Gold Ruby Glass

 

A gold florin.

Legend claims gold ruby glass

 was discovered when a nobel threw

a gold coin into a glass maker's crucible.

Antonio Neri is best remembered for writing L'Arte Vetraria. It was the first printed book entirely devoted to the formulation of glass, which he published in Florence, Italy, in 1612. If we were to single out just one of his more than a hundred recipes, covering glass, lead crystal, paste gems and enamels, it would have to be his prescription for "Transparent Red" ruby glass made with gold. This recipe still captivates glass artists today, as it has since Neri wrote the book. In fact, gold ruby glass is closely tied to the lore of alchemy and has intrigued experimenters as well as artists and collectors since the Roman Empire, possibly before.

Alchemists had long thought gold to be the perfect metal and that all other "lesser" metals (read: lead, tin, copper, iron, mercury and silver) could be coaxed to fully "mature" into gold. Experimenters thought that if they could capture the "essence" of the king of metals, it could be used to "seed" the other metals, and transmute them into pure gold. This is where ruby glass comes into the discussion. In general, glass is colored by the addition of finely powdered metals. Depending on the metal and how it is treated, a whole rainbow of colors can be produced in glass. Alchemists were convinced that the color was an indication that this "essence" of the metal had been released into the glass. 

Cranberry glass or Gold Ruby
 treasury chamber of the Wittelsbacher , Munich Residenz.

For artists and collectors, gold ruby is simply a very attractive color; the difficulty of producing it and working with it only adds to its cachet. Transparent red in glass can be produced other ways, notably with copper, but copper red has a slightly more orange color. Gold ruby, on the other hand, has a characteristic red color that can have slight hints of purple. It can be made light and ethereal or dark and heavily saturated, but viewed next to its competitors, it has a very distinctive hue that experts pride themselves on recognizing.

Neri’s recipe involves moistening gold powder with "aqua regia," which we know as a mixture of nitric and hydrochloric acids. He then spreads this wet mixture on an earthenware pan and heats it in the furnace "until it becomes a red powder, which will take place after many days." Here is that color change that alchemists looked for as an indication of transformation; we know today that Neri was producing gold chloride. This is one of the very few chemical compounds that gold forms and in fact, this is one of the main things that makes gold so special: it does not rust, nor corrode or tarnish, which are, in the end, all chemical reactions between the metal and its environment.

Neri directs his readers to sprinkle, little by little, the gold chloride into the glass melt. He says to "Use fine cristallo, thrown in water many times." Cristallo is the exceptionally clear glass invented by Venetian craftsmen, and "washing" was a technique to remove excess water soluble flux and other contaminants. He finishes his instructions abruptly by saying this method "will make the transparent ruby red glass; but you must experiment in order to find it." In other recipes, Neri goes to great lengths to explain his methods in detail, here he seems content to barely scratch the surface. Much speculation has taken place over the reason for this surprisingly short recipe. Was he ordered, perhaps by his Medici overlords, to keep details to a minimum? Some have wondered if Neri even knew how to produce gold ruby; the short recipe may have been a cover for his lack of knowledge.

Doubts about Neri's gold ruby glass recipe grew after his death, when it was discovered by other experimenters that the addition of small amounts of tin into the mix produced the ruby color quickly and reliably. This compound of tin and gold chloride was called "Cassius purple" after one of its inventors and its color. In some circles it was thought that the tin was an essential ingredient, a lost secret that had been rediscovered. The argument was that gold chloride alone could not produce the color, it must be combined with tin in the form of Cassius purple. However, this is not the case. 

In an 1846 edition of the Journal of the Franklin Institute (ser. 3, v. 11), professor of chemistry and natural philosophy, E. L. Schubarth, cites numerous investigators who demolish this theory. He wrote:

It must not be imagined from this, as some persons have lately stated, that it is necessary to use gold [combined with tin] in the state of Cassius purple.

Neri, at the end of the sixteenth and commencement of the seventeenth century, stated, that in order to stain glass a ruby color, it was only necessary to employ calcined chloride of gold. At a later period, Libar wrote to the same effect, and Merret certified that he had proved the efficacy of the process. In 1834 Golfier Besseyre stated, in the Journal of Pharmacy, that Douault Wieland colored his paste with perchloride of gold only. Lastly, in 1836, Fuss writes, that in Bohemia all the ruby-colored glass was prepared with chloride of gold only, and that glass might be stained red as well with metallic gold, as with oxide of gold or Cassius purple.

It is therefore a fact known for some time, that glass may be stained red, without either Cassius purple or oxide of tin, with [only] metallic gold or preparations of gold. In the glass-works of Bohemia and Silesia perchloride of gold only is used, without the addition of oxide of tin, in order to produce their fine rose or carmine-colored glass.

Of the men cited, Douault-Wieland was a Parisian jeweler who was famous for his artificial gems and crystal glassware. He was praised for his skills by Napoleon. Paul Golfier-Besseyre was a well respected French chemist. Besides many other endeavors, he worked for the glass industry and performed numerous experiments on the formulation of glass. He produced a gold ruby using the same ingredients as Neri. He determined good color could be achieved by letting a new batch of the glass age for a protracted period of time at temperatures below the melting point of gold. Periodically, he removed the glass from the furnace and poured it into water to wash it. The result was a yellowish glass when molten, but when a gaffer finished a piece it was gently reheated and the ruby color developed. 

Glassmaker Sara Vincx

 

Still life with façon de Venise wineglass,

Alexander Adriaenssen (1587-1661)

Antwerp.

In the 1590s, after the death of her husband, Sara Vincx ran a successful glassmaking business in the city of Antwerp. In the midst of a major war, she presided over a furnace where craftsmen from Murano, Italy, made fine cristallo glassware for the elite families in Flanders. Vinx is the first documented female owner of a glass furnace anywhere.

The Dutch Eighty Years' War for independence from Spain was heating up in Flanders; towns were being pillaged and burned to the ground throughout the Low Countries. Even so, Vincx ably managed a crew of expert glass artists and brought her company's wares to market. When competitors tried to duplicate her products, she successfully defended her shop in court. Later, she remarried to Filippo Gridolfi, one of her foremen at the furnace. The two went on to open a show-room on the Meir, the most prestigious sales district of the city. They also welcomed glassmaker Antonio Neri to work at their facility. Neri was living in the city on an extended seven year visit to his friend and fellow alchemical experimenter Emmanuel Ximenes. 

