Aventurine Glass

 

Small amphora in aventurine glass,

Murano, Salviati.

With all its glitz and sparkle, aventurine (avventurina) stands out as a flamboyant extrovert among the varieties of glass. Developed and perfected on the Venetian island of Murano, also known as 'goldstone', it consists of a transparent base glass with myriad reflective crystalline "spangles" running throughout. The classical version is a deep golden brown with crystallites composed mainly of metallic copper, with a few related compounds as supporting cast. However, numerous colors have been developed, including red, orange, yellow, green, blue, violet, black and white. 

Folklore holds that aventurine was discovered by accident ("a venturi") when unknown monks inadvertently dropped copper or brass shavings into a glass melt as early as the thirteenth century. [1] However, more thorough investigations have recently identified 1620 as a likely date for the first appearance of aventurine glass. [2] No example or written account has been found that dates prior to the seventeenth century. An alternate story accounts for the name aventurine being derived from 'adventure'; referring to the difficulty and uncertainty involved in its production.[3] At first, the formula was a closely held secret among a few glassmakers and subsequently it was lost and then rediscovered not once but  twice.

To complicate matters, natural minerals with a similar appearance were named after the glass, leading to the misconception that they were also discovered after the glass was invented. This is clearly not the case. Early examples of mineral aventurine artifacts date to the Neolithic era [4] and can be found throughout history. First century Roman writer Pliny mentions a type of stone with silvery flecks, a passage that was well known when the glass was developed.  The compositions of these minerals were also identified early; either species of quartz that contain flecks of mica, or a type of feldspar (sunstone).[5] Mineral aventurine turns up as the eyes of Greek statues, in stonework mosaics and later in the 'pietre dure' art perfected by the Medici artisans in Florence around the time Antonio Neri started making glass there. The chances are good that examples of the mineral were known to Neri as well as to the glassmakers on Murano, but a recipe for the glass version does not turn up in Neri’s 1612 book; he was apparently too early by a decade.  

The story of aventurine's accidental discovery by monks may well be apocryphal; nevertheless, it is a great entrée to understanding how the formulation works. First, contrary to what the story implies, aventurine is not the result of dumping metallic confetti into glass. The reflective "spangles" (as early researchers were fond of calling them) are actually uniformly sized, mirror-like crystals that are grown in the glass. In truth, the formula is quite similar to recipes already in use by Neri and others; the difference was in proportions and in how the glass was treated after it was in the furnace. The formula for aventurine calls for the addition of copper, iron and tin oxides, to a base that was a hybrid of soda, potash and lead glass. Neri’s recipe #128 is titled "A Proven Way to Make Rosichiero" [6] and provides for all of these ingredients, albeit in lower concentrations. Rosichiero was a transparent tawny red colored glass that was a staple of furnaces throughout Italy. 

The secret to producing the reflective "spangles" was to mix the glass and heat it in the furnace in a normal way, but then to slowly reduce the heat while creating a low oxygen “reducing” atmosphere. The furnace draught was shut; the glass pot was fitted with a tight lid and then covered with ashes and allowed to cool very slowly.  

Initially, the batch is saturated with copper oxide. This means the glass has dissolved as much copper, iron and tin as it can and any further addition of these powders will simply float to the bottom of the pot.  The exact amount of powdered metals able to dissolve is a function of temperature; the hotter the glass the more that will dissolve and the cooler the glass the less that will dissolve. The key concept here is that as the glass slowly cools, the metals start to come out of solution and crystals start to form. There is some complex chemistry happening at the same time; the reducing atmosphere encourage the metals to stay in a pure un-oxidized form,  Furthermore any oxygen or sulfur  that happens to be present will preferentially combine with the iron, leaving the copper crystals pristine. Once cooled to room temperature, a successful batch would be broken away from the glass pot by workers and divided into smaller pieces. Glass artisans wanting to incorporate the aventurine into their work needed to work quickly. They carefully reheated an appropriate nugget and coated (encase) it in a layer of clear glass; once molten, direct exposure to the air would destroy the glittery effect. 

Over time, it was discovered that various colors could be produced with the addition of different chemicals, but the central principal of growing tiny metallic crystals is the same.


[1]  The earliest instance of this story in print that I can find is fairly late;  Faustino Corsi, Delle pietre antiche: libri quattro (Rome: Salviuccio e figlio, 1828)  pp. 166-167.  
[2] Cesare Moretti (†), Bernard Gratuze and Sandro Hreglich,  “Le verre aventurine (‘ avventurina ‘) : son histoire, les recettes, les analyses, sa fabrication”, ArcheoSciences, 37 | 2013, 135-154.
[3] For instance see  Giulio Salviati, “Venetian Glass” Journal of the Society of Arts (Proceedings), Volume 37 (7 June,1889), p. 630
[4] Neolithic Quartz Aventurine Pendant - 7 Cm/ 2. 76 ", green - 6500 To 2000 Bp – Sahara. Item Id: 106549,  Weight: 83 gm. Sahara - Mauritania - Tagant country.
http://ancientpoint.com/inf/106549-neolithic_quartz_aventurine_pendant___7_cm_2___76____6500_to_2000_bp___sahara.html
[5] Dizionario del cittadino, o sia Ristretto storico, teorico e ..., Volume 1 pp. 38-39.
[6] Antonio Neri, L'Arte Vetraria (Firenze: Giunti, 1612).
[7] Sauzay, A. (1870) Marvels of Glassmaking in All Ages. London, 1870 pp. 173 - 175.

Art and Science

 

Jacopo Ligozzi,1518,  fanciful glass vessels,

ink and watercolor on paper.

Antonio Neri's writing on glassmaking and alchemy was distinguished from that of many contemporary authors in that his work was all deeply rooted in hands-on experience. He worked in the early 17th century, when art and science were different sides of the same endeavor to understand the world. His contemporaries were often content to repeat century's old teachings about the four Aristotelian elements; that chemical interactions could be explained through an analysis of the balance between hot and cold, dry and wet. But more and more, these notions were being discarded and replaced. It is common to cite the invention of instruments, and other technical developments; these factors certainly did contribute to advancement. But many different forces worked toward the emergence of early modern science, and one in particular is so obvious that it is easily overlooked: artists.

Working with hot glass was a profession in which attention to nature was essential: artists did not have the luxury of fanciful explanations of physical processes. They were obliged by their work to learn the ways glass mixed, moved and behaved in the furnace, not as they imagined it should, but as it actually did. The only way to achieve the complex forms and vessels for which master glassblowers were renowned was through long experience. Failure to understand the glass and predict its properties accurately resulted in failure of the piece.

Neri was immersed in this environment and the same principles applied to his own work in formulating the glass. Ancient theories had little value if they did not accurately predict nature. Like the glass artists, the way forward for Neri was careful attention and hands-on experience. He learned the value of starting with highly purified ingredients for his glass melts. He learned that too much glass salt resulted in a putrid 'gall' that would need to be skimmed off the molten surface. Substituting salts made from fern plants, for the Kali based ones from the Levant, produced a more lustrous glass, yet it stiffened more quickly for the glassblowers.

