not stick too much on the glass even if overheated. Then they preheat the, piera (called a 'plate' in the US) to dry the clay. While it is still hot but not scorching they lay down the canes so they are partially warmed before they go in the furnace. Remember that they are not annealed [and could easily shatter from thermal shock]. Then two little square metal pieces are placed at the two ends to hold the cane in place. These are called fereti (V) ferretti (I) . Some of these same terms are also used in the US by skillful glass blowers.[2]

On the end of an iron blowpipe, the fused mat of glass rods is wrapped around into a hollow cylinder. Next the open end is gently worked closed. This forms a sealed bubble of glass that can be manipulated by standard glassblowing techniques. Soft from the heat of the furnace, the glass can be given a twist so the parallel threads form a loose spiral. This piece is stored in a ‘garage’ kiln while a second bubble is formed in the same way but with the spiral running in the opposite direction. The first bubble is opened wide at one end, removed from its iron rod and placed in a cradle on the floor which holds it upright. The second bubble is carefully lowered into the open end of the first bubble. The glass artist stands above, with the second bubble inside the first and blows, inflating the inner glass until it comes in contact with the outer bubble.

Because both glass bubbles are formed with canes, they have a ribbed texture both inside and outside. When the two glass bubbles contact each other, the high-points of the ribs meet first, which is where the threads of the two bubbles cross. The valleys of the ribs are where one cane is fused to the next; these areas cross between the bubbles at the center of each diamond in the pattern. The two bubbles fuse together trapping air in the valleys. As the glass is worked and heated these regions form small, perfectly round air bubbles trapped inside the glass. You can see this for yourself by taking two or three fingers of each hand and crossing them against each other. Imagine the threads of opaque glass running down the center of each finger. The air bubbles are trapped where you can see light between your fingers.
Reticello ("fillacello") style flamework pendant,
by Adam Reetz 2015.

The distinctive diamond pattern of reticello has been successfully achieved with other glassmaking techniques. In flameworking, glass is manipulated using only a torch and handtools. The torch is fixed to a bench where the artist either stands or sits. In general, this is a more accessible technique because it does not require a glass furnace. Here, the reticello pattern is accomplished by starting with glass tubing. The crisscross pattern is ‘painted’ onto the outside of the tubing, one line at a time; with very thin rods of glass known as “stringers.” In one version, evenly spaced straight parallel lines are drawn along the length of the tube. The tube is then reheated in the flame and twisted. Next, a second set of lines are drawn twisting in the other direction, forming the diamonds. The ends of the tube are drawn down and one end can be mounted to a rod or tube of glass and further manipulated in the flame. 

In a testament to the continued popularity of reticello, a new colorful variation of the flamework technique has emerged within the past decade, among American flameworkers. [3] This has been playfully dubbed “fillacello.” After painting the fishnet pattern on tubing, and further working the glass, the individual diamonds are “filled” with various colors using stringers. The resulting effect recalls mosaics and the ancient inspirations of reticello.

[1] The iron tool used to move the 'piera' of filigrana cane in and out of the furnace is called a 'pasorale' (V), 'pastorale' (I) = pastoral, named after the staff carried by the pope. It consists of a straight rod with a U-shaped fork in the end. Thanks to Emilio Santini for his kind assistance with Muranese terminology and knowledge of hotshop technique.
[2] Private correspondence, March 2015. Here is a video of the reticello technique as executed by American glass artist Dante Maroni. http://www.youtube.com/watch?v=WJ3DDon23Lc
[3] My research point to the first examples of this technique emerging on the west coat of the United States around 2005-07. (Further information on its origin would be greatly appreciated).



Friday, February 19, 2016

Filigrana

Mezza Filigrana footed vase, circa 1950s,
by Dino Martens (for Aureliano Toso).
Filigrana is a classical glassmaking technique developed in the sixteenth century on the Venetian island of Murano. In the broadest sense, a piece of filigrana -- let's say a vessel -- is composed of transparent glass with very fine vertical threads of color running through it. Traditionally, these threads were opaque white lattimo (milk) glass, running through a colorless high quality product known as cristallo. Because of this, the technique was originally known as “latticino,” a term still in use, but now falling out of favor and being replaced by filigrana (filigree), a name that does not imply any particular color. 