The seven years that Antonio Neri spent in Antwerp were arguably the most formative for his knowledge of glassmaking. While his first exposure to the art was in Italy, a large portion of the skills and recipes exhibited in his book, L'Arte Vetraria, trace to his activities in the Low Countries. Neri writes "This will make a beautiful aquamarine so nice and marvelous, that you will be astonished, as I have done many times in Flanders in the city of Antwerp to the marvel of all those that saw it." On tinting rock crystal: "In Antwerp, I made quite a bit of this, some ranged in tint from an opal color that looked very beautiful, to a girasol, similarly nice." On equipment: "In Antwerp, I built a furnace that held twenty glass-pots of various colors and when fired for twenty-four hours everything fused and purified." He also speaks of chalcedony glass, paste gems  and ultramarine paint all crafted in Antwerp.

Neri was apparently on good terms with Vincx and Gridolfi, perhaps he was introduced through Ximenes, one of the wealthiest men in the city. In his book Neri describes Gridolfi as "a most courteous gentleman." Vincx and Gridolfi possessed exclusive rights in the region to produce cristallo glass in the Venetian style (façon de Venice) a type of glass that Neri was already quite familiar with from his time making glass in Florence. The license, or patent as it was called, passed down from previous owners, was quite a valuable part of the operation. Employed in their shop was a steady stream of craftsmen from Murano. They made the finest glassware for the upper classes of Antwerp and surrounding areas. Because these craftsmen were bringing the secret techniques with them, they worked outside of the guild system, which would have otherwise required them to share their techniques with other artisans. Through special arrangements with the local authorities, the Venetians were exempt from joining. 


Sara Vincx (or Vincks) was the widow of the former owner, Ambrogio de Mongarda. Gridolfi had previously worked in the shop under Mongarda, who had been in the business for twenty years. Vincx was pressed into service by unhappy circumstances. In 1594, Ambrogio returned alone to Venice to recuperate from gout, but by the following year he was dead, leaving Sara to both run the glass shop and care for at least eight young children. Sara Vincx carries a distinction as the first documented female owner of a glass furnace anywhere. She took an active role in the business as attested by lawsuits she filed, and won, against rival shops that violated her patent. Records show she also expanded the furnace and hired two new artisans to increase production.

Despite the war and the Spanish blockade of the Scheldt River, which shut down trade by sea for a number of years in Antwerp, the glass furnace there thrived and reached its zenith under Vincx and Gridolfi. Soon after their marriage, seventeen employees were counted working at the shop. They established their own retail presence on the Meir, selling high-end cristallo within steps of the Ximenes palace. Their glass operation enjoyed top-rung status, and no doubt, Antonio Neri's involvement must have bolstered the reputation of the firm even further.

*This post first appeared here in a shorter form on 4 October 2013.

Gold Ruby Glass

A gold florin.

Legend claims gold ruby glass

 was discovered when a nobel threw

a gold coin into a glass maker's crucible.

Antonio Neri is best remembered for writing L'Arte Vetraria. It was the first printed book entirely devoted to the formulation of glass, which he published in Florence, Italy, in 1612. If we were to single out just one of his more than a hundred technical recipes, covering glass, lead crystal, paste gems and enamels, it would have to be his prescription for "Transparent Red" ruby glass made with gold. This recipe still captivates glass artists today, as it has since Neri wrote the book. In fact, gold ruby glass is closely tied to the lore of alchemy and has intrigued experimenters as well as artists and collectors since the Roman Empire, possibly before.

Alchemists had long thought gold to be the perfect metal and that all other "lesser" metals (read: lead, tin, copper, iron, mercury and silver) could be coaxed to fully "mature" into gold. Experimenters thought that if they could capture the "essence" of the king of metals, it could be used to "seed" the other metals, and transmute them into pure gold. This is where ruby glass comes into the discussion. In general, glass is colored by the addition of finely powdered metals. Depending on the metal and how it is treated, a whole rainbow of colors can be produced in glass. Alchemists were convinced that the color was an indication that this "essence" of the metal had been released into the glass. 

Cranberry glass or Gold Ruby
 treasury chamber of the Wittelsbacher , Munich Residenz.

For artists and collectors, gold ruby is simply a very attractive color; the difficulty of producing it and working with it only adds to its cachet. Transparent red in glass can be produced other ways, notably with copper, but copper red has a slightly more orange color. Gold ruby, on the other hand, has a characteristic red color that can have slight hints of purple. It can be made light and ethereal or dark and heavily saturated, but viewed next to its competitors, it has a very distinctive hue that experts pride themselves on recognizing.

Neri’s recipe involves moistening gold powder with "aqua regia," which we know as a mixture of nitric and hydrochloric acids. He then spreads this wet mixture on an earthenware pan and heats it in the furnace "until it becomes a red powder, which will take place after many days." Here is that color change that alchemists looked for as an indication of transformation; we know today that Neri was producing gold chloride. This is one of the very few chemical compounds that gold forms and in fact, this is one of the main things that makes gold so special: it does not rust, nor corrode or tarnish, which are, in the end, all chemical reactions between the metal and its environment.

Neri directs his readers to sprinkle, little by little, the gold chloride into the glass melt. He says to "Use fine cristallo, thrown in water many times." Cristallo is the exceptionally clear glass invented by Venetian craftsmen, and "washing" was a technique to remove excess water soluble flux and other contaminants. He finishes his instructions abruptly by saying this method "will make the transparent ruby red glass; but you must experiment in order to find it." In other recipes, Neri goes to great lengths to explain his methods in detail, here he seems content to barely scratch the surface. Much speculation has taken place over the reason for this surprisingly short recipe. Was he ordered, perhaps by his Medici overlords, to keep details to a minimum? Some have wondered if Neri even knew how to produce gold ruby; the short recipe may have been a cover for his lack of knowledge.