A glass artist's work also serves as a kind of narrative. For those familiar with the techniques, a finished piece of glass work can be 'read' like a story: The handles were put on last, before that, perhaps a thin bead of color was applied to the lip of the vessel. And the work started as a blown bubble of glass, shaped and opened with special tools. Each step is an insight into the artist's technique, but also into the way nature itself operates. Each motion was a well practiced negotiation between the artist and the properties of the material.

On one hand, an artist's job was to produce objects contemplated for their physical beauty and cultural significance. On the other hand, the act of producing these objects created an environment where accurate reasoning flourished. By collecting artists and employing them together, the Medici rulers of Tuscany were creating a cauldron effect where experiences collected, stewed and nature's secrets unraveled.

* This post first appeared here on 23 October 2013.

Aventurine Glass

Small amphora in aventurine glass,

Murano, Salviati.

With all its glitz and sparkle, aventurine (avventurina) stands out as a flamboyant extrovert among the varieties of glass. Developed and perfected on the Venetian island of Murano, also known as 'goldstone', it consists of a transparent base glass with myriad reflective crystalline "spangles" running throughout. The classical version is a deep golden brown with crystallites composed mainly of metallic copper, with a few related compounds as supporting cast. However, numerous colors have been developed, including red, orange, yellow, green, blue, violet, black and white. 

Folklore holds that aventurine was discovered by accident ("a venturi") when unknown monks inadvertently dropped copper or brass shavings into a glass melt as early as the thirteenth century. [1] However, more thorough investigations have recently identified 1620 as a likely date for the first appearance of aventurine glass. [2] No example or written account has been found that dates prior to the seventeenth century. An alternate story accounts for the name aventurine being derived from 'adventure'; referring to the difficulty and uncertainty involved in its production.[3] At first, the formula was a closely held secret among a few glassmakers and subsequently it was lost and then rediscovered not once but  twice.

To complicate matters, natural minerals with a similar appearance were named after the glass, leading to the misconception that they were also discovered after the glass was invented. This is clearly not the case. Early examples of mineral aventurine artifacts date to the Neolithic era [4] and can be found throughout history. First century Roman writer Pliny mentions a type of stone with silvery flecks, a passage that was well known when the glass was developed.  The compositions of these minerals were also identified early; either species of quartz that contain flecks of mica, or a type of feldspar (sunstone).[5] Mineral aventurine turns up as the eyes of Greek statues, in stonework mosaics and later in the 'pietre dure' art perfected by the Medici artisans in Florence around the time Antonio Neri started making glass there. The chances are good that examples of the mineral were known to Neri as well as to the glassmakers on Murano, but a recipe for the glass version does not turn up in Neri’s 1612 book; he was apparently too early by a decade.  

The story of aventurine's accidental discovery by monks may well be apocryphal; nevertheless, it is a great entrée to understanding how the formulation works. First, contrary to what the story implies, aventurine is not the result of dumping metallic confetti into glass. The reflective "spangles" (as early researchers were fond of calling them) are actually uniformly sized, mirror-like crystals that are grown in the glass. In truth, the formula is quite similar to recipes already in use by Neri and others; the difference was in proportions and in how the glass was treated after it was in the furnace. The formula for aventurine calls for the addition of copper, iron and tin oxides, to a base that was a hybrid of soda, potash and lead glass. Neri’s recipe #128 is titled "A Proven Way to Make Rosichiero" [6] and provides for all of these ingredients, albeit in lower concentrations. Rosichiero was a transparent tawny red colored glass that was a staple of furnaces throughout Italy. 

The secret to producing the reflective "spangles" was to mix the glass and heat it in the furnace in a normal way, but then to slowly reduce the heat while creating a low oxygen “reducing” atmosphere. The furnace draught was shut; the glass pot was fitted with a tight lid and then covered with ashes and allowed to cool very slowly.  

Initially, the batch is saturated with copper oxide. This means the glass has dissolved as much copper, iron and tin as it can and any further addition of these powders will simply float to the bottom of the pot.  The exact amount of powdered metals able to dissolve is a function of temperature; the hotter the glass the more that will dissolve and the cooler the glass the less that will dissolve. The key concept here is that as the glass slowly cools, the metals start to come out of solution and crystals start to form. There is some complex chemistry happening at the same time; the reducing atmosphere encourage the metals to stay in a pure un-oxidized form,  Furthermore any oxygen or sulfur  that happens to be present will preferentially combine with the iron, leaving the copper crystals pristine. Once cooled to room temperature, a successful batch would be broken away from the glass pot by workers and divided into smaller pieces. Glass artisans wanting to incorporate the aventurine into their work needed to work quickly. They carefully reheated an appropriate nugget and coated (encase) it in a layer of clear glass; once molten, direct exposure to the air would destroy the glittery effect. 

Over time, it was discovered that various colors could be produced with the addition of different chemicals, but the central principal of growing tiny metallic crystals is the same.


[1]  The earliest instance of this story in print that I can find is fairly late;  Faustino Corsi, Delle pietre antiche: libri quattro (Rome: Salviuccio e figlio, 1828)  pp. 166-167.  
[2] Cesare Moretti (†), Bernard Gratuze and Sandro Hreglich,  “Le verre aventurine (‘ avventurina ‘) : son histoire, les recettes, les analyses, sa fabrication”, ArcheoSciences, 37 | 2013, 135-154.
[3] For instance see  Giulio Salviati, “Venetian Glass” Journal of the Society of Arts (Proceedings), Volume 37 (7 June,1889), p. 630
[4] Neolithic Quartz Aventurine Pendant - 7 Cm/ 2. 76 ", green - 6500 To 2000 Bp – Sahara. Item Id: 106549,  Weight: 83 gm. Sahara - Mauritania - Tagant country.
http://ancientpoint.com/inf/106549-neolithic_quartz_aventurine_pendant___7_cm_2___76____6500_to_2000_bp___sahara.html
[5] Dizionario del cittadino, o sia Ristretto storico, teorico e ..., Volume 1 pp. 38-39.
[6] Antonio Neri, L'Arte Vetraria (Firenze: Giunti, 1612).
[7] Sauzay, A. (1870) Marvels of Glassmaking in All Ages. London, 1870 pp. 173 - 175.

Sisters of an Alchemist

Pharmacy, apothecary and assistant 
cooking medicine, woodcut, from: 
Hieronymus Brunschwig
 (circa 1450 - circa 1512)

Among the ten children born to glassmaker Antonio Neri’s parents, three of them were girls; Lessandra, Maria, and Lucrezia. Because women were not allowed to legally own property, or sign contracts many of the usual sources of information are silent. Most of what we can learn about them is through their relationships with the men around them.