Over the centuries, this and closely related techniques became a kind of trademark for the Murano glass industry. Parallel threads in a loose spiral winding around a vessel from top to bottom form what is perhaps the most basic application of the method. This is known as mezza filigrana (half filigree). The reason for the “half” becomes apparent when we consider its far more famous cousin reticello. With this technique, two sets of threads are used winding in opposite directions to form a fishnet pattern of  diamonds. The name recalls reticella, a traditional Venetian lace. When the work is done properly, tiny air bubbles are trapped inside the glass, one in the center of each diamond of the fishnet pattern.

Even more exotic variations have been developed, which we will discuss another time. First, let's explore how the glass artisan is able to achieve these fine threads in the glass, so perfectly spaced. I should hasten to say that I am not a glassblower and this description is not an instructional, but simply a window into some of the fabulous artistry that takes place in a glass shop. These techniques take hundreds or thousands of hours of practice to master. Even a shallow understanding of the steps that go into a piece of filigrana lead to a far richer appreciation than simply being able to identify it by name.

 “Cane” is a general term for long straight rods of glass. They have many uses in glass artistry and the method by which they are made can be surprising the first time you see it done. It is the same method as was practiced a thousand years ago. A gob of molten glass is removed from the furnace on the end of an iron rod. A second rod is attached by another artisan, with the lump of molten glass between the two rods. They start to pull in opposite directions, slowly at first. They swing and manipulate the hot glass as it cools, forming a mass of relatively uniform diameter. They continue to walk away from each other, the glass pulling thinner as they go. Practiced artisans can end up with a uniform pencil thin straight rod of glass that extends for many meters. It is laid on spaced wooden slats on the floor, allowed to cool and then snapped at regular intervals to form smaller rods.

In the case of filigrana cane, the artisan starts with a smaller gob of opaque glass; let us say lattimo (white). This gob is then dipped into clear glass, which encases it in a heavy transparent layer. When the cane is pulled, the result is a clear rod with a filament of opaque white glass running down the center. Short lengths of cane are laid side by side in a pan. The pan is heated so that adjacent rods start to fuse together into a mat. The glass artist will again take a gather of glass from the furnace around the end of an iron blowpipe and flatten it into a disk, leaving the blowhole unobstructed. The disk, known as a "collar"[2] is touched to the mat of canes at one end and rolled so that the canes wrap around and form a cylinder. The open end of the cylinder is then closed down, in effect forming a bubble on the end of the pipe. The glassblower can then treat this as if it were a bubble formed straight out of the furnace, but of course, this bubble has the threads of lattimo glass running through it. The bubble is then manipulated into a finished piece. [2]


Miniature flameworked vessels (aprox. 3cm tall)
in the style of filigrana, by Emilio Santini. 
Outside of the hot shop, there are methods that use only a torch to duplicate the appearance of filigrana and reticello on a smaller scale. This involves starting with glass tubing and "painting" the threads on using thin "stringers" of glass. It is a completely different technique which requires an entirely different set of skills. In the right hands, the results can be strikingly similar. Now that we have the basics down, we can discuss the more spectacular variations that have been developed, which we will talk about next time.


[1] "Colletto"(Italian) "Coeto" (Venetian), means narrow neck or little neck.


[2] The following Youtube video shows American glass artist William Gudenrath, assisted by Harry Siemens pulling filigrana cane and executing a reticello vase at the Corning Museum of Glass. http://www.youtube.com/watch?v=xCrdewFgObc

Wednesday, February 17, 2016

Gold Ruby Glass

A gold florin.
Legend claims gold ruby glass
 was discovered when a nobel threw
a gold coin into a glass maker's crucible.
Antonio Neri is best remembered for writing L'Arte Vetraria. It was the first printed book entirely devoted to the formulation of glass, which he published in Florence, Italy, in 1612. If we were to single out just one of his more than a hundred recipes, covering glass, lead crystal, paste gems and enamels, it would have to be his prescription for "Transparent Red" ruby glass made with gold. This recipe still captivates glass artists today, as it has since Neri wrote the book. In fact, gold ruby glass is closely tied to the lore of alchemy and has intrigued experimenters as well as artists and collectors since the Roman Empire, possibly before.