Doubts about Neri's gold ruby glass recipe grew after his death, when it was discovered by other experimenters that the addition of small amounts of tin into the mix produced the ruby color quickly and reliably. This compound of tin and gold chloride was called "Cassius purple" after one of its inventors and its color. In some circles it was thought that the tin was an essential ingredient, a lost secret that had been rediscovered. The argument was that gold chloride alone could not produce the color, it must be combined with tin in the form of Cassius purple. However, this is not the case. 

In an 1846 edition of the Journal of the Franklin Institute (ser. 3, v. 11), professor of chemistry and natural philosophy, E. L. Schubarth, cites numerous investigators who demolish this theory. He wrote:

It must not be imagined from this, as some persons have lately stated, that it is necessary to use gold [combined with tin] in the state of Cassius purple.

Neri, at the end of the sixteenth and commencement of the seventeenth century, stated, that in order to stain glass a ruby color, it was only necessary to employ calcined chloride of gold. At a later period, Libar wrote to the same effect, and Merret certified that he had proved the efficacy of the process. In 1834 Golfier Besseyre stated, in the Journal of Pharmacy, that Douault Wieland colored his paste with perchloride of gold only. Lastly, in 1836, Fuss writes, that in Bohemia all the ruby-colored glass was prepared with chloride of gold only, and that glass might be stained red as well with metallic gold, as with oxide of gold or Cassius purple.

It is therefore a fact known for some time, that glass may be stained red, without either Cassius purple or oxide of tin, with [only] metallic gold or preparations of gold. In the glass-works of Bohemia and Silesia perchloride of gold only is used, without the addition of oxide of tin, in order to produce their fine rose or carmine-colored glass.

Of the men cited, Douault-Wieland was a Parisian jeweler who was famous for his artificial gems and crystal glassware. He was praised for his skills by Napoleon. Paul Golfier-Besseyre was a well respected French chemist. Besides many other endeavors, he worked for the glass industry and performed numerous experiments on the formulation of glass. He produced a gold ruby using the same ingredients as Neri. He determined good color could be achieved by letting a new batch of the glass age for a protracted period of time at temperatures below the melting point of gold. Periodically, he removed the glass from the furnace and poured it into water to wash it. The result was a yellowish glass when molten, but when a gaffer finished a piece it was gently reheated and the ruby color developed. 

Filigrana Glass

Mezza Filigrana footed vase, circa 1950s,

by Dino Martens (for Aureliano Toso).

Filigrana is a classical glassmaking technique developed in the sixteenth century on the Venetian island of Murano. In the broadest sense, a piece of filigrana -- let's say a vessel -- is composed of transparent glass with very fine vertical threads of color running through it. Traditionally, these threads were opaque white lattimo (milk) glass, running through a colorless high quality product known as cristallo. Because of this, the technique was originally known as “latticino,” a term still in use, but now falling out of favor and being replaced by filigrana (filigree), a name that does not imply any particular color. 

Over the centuries, this and closely related techniques became a kind of trademark for the Murano glass industry. Parallel threads in a loose spiral winding around a vessel from top to bottom form what is perhaps the most basic application of the method. This is known as mezza filigrana (half filigree). The reason for the “half” becomes apparent when we consider its far more famous cousin reticello. With this technique, two sets of threads are used winding in opposite directions to form a fishnet pattern of  diamonds. The name recalls reticella, a traditional Venetian lace. When the work is done properly, tiny air bubbles are trapped inside the glass, one in the center of each diamond of the fishnet pattern.

Even more exotic variations have been developed, which we will discuss another time. First, let's explore how the glass artisan is able to achieve these fine threads in the glass, so perfectly spaced. I should hasten to say that I am not a glassblower and this description is not an instructional, but simply a window into some of the fabulous artistry that takes place in a glass shop. These techniques take hundreds or thousands of hours of practice to master. Even a shallow understanding of the steps that go into a piece of filigrana lead to a far richer appreciation than simply being able to identify it by name.

 “Cane” is a general term for long straight rods of glass. They have many uses in glass artistry and the method by which they are made can be surprising the first time you see it done. It is the same method as was practiced a thousand years ago. A gob of molten glass is removed from the furnace on the end of an iron rod. A second rod is attached by another artisan, with the lump of molten glass between the two rods. They start to pull in opposite directions, slowly at first. They swing and manipulate the hot glass as it cools, forming a mass of relatively uniform diameter. They continue to walk away from each other, the glass pulling thinner as they go. Practiced artisans can end up with a uniform pencil thin straight rod of glass that extends for many meters. It is laid on spaced wooden slats on the floor, allowed to cool and then snapped at regular intervals to form smaller rods.

In the case of filigrana cane, the artisan starts with a smaller gob of opaque glass; let us say lattimo (white). This gob is then dipped into clear glass, which encases it in a heavy transparent layer. When the cane is pulled, the result is a clear rod with a filament of opaque white glass running down the center. Short lengths of cane are laid side by side in a pan. The pan is heated so that adjacent rods start to fuse together into a mat. The glass artist will again take a gather of glass from the furnace around the end of an iron blowpipe and flatten it into a disk, leaving the blowhole unobstructed. The disk, known as a "collar"[2] is touched to the mat of canes at one end and rolled so that the canes wrap around and form a cylinder. The open end of the cylinder is then closed down, in effect forming a bubble on the end of the pipe. The glassblower can then treat this as if it were a bubble formed straight out of the furnace, but of course, this bubble has the threads of lattimo glass running through it. The bubble is then manipulated into a finished piece. [2]

Miniature flameworked vessels (aprox. 3cm tall)
in the style of filigrana, by Emilio Santini. 

Outside of the hot shop, there are methods that use only a torch to duplicate the appearance of filigrana and reticello on a smaller scale. This involves starting with glass tubing and "painting" the threads on using thin "stringers" of glass. It is a completely different technique which requires an entirely different set of skills. In the right hands, the results can be strikingly similar. Now that we have the basics down, we can discuss the more spectacular variations that have been developed, which we will talk about next time.


[1] "Colletto"(Italian) "Coeto" (Venetian), means narrow neck or little neck.
[2] The following Youtube video shows American glass artist William Gudenrath, assisted by Harry Siemens pulling filigrana cane and executing a reticello vase at the Corning Museum of Glass. http://www.youtube.com/watch?v=xCrdewFgObc

Incalmo Glass

Incalmo vessels by Tapio Wirkkala for Venini.