The Neri's were a patrician family, and the children enjoyed a very comfortable existence for the late sixteenth century. There is evidence that all three sisters survived into adulthood. Lessandra was the first-born, nine years older than Maria, and twelve years older than Lucrezia.

When Lessandra was around age seventeen, her famous father, Neri Neri, was appointed as personal physician to the newly crowned Grand Duke Ferdinando de’ Medici. However, only a few short years later their mother Dianora died at age 42, of causes that are unknown, perhaps childbirth. The girls were 22, 13 and 10. A few short years later they lost both their father, and a brother.

Two information sources for the Neri sisters are their birth records kept at the Opera del Duomo and genealogy records for the family which are filed at the National Archives, both in Florence. The baptism records hold a wealth of indirect material through the names of their godparents. While these do not tell us anything specific about them, it does tell us who their influences were; who they looked to for strength and spiritual guidance, under the circumstances, this is the best we can do.

Lessandra (b. 1572) claimed Baccio Valori as her godfather. The Valori family had a long, tragic history with the ruling Medici family. His father, grandfather and great-grandfather were all close Medici supporters, yet each ended up exiled, imprisoned, or executed after relationships soured. On one hand he was faithfully employed by the Medici, yet he reportedly spent a good deal of his time collecting letters and papers documenting his family’s close support of Girolamo Savonarola, the firebrand Dominican priest who lead Florence in the late 1490s, after the Medici had been temporarily expelled from the city.

Lessandra’s godmother was Marietta Gaetani, also from a noble family, which included dukes, cardinals and popes. They played prominent roles in the politics of Pisa, Rome and Naples for several centuries. Marietta’s father owned the house from whose tower Galileo showed the moons of Jupiter to Grand Duke Cosimo II in 1610.

The genealogical records imply that Lessandra later took vows with the S. Agata monastery on the North end of Florence and took the name suor Emilia.

Maria’s (b. 1581) godfather was Monsignor Giovanni Alberti. Giovanni was the son of a Florentine senator. He served as protonotary apostolic for Pope Gregory XIII and as bishop of Cortona under Pope Clement VIII. A godfather serving in the papal inner chambers was a good family contact indeed. Also appearing for Maria was Pierfilippo Perini, a physician and lawyer. The Registri lists Maria Neri's godmother as Alessandra di Girolamo Pepi. Among the prominent Florentine republicans was Alessandra's father, Girolamo. He was tortured by Alessandro de' Medici in the 1530s, upon the family's regaining control of Florence after the siege.The genealogy indicates that she married into the Boscoli family, but further work is needed to identify a specific individual.

Lucrezia (b. 1584), the youngest Neri girl, has a single godparent listed in the register, Montiglio degli Albizi. The Albizi family boasted powerful bankers and politicians. This was another case where deep divisions over Medici rule drove a family apart. Perhaps the best-recognized member of the Albizzi family was Eleonora degli Albizi. She was the young consort of grand duke Cosimo I. Folklore has it that in 1566, Cosimo intended to retire from public life and marry Albizi quietly, after the birth of a girl, but his regent son, Francesco I, forbade it to due to the inheritance complications that would ensue. The story is that Cosimo's long-time personal secretary, Sforza Almeni, leaked word of the clandestine marriage to the family. For his betrayal, an enraged Cosimo murdered Almeni in cold blood. Eleonora later gave birth to Don Giovanni de’ Medici, the uncle and friend of Don Antonio, Neri's sponsor. The specific Albizi family member we are interested in, Lucrezia's godfather, Montiglio degli Albizi, seems to have eluded history. Lucretia married into the Talenti family, but no further details are known.

Art and Science

Jacopo Ligozzi,1518,  fanciful glass vessels,

ink and watercolor on paper.

Antonio Neri's writing on glassmaking and alchemy was distinguished from that of many contemporary authors in that his work was all deeply rooted in hands-on experience. He worked in the early 17th century, when art and science were different sides of the same endeavour to understand the world. His contemporaries were often content to repeat century's old teachings about the four Aristotelian elements; that chemical interactions could be explained through an analysis of the balance between hot and cold, dry and wet. But more and more, these notions were being discarded and replaced. It is common to cite the invention of instruments, and other technical developments; these factors certainly did contribute to advancement. But many different forces worked toward the emergence of early modern science, and one in particular is so obvious that it is easily overlooked: artists.

Working with hot glass was a profession in which attention to nature was essential: artists did not have the luxury of fanciful explanations of physical processes. They were obliged by their work to learn the ways glass mixed, moved and behaved in the furnace, not as they imagined it should, but as it actually did. The only way to achieve the complex forms and vessels for which master glassblowers were renowned was through long experience. Failure to understand the glass and predict its properties accurately resulted in failure of the piece.

Neri was immersed in this environment and the same principles applied to his own work in formulating the glass. Ancient theories had little value if they did not accurately predict nature. Like the glass artists, the way forward for Neri was careful attention and hands-on experience. He learned the value of starting with highly purified ingredients for his glass melts. He learned that too much glass salt resulted in a putrid 'gall' that would need to be skimmed off the molten surface. Substituting salts made from fern plants, for the Kali based ones from the Levant, produced a more lustrous glass, yet it stiffened more quickly for the glassblowers.

A glass artist's work also serves as a kind of narrative. For those familiar with the techniques, a finished piece of glass work can be 'read' like a story: The handles were put on last, before that, perhaps a thin bead of color was applied to the lip of the vessel. And the work started as a blown bubble of glass, shaped and opened with special tools. Each step is an insight into the artist's technique, but also into the way nature itself operates. Each motion was a well practiced negotiation between the artist and the properties of the material.

On one hand, an artist's job was to produce objects contemplated for their physical beauty and cultural significance. On the other hand, the act of producing these objects created an environment where accurate reasoning flourished. By collecting artists and employing them together, the Medici rulers of Tuscany were creating a cauldron effect where experiences collected, stewed and nature's secrets unraveled.

* This post first appeared here on 23 October 2013.

Sisters of an Alchemist

Portrait of the Egerton Sisters
(no relation to Neri)
English School,  c. 1601-1602

Among the ten children born to glassmaker Antonio Neri’s parents, three of them were girls; Lessandra, Maria, and Lucrezia. Because women were not allowed to legally own property, or sign contracts many of the usual sources of information are silent. Most of what we can learn about them is through their relationships with the men around them.

The Neri's were a patrician family, and the children enjoyed a very comfortable existence for the late sixteenth century. There is evidence that all three sisters survived into adulthood. Lessandra was the first-born, nine years older than Maria, and twelve years older than Lucrezia.

When Lessandra was around age seventeen, her famous father, Neri Neri, was appointed as personal physician to the newly crowned Grand Duke Ferdinando de’ Medici. However, only a few short years later their mother Dianora died at age 42, of causes that are unknown, perhaps childbirth. The girls were 22, 13 and 10. A few short years later they lost both their father, and a brother.