Alchemists had long thought gold to be the perfect metal and that all other "lesser" metals (read: lead, tin, copper, iron, mercury and silver) could be coaxed to fully "mature" into gold. Experimenters thought that if they could capture the "essence" of the king of metals, it could be used to "seed" the other metals, and transmute them into pure gold. This is where ruby glass comes into the discussion. In general, glass is colored by the addition of finely powdered metals. Depending on the metal and how it is treated, a whole rainbow of colors can be produced in glass. Alchemists were convinced that the color was an indication that this "essence" of the metal had been released into the glass. 
Cranberry glass or Gold Ruby
 treasury chamber of the Wittelsbacher , Munich Residenz.

For artists and collectors, gold ruby is simply a very attractive color; the difficulty of producing it and working with it only adds to its cachet. Transparent red in glass can be produced other ways, notably with copper, but copper red has a slightly more orange color. Gold ruby, on the other hand, has a characteristic red color that can have slight hints of purple. It can be made light and ethereal or dark and heavily saturated, but viewed next to its competitors, it has a very distinctive hue that experts pride themselves on recognizing.

Neri’s recipe involves moistening gold powder with "aqua regia," which we know as a mixture of nitric and hydrochloric acids. He then spreads this wet mixture on an earthenware pan and heats it in the furnace "until it becomes a red powder, which will take place after many days." Here is that color change that alchemists looked for as an indication of transformation; we know today that Neri was producing gold chloride. This is one of the very few chemical compounds that gold forms and in fact, this is one of the main things that makes gold so special: it does not rust, nor corrode or tarnish, which are, in the end, all chemical reactions between the metal and its environment.

Neri directs his readers to sprinkle, little by little, the gold chloride into the glass melt. He says to "Use fine cristallo, thrown in water many times." Cristallo is the exceptionally clear glass invented by Venetian craftsmen, and "washing" was a technique to remove excess water soluble flux and other contaminants. He finishes his instructions abruptly by saying this method "will make the transparent ruby red glass; but you must experiment in order to find it." In other recipes, Neri goes to great lengths to explain his methods in detail, here he seems content to barely scratch the surface. Much speculation has taken place over the reason for this surprisingly short recipe. Was he ordered, perhaps by his Medici overlords, to keep details to a minimum? Some have wondered if Neri even knew how to produce gold ruby; the short recipe may have been a cover for his lack of knowledge.

Doubts about Neri's gold ruby glass recipe grew after his death, when it was discovered by other experimenters that the addition of small amounts of tin into the mix produced the ruby color quickly and reliably. This compound of tin and gold chloride was called "Cassius purple" after one of its inventors and its color. In some circles it was thought that the tin was an essential ingredient, a lost secret that had been rediscovered. The argument was that gold chloride alone could not produce the color, it must be combined with tin in the form of Cassius purple. However, this is not the case. 

In an 1846 edition of the Journal of the Franklin Institute (ser. 3, v. 11), professor of chemistry and natural philosophy, E. L. Schubarth, cites numerous investigators who demolish this theory. He wrote:
It must not be imagined from this, as some persons have lately stated, that it is necessary to use gold [combined with tin] in the state of Cassius purple.
Neri, at the end of the sixteenth and commencement of the seventeenth century, stated, that in order to stain glass a ruby color, it was only necessary to employ calcined chloride of gold. At a later period, Libar wrote to the same effect, and Merret certified that he had proved the efficacy of the process. In 1834 Golfier Besseyre stated, in the Journal of Pharmacy, that Douault Wieland colored his paste with perchloride of gold only. Lastly, in 1836, Fuss writes, that in Bohemia all the ruby-colored glass was prepared with chloride of gold only, and that glass might be stained red as well with metallic gold, as with oxide of gold or Cassius purple.
It is therefore a fact known for some time, that glass may be stained red, without either Cassius purple or oxide of tin, with [only] metallic gold or preparations of gold. In the glass-works of Bohemia and Silesia perchloride of gold only is used, without the addition of oxide of tin, in order to produce their fine rose or carmine-colored glass.
Of the men cited, Douault-Wieland was a Parisian jeweler who was famous for his artificial gems and crystal glassware. He was praised for his skills by Napoleon. Paul Golfier-Besseyre was a well respected French chemist. Besides many other endeavors, he worked for the glass industry and performed numerous experiments on the formulation of glass. He produced a gold ruby using the same ingredients as Neri. He determined good color could be achieved by letting a new batch of the glass age for a protracted period of time at temperatures below the melting point of gold. Periodically, he removed the glass from the furnace and poured it into water to wash it. The result was a yellowish glass when molten, but when a gaffer finished a piece it was gently reheated and the ruby color developed.