In this post, we will explore one of the classical techniques of glass art. Along with filigrana, latticino, reticello and pezzato, incalmo is a classical Venetian technique well established in the art, even if poorly understood by many outsiders.

‘Incalmo’, in Venetian dialect literally means “graft” as in joining two plants. That is a pretty good description of how this effect is achieved; think of a vase whose bottom-half is one color and top is another. The glass artist blows two separate bubbles of glass, opens them and joins them together to form a single bubble. It is a difficult operation because the two open lips must be exactly the same size to join properly. The process can be continued to add more colors; virtuoso pieces may include several sections, each a different color. In addition, the position of the iron rod that the artist uses to hold the bubble can be changed while the piece is under construction, leading to asymmetrical effects.

16th century incalmo plate,
unknown artist.

The above description is the classical way of achieving incalmo, but modern materials and equipment allow artists to achieve a similar effect with considerably less skill. For instance, precise diameter glass tubing is now available in a wide variety of colors. This can be cut into rings with a saw, then stacked in a kiln and fused together. From there, this “prefabricated incalmo tube can be worked by traditional methods. Whether or not this meets the definition of true incalmo depends entirely on whether one focuses on the method or on the end result.

9-10th century incalmo vase,
Syria or Iraq.

The name ‘incalmo’, was applied to glass in the first half of the twentieth century by the Venini factory on Murano, in Venice. [1] However, both the word and the method are much older. The Venini artisans revived the technique to great acclaim, but Venetian examples date from the sixteenth century and Islamic examples from ninth century Syria have also survived. It is not hard to imagine that this joining technique was experimented with shortly after glassblowing became common around the first century BCE. However, what is truly amazing is that any of these early examples survived to be sold to customers without breaking in the cooling process. The reason for this is a technical issue that we have not discussed yet.

All glass expands a little when it is heated and shrinks when it cools. Different formulations of glass generally expand by differing amounts. When a single piece incorporates more than one type of glass, and the thermal expansions differ significantly, the result is disaster. After the piece is finished it is placed in a kiln where it slowly cools back to room temperature. Because of the mismatch, one area wants to shrink more than the adjacent area and the glass cracks along the join. The expansion and contraction is microscopic, but it is enough to ruin hours and hours of work, leading to much gnashing of teeth the morning after, when the finished work is inspected. 

The Venini glass masters had the benefit of this knowledge, but for earlier artisans, trial and error must have played a big role in determining which formulas were compatible. Different colors mean different metallic additives and to match expansion other ingredients would need to be adjusted. Today, manufacturers produce glass in a series based on expansion; artists can be relatively sure that two different colors from the same series can be “grafted” and not self-destruct when cooled.

[1] I have not absolutely confirmed this, but authoritative secondary references credit Venini, and I can find no mention to "incalmo" as a glass technique prior to the twentieth century.

Sara Vincx, Glassmaker

Still life with façon de Venise wineglass,

Alexander Adriaenssen (1587-1661)

Antwerp.

In the 1590s, after the death of her husband, Sara Vincx ran a successful glassmaking business in the city of Antwerp. In the midst of a major war, she presided over a furnace where craftsmen from Murano, Italy, made fine cristallo glassware for the elite families in Flanders. Vinx is the first documented female owner of a glass furnace anywhere.

The Dutch Eighty Years' War for independence from Spain was heating up in Flanders; towns were being pillaged and burned to the ground throughout the Low Countries. Even so, Vincx ably managed a crew of expert glass artists and brought her company's wares to market. When competitors tried to duplicate her products, she successfully defended her shop in court. Later, she remarried to Filippo Gridolfi, one of her foremen at the furnace. The two went on to open a show-room on the Meir, the most prestigious sales district of the city. They also welcomed glassmaker Antonio Neri to work at their facility. Neri was living in the city on an extended seven year visit to his friend and fellow alchemical experimenter Emmanuel Ximenes. 

The seven years that Antonio Neri spent in Antwerp were arguably the most formative for his knowledge of glassmaking. While his first exposure to the art was in Italy, a large portion of the skills and recipes exhibited in his book, L'Arte Vetraria, trace to his activities in the Low Countries. Neri writes "This will make a beautiful aquamarine so nice and marvelous, that you will be astonished, as I have done many times in Flanders in the city of Antwerp to the marvel of all those that saw it." On tinting rock crystal: "In Antwerp, I made quite a bit of this, some ranged in tint from an opal color that looked very beautiful, to a girasol, similarly nice." On equipment: "In Antwerp, I built a furnace that held twenty glass-pots of various colors and when fired for twenty-four hours everything fused and purified." He also speaks of chalcedony glass, paste gems  and ultramarine paint all crafted in Antwerp.

Neri was apparently on good terms with Vincx and Gridolfi, perhaps he was introduced through Ximenes, one of the wealthiest men in the city. In his book Neri describes Gridolfi as "a most courteous gentleman." Vincx and Gridolfi possessed exclusive rights in the region to produce cristallo glass in the Venetian style (façon de Venice) a type of glass that Neri was already quite familiar with from his time making glass in Florence. The license, or patent as it was called, passed down from previous owners, was quite a valuable part of the operation. Employed in their shop was a steady stream of craftsmen from Murano. They made the finest glassware for the upper classes of Antwerp and surrounding areas. Because these craftsmen were bringing the secret techniques with them, they worked outside of the guild system, which would have otherwise required them to share their techniques with other artisans. Through special arrangements with the local authorities, the Venetians were exempt from joining. 


Sara Vincx (or Vincks) was the widow of the former owner, Ambrogio de Mongarda. Gridolfi had previously worked in the shop under Mongarda, who had been in the business for twenty years. Vincx was pressed into service by unhappy circumstances. In 1594, Ambrogio returned alone to Venice to recuperate from gout, but by the following year he was dead, leaving Sara to both run the glass shop and care for at least eight young children. Sara Vincx carries a distinction as the first documented female owner of a glass furnace anywhere. She took an active role in the business as attested by lawsuits she filed, and won, against rival shops that violated her patent. Records show she also expanded the furnace and hired two new artisans to increase production.