Two information sources for the Neri sisters are their birth records kept at the Opera del Duomo and genealogy records for the family which are filed at the National Archives, both in Florence. The baptism records hold a wealth of indirect material through the names of their godparents. While these do not tell us anything specific about them, it does tell us who their influences were; who they looked to for strength and spiritual guidance, under the circumstances, this is the best we can do.

Lessandra (b. 1572) claimed Baccio Valori as her godfather. The Valori family had a long, tragic history with the ruling Medici family. His father, grandfather and great-grandfather were all close Medici supporters, yet each ended up exiled, imprisoned, or executed after relationships soured. On one hand he was faithfully employed by the Medici, yet he reportedly spent a good deal of his time collecting letters and papers documenting his family’s close support of Girolamo Savonarola, the firebrand Dominican priest who lead Florence in the late 1490s, after the Medici had been temporarily expelled from the city.

Lessandra’s godmother was Marietta Gaetani, also from a noble family, which included dukes, cardinals and popes. They played prominent roles in the politics of Pisa, Rome and Naples for several centuries. Marietta’s father owned the house from whose tower Galileo showed the moons of Jupiter to Grand Duke Cosimo II in 1610.

The genealogical records imply that Lessandra later took vows with the S. Agata monastery on the North end of Florence and took the name suor Emilia.


Maria’s (b. 1581) godfather was Monsignor Giovanni Alberti. Giovanni was the son of a Florentine senator. He served as protonotary apostolic for Pope Gregory XIII and as bishop of Cortona under Pope Clement VIII. A godfather serving in the papal inner chambers was a good family contact indeed. Also appearing for Maria was Pierfilippo Perini, a physician and lawyer. The Registri lists Maria Neri's godmother as Alessandra di Girolamo Pepi. Among the prominent Florentine republicans was Alessandra's father, Girolamo. He was tortured by Alessandro de' Medici in the 1530s, upon the family's regaining control of Florence after the siege.The genealogy indicates that she married into the Boscoli family, but further work is needed to identify a specific individual.

Lucrezia (b. 1584), the youngest Neri girl, has a single godparent listed in the register, Montiglio degli Albizi. The Albizi family boasted powerful bankers and politicians. This was another case where deep divisions over Medici rule drove a family apart. Perhaps the best-recognized member of the Albizzi family was Eleonora degli Albizi. She was the young consort of grand duke Cosimo I. Folklore has it that in 1566, Cosimo intended to retire from public life and marry Albizi quietly, after the birth of a girl, but his regent son, Francesco I, forbade it to due to the inheritance complications that would ensue. The story is that Cosimo's long-time personal secretary, Sforza Almeni, leaked word of the clandestine marriage to the family. For his betrayal, an enraged Cosimo murdered Almeni in cold blood. Eleonora later gave birth to Don Giovanni de’ Medici, the uncle and friend of Don Antonio, Neri's sponsor. The specific Albizi family member we are interested in, Lucrezia's godfather, Montiglio degli Albizi, seems to have eluded history. Lucretia married into the Talenti family, but no further details are known.

Aventurine Glass

Small amphora in aventurine glass,

Murano, Salviati.

With all its glitz and sparkle, aventurine (avventurina) stands out as a flamboyant extrovert among the varieties of glass. Developed and perfected on the Venetian island of Murano, also known as 'goldstone', it consists of a transparent base glass with myriad reflective crystalline "spangles" running throughout. The classical version is a deep golden brown with crystallites composed mainly of metallic copper, with a few related compounds as supporting cast. However, numerous colors have been developed, including red, orange, yellow, green, blue, violet, black and white. 

Folklore holds that aventurine was discovered by accident ("a venturi") when unknown monks inadvertently dropped copper or brass shavings into a glass melt as early as the thirteenth century. [1] However, more thorough investigations have recently identified 1620 as a likely date for the first appearance of aventurine glass. [2] No example or written account has been found that dates prior to the seventeenth century. An alternate story accounts for the name aventurine being derived from 'adventure'; referring to the difficulty and uncertainty involved in its production.[3] At first, the formula was a closely held secret among a few glassmakers and subsequently it was lost and then rediscovered not once but  twice.

To complicate matters, natural minerals with a similar appearance were named after the glass, leading to the misconception that they were also discovered after the glass was invented. This is clearly not the case. Early examples of mineral aventurine artifacts date to the Neolithic era [4] and can be found throughout history. First century Roman writer Pliny mentions a type of stone with silvery flecks, a passage that was well known when the glass was developed.  The compositions of these minerals were also identified early; either species of quartz that contain flecks of mica, or a type of feldspar (sunstone).[5] Mineral aventurine turns up as the eyes of Greek statues, in stonework mosaics and later in the 'pietre dure' art perfected by the Medici artisans in Florence around the time Antonio Neri started making glass there. The chances are good that examples of the mineral were known to Neri as well as to the glassmakers on Murano, but a recipe for the glass version does not turn up in Neri’s 1612 book; he was apparently too early by a decade.  

The story of aventurine's accidental discovery by monks may well be apocryphal; nevertheless, it is a great entrée to understanding how the formulation works. First, contrary to what the story implies, aventurine is not the result of dumping metallic confetti into glass. The reflective "spangles" (as early researchers were fond of calling them) are actually uniformly sized, mirror-like crystals that are grown in the glass. In truth, the formula is quite similar to recipes already in use by Neri and others; the difference was in proportions and in how the glass was treated after it was in the furnace. The formula for aventurine calls for the addition of copper, iron and tin oxides, to a base that was a hybrid of soda, potash and lead glass. Neri’s recipe #128 is titled "A Proven Way to Make Rosichiero" [6] and provides for all of these ingredients, albeit in lower concentrations. Rosichiero was a transparent tawny red colored glass that was a staple of furnaces throughout Italy. 

The secret to producing the reflective "spangles" was to mix the glass and heat it in the furnace in a normal way, but then to slowly reduce the heat while creating a low oxygen “reducing” atmosphere. The furnace draught was shut; the glass pot was fitted with a tight lid and then covered with ashes and allowed to cool very slowly.  

Initially, the batch is saturated with copper oxide. This means the glass has dissolved as much copper, iron and tin as it can and any further addition of these powders will simply float to the bottom of the pot.  The exact amount of powdered metals able to dissolve is a function of temperature; the hotter the glass the more that will dissolve and the cooler the glass the less that will dissolve. The key concept here is that as the glass slowly cools, the metals start to come out of solution and crystals start to form. There is some complex chemistry happening at the same time; the reducing atmosphere encourage the metals to stay in a pure un-oxidized form,  Furthermore any oxygen or sulfur  that happens to be present will preferentially combine with the iron, leaving the copper crystals pristine. Once cooled to room temperature, a successful batch would be broken away from the glass pot by workers and divided into smaller pieces. Glass artisans wanting to incorporate the aventurine into their work needed to work quickly. They carefully reheated an appropriate nugget and coated (encase) it in a layer of clear glass; once molten, direct exposure to the air would destroy the glittery effect. 