Despite the war and the Spanish blockade of the Scheldt River, which shut down trade by sea for a number of years in Antwerp, the glass furnace there thrived and reached its zenith under Vincx and Gridolfi. Soon after their marriage, seventeen employees were counted working at the shop. They established their own retail presence on the Meir, selling high-end cristallo within steps of the Ximenes palace. Their glass operation enjoyed top-rung status, and no doubt, Antonio Neri's involvement must have bolstered the reputation of the firm even further.

*This post first appeared here in a shorter form on 4 October 2013.

Sara Vincx, Glass Maker

Still life with façon de Venise wineglass,

Alexander Adriaenssen (1587-1661)

Antwerp.

In the 1590s, after the death of her husband, Sara Vincx ran a successful glassmaking business in the city of Antwerp. In the midst of a major war, she presided over a furnace where craftsmen from Murano, Italy, made fine cristallo glassware for the elite families in Flanders. Vinx is the first documented female owner of a glass furnace anywhere.

The Dutch Eighty Years' War for independence from Spain was heating up in Flanders; towns were being pillaged and burned to the ground throughout the Low Countries. Even so, Vincx ably managed a crew of expert glass artists and brought her company's wares to market. When competitors tried to duplicate her products, she successfully defended her shop in court. Later, she remarried to Filippo Gridolfi, one of her foremen at the furnace. The two went on to open a show-room on the Meir, the most prestigious sales district of the city. They also welcomed glassmaker Antonio Neri to work at their facility. Neri was living in the city on an extended seven year visit to his friend and fellow alchemical experimenter Emmanuel Ximenes. 

The seven years that Antonio Neri spent in Antwerp were arguably the most formative for his knowledge of glassmaking. While his first exposure to the art was in Italy, a large portion of the skills and recipes exhibited in his book, L'Arte Vetraria, trace to his activities in the Low Countries. Neri writes "This will make a beautiful aquamarine so nice and marvelous, that you will be astonished, as I have done many times in Flanders in the city of Antwerp to the marvel of all those that saw it." On tinting rock crystal: "In Antwerp, I made quite a bit of this, some ranged in tint from an opal color that looked very beautiful, to a girasol, similarly nice." On equipment: "In Antwerp, I built a furnace that held twenty glass-pots of various colors and when fired for twenty-four hours everything fused and purified." He also speaks of chalcedony glass, paste gems  and ultramarine paint all crafted in Antwerp.

Neri was apparently on good terms with Vincx and Gridolfi, perhaps he was introduced through Ximenes, one of the wealthiest men in the city. In his book Neri describes Gridolfi as "a most courteous gentleman." Vincx and Gridolfi possessed exclusive rights in the region to produce cristallo glass in the Venetian style (façon de Venice) a type of glass that Neri was already quite familiar with from his time making glass in Florence. The license, or patent as it was called, passed down from previous owners, was quite a valuable part of the operation. Employed in their shop was a steady stream of craftsmen from Murano. They made the finest glassware for the upper classes of Antwerp and surrounding areas. Because these craftsmen were bringing the secret techniques with them, they worked outside of the guild system, which would have otherwise required them to share their techniques with other artisans. Through special arrangements with the local authorities, the Venetians were exempt from joining. 


Sara Vincx (or Vincks) was the widow of the former owner, Ambrogio de Mongarda. Gridolfi had previously worked in the shop under Mongarda, who had been in the business for twenty years. Vincx was pressed into service by unhappy circumstances. In 1594, Ambrogio returned alone to Venice to recuperate from gout, but by the following year he was dead, leaving Sara to both run the glass shop and care for at least eight young children. Sara Vincx carries a distinction as the first documented female owner of a glass furnace anywhere. She took an active role in the business as attested by lawsuits she filed, and won, against rival shops that violated her patent. Records show she also expanded the furnace and hired two new artisans to increase production.

Despite the war and the Spanish blockade of the Scheldt River, which shut down trade by sea for a number of years in Antwerp, the glass furnace there thrived and reached its zenith under Vincx and Gridolfi. Soon after their marriage, seventeen employees were counted working at the shop. They established their own retail presence on the Meir, selling high-end cristallo within steps of the Ximenes palace. Their glass operation enjoyed top-rung status, and no doubt, Antonio Neri's involvement must have bolstered the reputation of the firm even further.

*This post first appeared here in a shorter form on 4 October 2013.

Gold Ruby Glass

A gold florin.

Legend claims gold ruby glass

 was discovered when a nobel threw

a gold coin into a glass maker's crucible.

Antonio Neri is best remembered for writing L'Arte Vetraria. It was the first printed book entirely devoted to the formulation of glass, which he published in Florence, Italy, in 1612. If we were to single out just one of his more than a hundred recipes, covering glass, lead crystal, paste gems and enamels, it would have to be his prescription for "Transparent Red" ruby glass made with gold. This recipe still captivates glass artists today, as it has since Neri wrote the book. In fact, gold ruby glass is closely tied to the lore of alchemy and has intrigued experimenters as well as artists and collectors since the Roman Empire, possibly before.

Alchemists had long thought gold to be the perfect metal and that all other "lesser" metals (read: lead, tin, copper, iron, mercury and silver) could be coaxed to fully "mature" into gold. Experimenters thought that if they could capture the "essence" of the king of metals, it could be used to "seed" the other metals, and transmute them into pure gold. This is where ruby glass comes into the discussion. In general, glass is colored by the addition of finely powdered metals. Depending on the metal and how it is treated, a whole rainbow of colors can be produced in glass. Alchemists were convinced that the color was an indication that this "essence" of the metal had been released into the glass. 

Cranberry glass or Gold Ruby
 treasury chamber of the Wittelsbacher , Munich Residenz.

For artists and collectors, gold ruby is simply a very attractive color; the difficulty of producing it and working with it only adds to its cachet. Transparent red in glass can be produced other ways, notably with copper, but copper red has a slightly more orange color. Gold ruby, on the other hand, has a characteristic red color that can have slight hints of purple. It can be made light and ethereal or dark and heavily saturated, but viewed next to its competitors, it has a very distinctive hue that experts pride themselves on recognizing.

Neri’s recipe involves moistening gold powder with "aqua regia," which we know as a mixture of nitric and hydrochloric acids. He then spreads this wet mixture on an earthenware pan and heats it in the furnace "until it becomes a red powder, which will take place after many days." Here is that color change that alchemists looked for as an indication of transformation; we know today that Neri was producing gold chloride. This is one of the very few chemical compounds that gold forms and in fact, this is one of the main things that makes gold so special: it does not rust, nor corrode or tarnish, which are, in the end, all chemical reactions between the metal and its environment.

Neri directs his readers to sprinkle, little by little, the gold chloride into the glass melt. He says to "Use fine cristallo, thrown in water many times." Cristallo is the exceptionally clear glass invented by Venetian craftsmen, and "washing" was a technique to remove excess water soluble flux and other contaminants. He finishes his instructions abruptly by saying this method "will make the transparent ruby red glass; but you must experiment in order to find it." In other recipes, Neri goes to great lengths to explain his methods in detail, here he seems content to barely scratch the surface. Much speculation has taken place over the reason for this surprisingly short recipe. Was he ordered, perhaps by his Medici overlords, to keep details to a minimum? Some have wondered if Neri even knew how to produce gold ruby; the short recipe may have been a cover for his lack of knowledge.

Doubts about Neri's gold ruby glass recipe grew after his death, when it was discovered by other experimenters that the addition of small amounts of tin into the mix produced the ruby color quickly and reliably. This compound of tin and gold chloride was called "Cassius purple" after one of its inventors and its color. In some circles it was thought that the tin was an essential ingredient, a lost secret that had been rediscovered. The argument was that gold chloride alone could not produce the color, it must be combined with tin in the form of Cassius purple. However, this is not the case. 

In an 1846 edition of the Journal of the Franklin Institute (ser. 3, v. 11), professor of chemistry and natural philosophy, E. L. Schubarth, cites numerous investigators who demolish this theory. He wrote:

It must not be imagined from this, as some persons have lately stated, that it is necessary to use gold [combined with tin] in the state of Cassius purple.

Neri, at the end of the sixteenth and commencement of the seventeenth century, stated, that in order to stain glass a ruby color, it was only necessary to employ calcined chloride of gold. At a later period, Libar wrote to the same effect, and Merret certified that he had proved the efficacy of the process. In 1834 Golfier Besseyre stated, in the Journal of Pharmacy, that Douault Wieland colored his paste with perchloride of gold only. Lastly, in 1836, Fuss writes, that in Bohemia all the ruby-colored glass was prepared with chloride of gold only, and that glass might be stained red as well with metallic gold, as with oxide of gold or Cassius purple.

It is therefore a fact known for some time, that glass may be stained red, without either Cassius purple or oxide of tin, with [only] metallic gold or preparations of gold. In the glass-works of Bohemia and Silesia perchloride of gold only is used, without the addition of oxide of tin, in order to produce their fine rose or carmine-colored glass.

Of the men cited, Douault-Wieland was a Parisian jeweler who was famous for his artificial gems and crystal glassware. He was praised for his skills by Napoleon. Paul Golfier-Besseyre was a well respected French chemist. Besides many other endeavors, he worked for the glass industry and performed numerous experiments on the formulation of glass. He produced a gold ruby using the same ingredients as Neri. He determined good color could be achieved by letting a new batch of the glass age for a protracted period of time at temperatures below the melting point of gold. Periodically, he removed the glass from the furnace and poured it into water to wash it. The result was a yellowish glass when molten, but when a gaffer finished a piece it was gently reheated and the ruby color developed. 

Sara Vincx, Glass Maker

Still life with façon de Venise wineglass,

Alexander Adriaenssen (1587-1661)

Antwerp.

In the 1590s, after the death of her husband, Sara Vincx ran a successful glassmaking business in the city of Antwerp. In the midst of a major war, she presided over a furnace where craftsmen from Murano, Italy, made fine cristallo glassware for the elite families in Flanders. Vinx is the first documented female owner of a glass furnace anywhere.

The Dutch Eighty Years' War for independence from Spain was heating up in Flanders; towns were being pillaged and burned to the ground throughout the Low Countries. Even so, Vincx ably managed a crew of expert glass artists and brought her company's wares to market. When competitors tried to duplicate her products, she successfully defended her shop in court. Later, she remarried to Filippo Gridolfi, one of her foremen at the furnace. The two went on to open a show-room on the Meir, the most prestigious sales district of the city. They also welcomed glassmaker Antonio Neri to work at their facility. Neri was living in the city on an extended seven year visit to his friend and fellow alchemical experimenter Emmanuel Ximenes. 

The seven years that Antonio Neri spent in Antwerp were arguably the most formative for his knowledge of glassmaking. While his first exposure to the art was in Italy, a large portion of the skills and recipes exhibited in his book, L'Arte Vetraria, trace to his activities in the Low Countries. Neri writes "This will make a beautiful aquamarine so nice and marvelous, that you will be astonished, as I have done many times in Flanders in the city of Antwerp to the marvel of all those that saw it." On tinting rock crystal: "In Antwerp, I made quite a bit of this, some ranged in tint from an opal color that looked very beautiful, to a girasol, similarly nice." On equipment: "In Antwerp, I built a furnace that held twenty glass-pots of various colors and when fired for twenty-four hours everything fused and purified." He also speaks of chalcedony glass, paste gems  and ultramarine paint all crafted in Antwerp.

Neri was apparently on good terms with Vincx and Gridolfi, perhaps he was introduced through Ximenes, one of the wealthiest men in the city. In his book Neri describes Gridolfi as "a most courteous gentleman." Vincx and Gridolfi possessed exclusive rights in the region to produce cristallo glass in the Venetian style (façon de Venice) a type of glass that Neri was already quite familiar with from his time making glass in Florence. The license, or patent as it was called, passed down from previous owners, was quite a valuable part of the operation. Employed in their shop was a steady stream of craftsmen from Murano. They made the finest glassware for the upper classes of Antwerp and surrounding areas. Because these craftsmen were bringing the secret techniques with them, they worked outside of the guild system, which would have otherwise required them to share their techniques with other artisans. Through special arrangements with the local authorities, the Venetians were exempt from joining. 