Over time, it was discovered that various colors could be produced with the addition of different chemicals, but the central principal of growing tiny metallic crystals is the same.


[1]  The earliest instance of this story in print that I can find is fairly late;  Faustino Corsi, Delle pietre antiche: libri quattro (Rome: Salviuccio e figlio, 1828)  pp. 166-167.  
[2] Cesare Moretti (†), Bernard Gratuze and Sandro Hreglich,  “Le verre aventurine (‘ avventurina ‘) : son histoire, les recettes, les analyses, sa fabrication”, ArcheoSciences, 37 | 2013, 135-154.
[3] For instance see  Giulio Salviati, “Venetian Glass” Journal of the Society of Arts (Proceedings), Volume 37 (7 June,1889), p. 630
[4] Neolithic Quartz Aventurine Pendant - 7 Cm/ 2. 76 ", green - 6500 To 2000 Bp – Sahara. Item Id: 106549,  Weight: 83 gm. Sahara - Mauritania - Tagant country.
http://ancientpoint.com/inf/106549-neolithic_quartz_aventurine_pendant___7_cm_2___76____6500_to_2000_bp___sahara.html
[5] Dizionario del cittadino, o sia Ristretto storico, teorico e ..., Volume 1 pp. 38-39.
[6] Antonio Neri, L'Arte Vetraria (Firenze: Giunti, 1612).
[7] Sauzay, A. (1870) Marvels of Glassmaking in All Ages. London, 1870 pp. 173 - 175.

Art and Science

Jacopo Ligozzi,1518,  fanciful glass vessels,

ink and watercolor on paper.

Antonio Neri's writing on glassmaking and alchemy was distinguished from that of many contemporary authors in that his work was all deeply rooted in hands-on experience. He worked in the early 17th century, when art and science were different sides of the same endeavour to understand the world. His contemporaries were often content to repeat century's old teachings about the four Aristotelian elements; that chemical interactions could be explained through an analysis of the balance between hot and cold, dry and wet. But more and more, these notions were being discarded and replaced. It is common to cite the invention of instruments, and other technical developments; these factors certainly did contribute to advancement. But many different forces worked toward the emergence of early modern science, and one in particular is so obvious that it is easily overlooked: artists.

Working with hot glass was a profession in which attention to nature was essential: artists did not have the luxury of fanciful explanations of physical processes. They were obliged by their work to learn the ways glass mixed, moved and behaved in the furnace, not as they imagined it should, but as it actually did. The only way to achieve the complex forms and vessels for which master glassblowers were renowned was through long experience. Failure to understand the glass and predict its properties accurately resulted in failure of the piece.

Neri was immersed in this environment and the same principles applied to his own work in formulating the glass. Ancient theories had little value if they did not accurately predict nature. Like the glass artists, the way forward for Neri was careful attention and hands-on experience. He learned the value of starting with highly purified ingredients for his glass melts. He learned that too much glass salt resulted in a putrid 'gall' that would need to be skimmed off the molten surface. Substituting salts made from fern plants, for the Kali based ones from the Levant, produced a more lustrous glass, yet it stiffened more quickly for the glassblowers.

A glass artist's work also serves as a kind of narrative. For those familiar with the techniques, a finished piece of glass work can be 'read' like a story: The handles were put on last, before that, perhaps a thin bead of color was applied to the lip of the vessel. And the work started as a blown bubble of glass, shaped and opened with special tools. Each step is an insight into the artist's technique, but also into the way nature itself operates. Each motion was a well practiced negotiation between the artist and the properties of the material.

On one hand, an artist's job was to produce objects contemplated for their physical beauty and cultural significance. On the other hand, the act of producing these objects created an environment where accurate reasoning flourished. By collecting artists and employing them together, the Medici rulers of Tuscany were creating a cauldron effect where experiences collected, stewed and nature's secrets unraveled.

* This post first appeared here on 23 October 2013.

Sisters of an Alchemist

Portrait of the Egerton Sisters
(no relation to Neri)
English School,  c. 1601-1602

Among the ten children born to glassmaker Antonio Neri’s parents, three of them were girls; Lessandra, Maria, and Lucrezia. Because women were not allowed to legally own property, or sign contracts many of the usual sources of information are silent. Most of what we can learn about them is through their relationships with the men around them.

The Neri's were a patrician family, and the children enjoyed a very comfortable existence for the late sixteenth century. There is evidence that all three sisters survived into adulthood. Lessandra was the first-born, nine years older than Maria, and twelve years older than Lucrezia.

When Lessandra was around age seventeen, her famous father, Neri Neri, was appointed as personal physician to the newly crowned Grand Duke Ferdinando de’ Medici. However, only a few short years later their mother Dianora died at age 42, of causes that are unknown, perhaps childbirth. The girls were 22, 13 and 10. A few short years later they lost both their father, and a brother.

Two information sources for the Neri sisters are their birth records kept at the Opera del Duomo and genealogy records for the family which are filed at the National Archives, both in Florence. The baptism records hold a wealth of indirect material through the names of their godparents. While these do not tell us anything specific about them, it does tell us who their influences were; who they looked to for strength and spiritual guidance, under the circumstances, this is the best we can do.

Lessandra (b. 1572) claimed Baccio Valori as her godfather. The Valori family had a long, tragic history with the ruling Medici family. His father, grandfather and great-grandfather were all close Medici supporters, yet each ended up exiled, imprisoned, or executed after relationships soured. On one hand he was faithfully employed by the Medici, yet he reportedly spent a good deal of his time collecting letters and papers documenting his family’s close support of Girolamo Savonarola, the firebrand Dominican priest who lead Florence in the late 1490s, after the Medici had been temporarily expelled from the city.

Lessandra’s godmother was Marietta Gaetani, also from a noble family, which included dukes, cardinals and popes. They played prominent roles in the politics of Pisa, Rome and Naples for several centuries. Marietta’s father owned the house from whose tower Galileo showed the moons of Jupiter to Grand Duke Cosimo II in 1610.

The genealogical records imply that Lessandra later took vows with the S. Agata monastery on the North end of Florence and took the name suor Emilia.


Maria’s (b. 1581) godfather was Monsignor Giovanni Alberti. Giovanni was the son of a Florentine senator. He served as protonotary apostolic for Pope Gregory XIII and as bishop of Cortona under Pope Clement VIII. A godfather serving in the papal inner chambers was a good family contact indeed. Also appearing for Maria was Pierfilippo Perini, a physician and lawyer. The Registri lists Maria Neri's godmother as Alessandra di Girolamo Pepi. Among the prominent Florentine republicans was Alessandra's father, Girolamo. He was tortured by Alessandro de' Medici in the 1530s, upon the family's regaining control of Florence after the siege.The genealogy indicates that she married into the Boscoli family, but further work is needed to identify a specific individual.