Sara Vincx (or Vincks) was the widow of the former owner, Ambrogio de Mongarda. Gridolfi had previously worked in the shop under Mongarda, who had been in the business for twenty years. Vincx was pressed into service by unhappy circumstances. In 1594, Ambrogio returned alone to Venice to recuperate from gout, but by the following year he was dead, leaving Sara to both run the glass shop and care for at least eight young children. Sara Vincx carries a distinction as the first documented female owner of a glass furnace anywhere. She took an active role in the business as attested by lawsuits she filed, and won, against rival shops that violated her patent. Records show she also expanded the furnace and hired two new artisans to increase production.

Despite the war and the Spanish blockade of the Scheldt River, which shut down trade by sea for a number of years in Antwerp, the glass furnace there thrived and reached its zenith under Vincx and Gridolfi. Soon after their marriage, seventeen employees were counted working at the shop. They established their own retail presence on the Meir, selling high-end cristallo within steps of the Ximenes palace. Their glass operation enjoyed top-rung status, and no doubt, Antonio Neri's involvement must have bolstered the reputation of the firm even further.

*This post first appeared here in a shorter form on 4 October 2013.

Filigrana Glass

Mezza Filigrana footed vase, circa 1950s,

by Dino Martens (for Aureliano Toso).

Filigrana is a classical glassmaking technique developed in the sixteenth century on the Venetian island of Murano. In the broadest sense, a piece of filigrana -- let's say a vessel -- is composed of transparent glass with very fine vertical threads of color running through it. Traditionally, these threads were opaque white lattimo (milk) glass, running through a colorless high quality product known as cristallo. Because of this, the technique was originally known as “latticino,” a term still in use, but now falling out of favor and being replaced by filigrana (filigree), a name that does not imply any particular color. 

Over the centuries, this and closely related techniques became a kind of trademark for the Murano glass industry. Parallel threads in a loose spiral winding around a vessel from top to bottom form what is perhaps the most basic application of the method. This is known as mezza filigrana (half filigree). The reason for the “half” becomes apparent when we consider its far more famous cousin reticello. With this technique, two sets of threads are used winding in opposite directions to form a fishnet pattern of  diamonds. The name recalls reticella, a traditional Venetian lace. When the work is done properly, tiny air bubbles are trapped inside the glass, one in the center of each diamond of the fishnet pattern.

Even more exotic variations have been developed, which we will discuss another time. First, let's explore how the glass artisan is able to achieve these fine threads in the glass, so perfectly spaced. I should hasten to say that I am not a glassblower and this description is not an instructional, but simply a window into some of the fabulous artistry that takes place in a glass shop. These techniques take hundreds or thousands of hours of practice to master. Even a shallow understanding of the steps that go into a piece of filigrana lead to a far richer appreciation than simply being able to identify it by name.

 “Cane” is a general term for long straight rods of glass. They have many uses in glass artistry and the method by which they are made can be surprising the first time you see it done. It is the same method as was practiced a thousand years ago. A gob of molten glass is removed from the furnace on the end of an iron rod. A second rod is attached by another artisan, with the lump of molten glass between the two rods. They start to pull in opposite directions, slowly at first. They swing and manipulate the hot glass as it cools, forming a mass of relatively uniform diameter. They continue to walk away from each other, the glass pulling thinner as they go. Practiced artisans can end up with a uniform pencil thin straight rod of glass that extends for many meters. It is laid on spaced wooden slats on the floor, allowed to cool and then snapped at regular intervals to form smaller rods.

In the case of filigrana cane, the artisan starts with a smaller gob of opaque glass; let us say lattimo (white). This gob is then dipped into clear glass, which encases it in a heavy transparent layer. When the cane is pulled, the result is a clear rod with a filament of opaque white glass running down the center. Short lengths of cane are laid side by side in a pan. The pan is heated so that adjacent rods start to fuse together into a mat. The glass artist will again take a gather of glass from the furnace around the end of an iron blowpipe and flatten it into a disk, leaving the blowhole unobstructed. The disk, known as a "collar"[2] is touched to the mat of canes at one end and rolled so that the canes wrap around and form a cylinder. The open end of the cylinder is then closed down, in effect forming a bubble on the end of the pipe. The glassblower can then treat this as if it were a bubble formed straight out of the furnace, but of course, this bubble has the threads of lattimo glass running through it. The bubble is then manipulated into a finished piece. [2]

Miniature flameworked vessels (aprox. 3cm tall)
in the style of filigrana, by Emilio Santini. 

Outside of the hot shop, there are methods that use only a torch to duplicate the appearance of filigrana and reticello on a smaller scale. This involves starting with glass tubing and "painting" the threads on using thin "stringers" of glass. It is a completely different technique which requires an entirely different set of skills. In the right hands, the results can be strikingly similar. Now that we have the basics down, we can discuss the more spectacular variations that have been developed, which we will talk about next time.


[1] "Colletto"(Italian) "Coeto" (Venetian), means narrow neck or little neck.
[2] The following Youtube video shows American glass artist William Gudenrath, assisted by Harry Siemens pulling filigrana cane and executing a reticello vase at the Corning Museum of Glass. http://www.youtube.com/watch?v=xCrdewFgObc

Incalmo of Venice

Incalmo vessels by Tapio Wirkkala for Venini.

In this post, we will explore one of the classical techniques of glass art. Along with filigrana, latticino, reticello and pezzato, incalmo is a classical Venetian technique well established in the art, even if poorly understood by many outsiders.

‘Incalmo’, in Venetian dialect literally means “graft” as in joining two plants. That is a pretty good description of how this effect is achieved; think of a vase whose bottom-half is one color and top is another. The glass artist blows two separate bubbles of glass, opens them and joins them together to form a single bubble. It is a difficult operation because the two open lips must be exactly the same size to join properly. The process can be continued to add more colors; virtuoso pieces may include several sections, each a different color. In addition, the position of the iron rod that the artist uses to hold the bubble can be changed while the piece is under construction, leading to asymmetrical effects.

16th century incalmo plate,
unknown artist.

The above description is the classical way of achieving incalmo, but modern materials and equipment allow artists to achieve a similar effect with considerably less skill. For instance, precise diameter glass tubing is now available in a wide variety of colors. This can be cut into rings with a saw, then stacked in a kiln and fused together. From there, this “prefabricated incalmo tube can be worked by traditional methods. Whether or not this meets the definition of true incalmo depends entirely on whether one focuses on the method or on the end result.

9-10th century incalmo vase,
Syria or Iraq.

The name ‘incalmo’, was applied to glass in the first half of the twentieth century by the Venini factory on Murano, in Venice. [1] However, both the word and the method are much older. The Venini artisans revived the technique to great acclaim, but Venetian examples date from the sixteenth century and Islamic examples from ninth century Syria have also survived. It is not hard to imagine that this joining technique was experimented with shortly after glassblowing became common around the first century BCE. However, what is truly amazing is that any of these early examples survived to be sold to customers without breaking in the cooling process. The reason for this is a technical issue that we have not discussed yet.

All glass expands a little when it is heated and shrinks when it cools. Different formulations of glass generally expand by differing amounts. When a single piece incorporates more than one type of glass, and the thermal expansions differ significantly, the result is disaster. After the piece is finished it is placed in a kiln where it slowly cools back to room temperature. Because of the mismatch, one area wants to shrink more than the adjacent area and the glass cracks along the join. The expansion and contraction is microscopic, but it is enough to ruin hours and hours of work, leading to much gnashing of teeth the morning after, when the finished work is inspected. 

The Venini glass masters had the benefit of this knowledge, but for earlier artisans, trial and error must have played a big role in determining which formulas were compatible. Different colors mean different metallic additives and to match expansion other ingredients would need to be adjusted. Today, manufacturers produce glass in a series based on expansion; artists can be relatively sure that two different colors from the same series can be “grafted” and not self-destruct when cooled.

[1] I have not absolutely confirmed this, but authoritative secondary references credit Venini, and I can find no mention to "incalmo" as a glass technique prior to the twentieth century.

Alberico Barbini

The island of Murano , circa 1600

attributed to Danckerts

In the early seventeenth century, Antonio Neri began preparing batches of glass for the royal family in Florence, Italy. This was a specialist vocation undertaken by alchemists, which by schooling, Neri was. His job as “conciatore” involved procuring the ingredients, preparing, mixing and melting them and working with the glass artisans, adjusting the consistency and colors for the work being done. It was a position that carried great prestige, and Neri’s book on glassmaking [1] would cement his name in history. 

Shortly before Neri was born, in 1576, the grand duke of Tuscany, Cosimo I de’ Medici, brokered a special deal with the doge of Venice to have master glass artisans come to Florence and teach their secrets. These men were from the island of Murano; the most famous center of glassmaking anywhere. There is only scant evidence that Neri himself traveled to Venice and perhaps only once, but there is no doubt that he benefited greatly from the knowledge of Muranese workers in Florence, Pisa and Antwerp during his lifetime. 

Over the intervening centuries, the title of the glass batcher changed, but the tradition and prestige of glass formulation continued well into the middle of the twentieth century. In fact, even today, among the small glass manufacturers that compose the studio glass movement, the glass batcher is considered to be something of a modern alchemist; keeper of the arcane knowledge of  the chemicals and amounts necessary to produce special colors and adjust properties of the glass.

Now, fast forward four centuries from Neri's Italy; in the early 1920s, a Milanese lawyer named Paolo Venini partnered with a Venetian-born antique dealer friend, Giacomo Cappellin, to start a new glass factory on Murano. [2] Even as recently as this, the glass batcher still held a respected position both within the factory and the community. Through several incarnations over the next half century Venini grew a world-wide reputation for innovative designs, of which color played an important part. They are specifically associated with the fazzoletto (handkerchief) style vase and the incalmo technique of fusing two or more colors of glass seamlessly in a single furnace-blown piece. 

In 1925, Cappellin split from Venini and took many of the craftsmen with him, in 1933 the new business was acquired by Pauly & C. Again, chemical knowledge and the artistry of reproducing ancient colors made a worldwide reputation. [3] As ownerships changed hands like cards in a game of poker, artisans shuffled between factories. It is easy to lose track of the individual glassworker. Even for a period so recent, many records exist only in the heads of the family members still living on the island. 

In 1956 the Stazione Sperimentale del Vetro (Experimental Station for Glass) was started on Murano with the mandate to preserve and promote the technical aspects of Italy’s glassmaking heritage. [4] The new institution was regarded by some traditionalists with great suspicion, but as we will see, others embraced the resource.

I recently sat down with renowned glass artist Emilio Santini, who today carries on a six-centuries-old family tradition in glasswork. [5] Emilio had recently called home, to Murano, which led to his father’s recollection of an uncle, who worked making color for Venini and Pauly. Here Emilio recounts the conversation:

Alberico Barbini was the uncle of my father, Mario Santini and the man in charge of making the glass batch “partie” (Venetian) “partite” (Italian). He was the brother of my grandmother, Delfina Barbini. He was not the only one [in my family] who worked for Venini in the early days but the most respected. At Venini he worked formulating glass after another great batch maker, [Albino] Carrara. 

In the early to mid [twentieth] century the batch maker still held an important position in the factory, not like now, you know, and he kept his formulations quite secret, although this relative of mine, Alberico, was smart enough to use the most modern technology available at that time. 

He was different from other batch makers in that when the Stazione Sperimentale del Vetro opened, he made extensive use of it in reproducing colors. At that time, and even now to an extent, the institution was not seen as good for traditional Murano glassmaking. 

He later moved on to Pauly where he was in charge of reproducing the glass colors that were in use in the seventeenth, eighteenth and nineteenth centuries. First, he assisted in remaking broken or missing pieces in private collections, then later in making reproduction antique stemware at Pauly that was impossible to distinguish from the originals. 

You must realize that all this does not come from documents but from the memory, still very sharp and lucid, of my father.

Addendum: On 7 August 2016, at the age of 96, Mario Santini died, surrounded by his family at his home on Murano.


[1] L’Arte Vetraria, (Neri 1612).
[2] Paolo Venini http://en.wikipedia.org/wiki/Paolo_Venini also see https://www.facebook.com/pages/Venini/198475426829887
[3] Pauly & C. Compagnia Venezia Murano http://en.wikipedia.org/wiki/Pauly_%26_C._%E2%80%93_Compagnia_Venezia_Murano
[4] Stazione Sperimentale del Vetro  http://www.spevetro.it/indexENG.htm
[5] Emilio Santini http://www.cmog.org/bio/emilio-santini
* This post first appeared here on 25 Feb 2015.