Lucrezia (b. 1584), the youngest Neri girl, has a single godparent listed in the register, Montiglio degli Albizi. The Albizi family boasted powerful bankers and politicians. This was another case where deep divisions over Medici rule drove a family apart. Perhaps the best-recognized member of the Albizzi family was Eleonora degli Albizi. She was the young consort of grand duke Cosimo I. Folklore has it that in 1566, Cosimo intended to retire from public life and marry Albizi quietly, after the birth of a girl, but his regent son, Francesco I, forbade it to due to the inheritance complications that would ensue. The story is that Cosimo's long-time personal secretary, Sforza Almeni, leaked word of the clandestine marriage to the family. For his betrayal, an enraged Cosimo murdered Almeni in cold blood. Eleonora later gave birth to Don Giovanni de’ Medici, the uncle and friend of Don Antonio, Neri's sponsor. The specific Albizi family member we are interested in, Lucrezia's godfather, Montiglio degli Albizi, seems to have eluded history. Lucretia married into the Talenti family, but no further details are known.

Aventurine

Small amphora in aventurine glass,

Murano, Salviati.

With all its glitz and sparkle, aventurine (avventurina) stands out as a flamboyant extrovert among the varieties of glass that were developed and perfected on the Venetian island of Murano. Also known as 'goldstone', it consists of a transparent base glass with myriad reflective crystalline "spangles" running throughout. The classical version is a deep golden brown with crystallites composed mainly of metallic copper, with a few related compounds as supporting cast. However, numerous colors have been developed, including red, orange, yellow, green, blue, violet, black and white. 

Folklore holds that aventurine was discovered by accident ("a venturi") when unknown monks inadvertently dropped copper or brass shavings into a glass melt as early as the thirteenth century. [1] However, more thorough investigations have recently identified 1620 as a likely date for the first appearance of aventurine glass. [2] No example or written account has been found that dates prior to the seventeenth century. An alternate story accounts for the name aventurine being derived from 'adventure'; referring to the difficulty and uncertainty involved in its production.[3] At first, the formula was a closely held secret among a few glassmakers and subsequently it was lost and then rediscovered not once but  twice.

To complicate matters, natural minerals with a similar appearance were named after the glass, leading to the misconception that they were also discovered after the glass was invented. This is clearly not the case. Early examples of mineral aventurine artifacts date to the Neolithic era [4] and can be found throughout history. First century Roman writer Pliny mentions a type of stone with silvery flecks, a passage that was well known when the glass was developed.  The compositions of these minerals were also identified early; either species of quartz that contain flecks of mica, or a type of feldspar (sunstone).[5] Mineral aventurine turns up as the eyes of Greek statues, in stonework mosaics and later in the 'pietre dure' art perfected by the Medici artisans in Florence around the time Antonio Neri started making glass there. The chances are good that examples of the mineral were known to Neri as well as to the glassmakers on Murano, but a recipe for the glass version does not turn up in Neri’s 1612 book; he was apparently too early by a decade.  

The story of aventurine's accidental discovery by monks may well be apocryphal; nevertheless, it is a great entrée to understanding how the formulation works. First, contrary to what the story implies, aventurine is not the result of dumping metallic confetti into glass. The reflective "spangles" (as early researchers were fond of calling them) are actually uniformly sized, mirror-like crystals that are grown in the glass. In truth, the formula is quite similar to recipes already in use by Neri and others; the difference was in proportions and in how the glass was treated after it was in the furnace. The formula for aventurine calls for the addition of copper, iron and tin oxides, to a base that was a hybrid of soda, potash and lead glass. Neri’s recipe #128 is titled "A Proven Way to Make Rosichiero" [6] and provides for all of these ingredients, albeit in lower concentrations. Rosichiero was a transparent tawny red colored glass that was a staple of furnaces throughout Italy. 

The secret to producing the reflective "spangles" was to mix the glass and heat it in the furnace in a normal way, but then to slowly reduce the heat while creating a low oxygen “reducing” atmosphere. The furnace draught was shut; the glass pot was fitted with a tight lid and then covered with ashes and allowed to cool very slowly.  

Initially, the batch is saturated with copper oxide. This means the glass has dissolved as much copper, iron and tin as it can and any further addition of these powders will simply float to the bottom of the pot.  The exact amount of powdered metals able to dissolve is a function of temperature; the hotter the glass the more that will dissolve and the cooler the glass the less that will dissolve. The key concept here is that as the glass slowly cools, the metals start to come out of solution and crystals start to form. There is some complex chemistry happening at the same time; the reducing atmosphere encourage the metals to stay in a pure un-oxidized form,  Furthermore any oxygen or sulfur  that happens to be present will preferentially combine with the iron, leaving the copper crystals pristine. Once cooled to room temperature, a successful batch would be broken away from the glass pot by workers and divided into smaller pieces. Glass artisans wanting to incorporate the aventurine into their work needed to work quickly. They carefully reheated an appropriate nugget and coated (encase) it in a layer of clear glass; once molten, direct exposure to the air would destroy the glittery effect. 

Over time, it was discovered that various colors could be produced with the addition of different chemicals, but the central principal of growing tiny metallic crystals is the same.


[1]  The earliest instance of this story in print that I can find is fairly late;  Faustino Corsi, Delle pietre antiche: libri quattro (Rome: Salviuccio e figlio, 1828)  pp. 166-167.  
[2] Cesare Moretti (†), Bernard Gratuze and Sandro Hreglich,  “Le verre aventurine (‘ avventurina ‘) : son histoire, les recettes, les analyses, sa fabrication”, ArcheoSciences, 37 | 2013, 135-154.
[3] For instance see  Giulio Salviati, “Venetian Glass” Journal of the Society of Arts (Proceedings), Volume 37 (7 June,1889), p. 630
[4] Neolithic Quartz Aventurine Pendant - 7 Cm/ 2. 76 ", green - 6500 To 2000 Bp – Sahara. Item Id: 106549,  Weight: 83 gm. Sahara - Mauritania - Tagant country.
http://ancientpoint.com/inf/106549-neolithic_quartz_aventurine_pendant___7_cm_2___76____6500_to_2000_bp___sahara.html
[5] Dizionario del cittadino, o sia Ristretto storico, teorico e ..., Volume 1 pp. 38-39.
[6] Antonio Neri, L'Arte Vetraria (Firenze: Giunti, 1612).
[7] Sauzay, A. (1870) Marvels of Glassmaking in All Ages. London, 1870 pp. 173 - 175.

Antonio Neri?

Medallion dedicated to Antonio Neri,

19th cent.(?), Artist unknown.

La Specola (Museum of natural history),

Florence, Italy.

Since there are many new readers of this blog, I thought a short primer might be in order. Posts here are all related in some way to a seventeenth century Italian priest named Antonio Neri. Occasionally the connection is tenuous, but always in the spirit of exploring his work and times as he experienced them. The blog is named Conciatore, which was a term used in sixteenth and seventeenth century Florence, Italy to describe specialists who formulated glass. Until very recently, our star, conciatore Antonio Neri, was known almost exclusively as the enigmatic author of the first printed book devoted to making glass from raw materials. 

The book's original title in 1612 was L'Arte Vetraria, [1] which translates to "the art of glassmaking," although, in 1662 Neri’s first translator, English Physician Christopher Merrett, chose to simplify the title to The Art of Glass. [2] The book would spread throughout Europe and became a bible of glassmaking for two centuries. Neri's original Italian was translated, retranslated and even plagiarized.[3] Over two dozen editions were published before 1900 in English, Latin, French, German Spanish and more recently in Japanese.[4]

There are manuscripts, papyrus scrolls and even cuneiform tablets that contain glass recipes far older than Neri's book. However he was the first into print, and perhaps more significant, his book was specifically devoted to the common man, stating in his introduction that the only qualification necessary to make glass successfully was the possession of a "kind and curious spirit." In a time when trade secrets were closely guarded assets, Neri assures his readers that, "given a bit of experience and practice, as long as you do not purposely foul-up, it will be impossible to fail," (provided, of course that one had access to the raw materials, a glass furnace and tools).

In his English translation, Merrett stated that he had tried and failed to find out anything whatsoever about the author. A mystique grew around Neri and his identity. He was a Catholic Priest and an alchemist. Stories endure to this day that he had been chased out of Florence over the secret to transmutation; changing base metals into gold and silver. While we now know that transmutation is not possible through ordinary chemistry, the story of his harassment does apparently have a basis in fact. 

Some historians felt such a minor character with few achievements to his name was not worthy of serious study and that is the way things stood for a very long time. More recently, careful research into contemporary records, manuscripts and letters has gone a long way to revealing Neri as a quite interesting character. At the beginning of his career, he worked for Medici prince Don Antonio at his palace-laboratory on the north side of Florence. After a couple of years, he moved to Pisa and lent a hand at a secondary Medici glass facility. A bundle of letters has survived from his friend in Antwerp, Emmanuel Ximenes. [5] Ximenes turns out to have been one of the wealthiest men in Flanders. After corresponding for a few years, Neri traveled to visit Ximenes and stayed for seven years, making some of the "best glass of his life." Finally, he returned to Florence and settled down to write his famous book. 

Far from the poor itinerant priest supposed by some, Neri turns out to be from a prominent patrician family. His father was the personal physician to Grand Duke Ferdinando de' Medici. His grandfather was a well-respected barber-surgeon and a close friend of poet Lodovico Domenici. His other grandfather (on his mother’s side) was Michelangelo's lawyer. Credible evidence in the Florentine State Archives supports the family's claim to being a distant cousin to Saint Philip Neri. [6]

He had nine siblings, three sisters and six brothers, although one brother died as an infant and another at age sixteen. The Neri children enjoyed a cadre of godparents that included the archbishop of Florence and members of the papal curia. The family went on to produce more physicians, and even marry into the Medici family before a lack of male heirs caused this branch of the Neri's to go extinct.

Over his lifetime, he is known to have written a dozen manuscripts,[7] many but not all of which are now lost.[8] He became a dedicated Paracelsan and thousands of pages of his experimental work survive today in the notebooks of his assistant Agnolo della Casa. In the final couple of years of his life, Antonio left glassmaking behind to devote his full attention to wider pursuits in chemistry and medicine. These were disciplines he had practiced his entire life. In 1614, he died at the age of thirty-eight. His long time sponsor Don Antonio de' Medici launched a full-scale investigation to find the late priest's recipe for the philosopher's stone, which he had been promised. Neri's friends and associates were interviewed and the Medici prince even went as far as consulting a medium in Venice to make contact with Neri in the afterlife, alas to no avail.[9]

Neri is an interesting character in his own right, but he also provides an excellent platform to explore alchemy in the early seventeenth century. He was a dedicated experimentalist in his work, which gave him a foothold in the coming revolution of our understanding of the natural world. He lived and worked at the same time Galileo tutored the future grand duke in Florence. The astronomer had himself been tutored in mathematics in the Cestello monastery on Borgo Pinti, in sight of the Neri household. The attached church is where Neri’s family attended services and where his father was buried. Galileo later supplied a copy of L'Arte Vetraria to Federico Cesi, founder of the Accademia dei Lincei, one of the first naturalist and 'scientific' societies in Europe.[10]

If you have an interest in the cultural and technical environment that led to our current understanding of chemistry, medicine and more, I urge you to join me here where we regularly strive to catch a glimpse of early modern science through one of its minor characters; glassmaker, alchemist and Catholic priest Antonio Neri. 

[1] Neri 1612, Neri 2003–07. 
[2] Neri 1662.
[3] Neri 1697.
[4] Neri 2007.
[4] Zecchin 1987–89.
[5] ASF 599.
[6] Boer, Engle 2010.
[8] Grazzini 2012.
[9] Galluzzi 1982.

[10] Galileo 1890–1909.

* These references all appear in the "bibliography" page linked on the right

Art and Science

Jacopo Ligozzi,1518,  fanciful glass vessels,

ink and watercolor on paper.

Antonio Neri's writing on glassmaking and alchemy was distinguished from that of many contemporary authors in that his work was all deeply rooted in hands-on experience. He worked in the early 17th century, when art and science were different sides of the same endeavour to understand the world. His contemporaries were often content to repeat century's old teachings about the four Aristotelian elements; that chemical interactions could be explained through an analysis of the balance between hot and cold, dry and wet. But more and more, these notions were being discarded and replaced. It is common to cite the invention of instruments, and other technical developments; these factors certainly did contribute to advancement. But many different forces worked toward the emergence of early modern science, and one in particular is so obvious that it is easily overlooked: artists.

Working with hot glass was a profession in which attention to nature was essential: artists did not have the luxury of fanciful explanations of physical processes. They were obliged by their work to learn the ways glass mixed, moved and behaved in the furnace, not as they imagined it should, but as it actually did. The only way to achieve the complex forms and vessels for which master glassblowers were renowned was through long experience. Failure to understand the glass and predict its properties accurately resulted in failure of the piece.

Neri was immersed in this environment and the same principles applied to his own work in formulating the glass. Ancient theories had little value if they did not accurately predict nature. Like the glass artists, the way forward for Neri was careful attention and hands-on experience. He learned the value of starting with highly purified ingredients for his glass melts. He learned that too much glass salt resulted in a putrid 'gall' that would need to be skimmed off the molten surface. Substituting salts made from fern plants, for the Kali based ones from the Levant, produced a more lustrous glass, yet it stiffened more quickly for the glassblowers.

A glass artist's work also serves as a kind of narrative. For those familiar with the techniques, a finished piece of glass work can be 'read' like a story: The handles were put on last, before that, perhaps a thin bead of color was applied to the lip of the vessel. And the work started as a blown bubble of glass, shaped and opened with special tools. Each step is an insight into the artist's technique, but also into the way nature itself operates. Each motion was a well practiced negotiation between the artist and the properties of the material.

On one hand, an artist's job was to produce objects contemplated for their physical beauty and cultural significance. On the other hand, the act of producing these objects created an environment where accurate reasoning flourished. By collecting artists and employing them together, the Medici rulers of Tuscany were creating a cauldron effect where experiences collected, stewed and nature's secrets unraveled.

* This post first appeared here on 23 October 2013.

Sisters of an Alchemist

Portrait of the Egerton Sisters
(no relation to Neri)
English School,  c. 1601-1602

Among the ten children born to glassmaker Antonio Neri’s parents, three of them were girls; Lessandra, Maria, and Lucrezia. Because women were not allowed to legally own property, or sign contracts many of the usual sources of information are silent. Most of what we can learn about them is through their relationships with the men around them.

The Neri's were a patrician family, and the children enjoyed a very comfortable existence for the late sixteenth century. There is evidence that all three sisters survived into adulthood. Lessandra was the first-born, nine years older than Maria, and twelve years older than Lucrezia.

When Lessandra was around age seventeen, her famous father, Neri Neri, was appointed as personal physician to the newly crowned Grand Duke Ferdinando de’ Medici. However, only a few short years later their mother Dianora died at age 42, of causes that are unknown, perhaps childbirth. The girls were 22, 13 and 10. A few short years later they lost both their father, and a brother.

Two information sources for the Neri sisters are their birth records kept at the Opera del Duomo and genealogy records for the family which are filed at the National Archives, both in Florence. The baptism records hold a wealth of indirect material through the names of their godparents. While these do not tell us anything specific about them, it does tell us who their influences were; who they looked to for strength and spiritual guidance, under the circumstances, this is the best we can do.

Lessandra (b. 1572) claimed Baccio Valori as her godfather. The Valori family had a long, tragic history with the ruling Medici family. His father, grandfather and great-grandfather were all close Medici supporters, yet each ended up exiled, imprisoned, or executed after relationships soured. On one hand he was faithfully employed by the Medici, yet he reportedly spent a good deal of his time collecting letters and papers documenting his family’s close support of Girolamo Savonarola, the firebrand Dominican priest who lead Florence in the late 1490s, after the Medici had been temporarily expelled from the city.

Lessandra’s godmother was Marietta Gaetani, also from a noble family, which included dukes, cardinals and popes. They played prominent roles in the politics of Pisa, Rome and Naples for several centuries. Marietta’s father owned the house from whose tower Galileo showed the moons of Jupiter to Grand Duke Cosimo II in 1610.

The genealogical records imply that Lessandra later took vows with the S. Agata monastery on the North end of Florence and took the name suor Emilia.


Maria’s (b. 1581) godfather was Monsignor Giovanni Alberti. Giovanni was the son of a Florentine senator. He served as protonotary apostolic for Pope Gregory XIII and as bishop of Cortona under Pope Clement VIII. A godfather serving in the papal inner chambers was a good family contact indeed. Also appearing for Maria was Pierfilippo Perini, a physician and lawyer. The Registri lists Maria Neri's godmother as Alessandra di Girolamo Pepi. Among the prominent Florentine republicans was Alessandra's father, Girolamo. He was tortured by Alessandro de' Medici in the 1530s, upon the family's regaining control of Florence after the siege.The genealogy indicates that she married into the Boscoli family, but further work is needed to identify a specific individual.

Lucrezia (b. 1584), the youngest Neri girl, has a single godparent listed in the register, Montiglio degli Albizi. The Albizi family boasted powerful bankers and politicians. This was another case where deep divisions over Medici rule drove a family apart. Perhaps the best-recognized member of the Albizzi family was Eleonora degli Albizi. She was the young consort of grand duke Cosimo I. Folklore has it that in 1566, Cosimo intended to retire from public life and marry Albizi quietly, after the birth of a girl, but his regent son, Francesco I, forbade it to due to the inheritance complications that would ensue. The story is that Cosimo's long-time personal secretary, Sforza Almeni, leaked word of the clandestine marriage to the family. For his betrayal, an enraged Cosimo murdered Almeni in cold blood. Eleonora later gave birth to Don Giovanni de’ Medici, the uncle and friend of Don Antonio, Neri's sponsor. The specific Albizi family member we are interested in, Lucrezia's godfather, Montiglio degli Albizi, seems to have eluded history. Lucretia married into the Talenti family, but no further details are known.

2018 Bead Symposium Lecture

Aventurine

Small amphora in aventurine glass ”,

Murano, Salviati.

With all its glitz and sparkle, aventurine (avventurina) stands out as a flamboyant extrovert among the varieties of glass that were developed and perfected on the Venetian island of Murano. Also known as 'goldstone', it consists of a transparent base glass with myriad reflective crystalline "spangles" running throughout. The classical version is a deep golden brown with crystallites composed mainly of metallic copper, with a few related compounds as supporting cast. However, numerous colors have been developed, including red, orange, yellow, green, blue, violet, black and white. 

Folklore holds that aventurine was discovered by accident ("a venturi") when unknown monks inadvertently dropped copper or brass shavings into a glass melt as early as the thirteenth century. [1] However, more thorough investigations have recently identified 1620 as a likely date for the first appearance of aventurine glass. [2] No example or written account has been found that dates prior to the seventeenth century. An alternate story accounts for the name aventurine being derived from 'adventure'; referring to the difficulty and uncertainty involved in its production.[3] At first, the formula was a closely held secret among a few glassmakers and subsequently it was lost and then rediscovered not once but  twice.

To complicate matters, natural minerals with a similar appearance were named after the glass, leading to the misconception that they were also discovered after the glass was invented. This is clearly not the case. Early examples of mineral aventurine artifacts date to the Neolithic era [4] and can be found throughout history. First century Roman writer Pliny mentions a type of stone with silvery flecks, a passage that was well known when the glass was developed.  The compositions of these minerals were also identified early; either species of quartz that contain flecks of mica, or a type of feldspar (sunstone).[5] Mineral aventurine turns up as the eyes of Greek statues, in stonework mosaics and later in the 'pietre dure' art perfected by the Medici artisans in Florence around the time Antonio Neri started making glass there. The chances are good that examples of the mineral were known to Neri as well as to the glassmakers on Murano, but a recipe for the glass version does not turn up in Neri’s 1612 book; he was apparently too early by a decade.  

The story of aventurine's accidental discovery by monks may well be apocryphal; nevertheless, it is a great entrée to understanding how the formulation works. First, contrary to what the story implies, aventurine is not the result of dumping metallic confetti into glass. The reflective "spangles" (as early researchers were fond of calling them) are actually uniformly sized, mirror-like crystals that are grown in the glass. In truth, the formula is quite similar to recipes already in use by Neri and others; the difference was in proportions and in how the glass was treated after it was in the furnace. The formula for aventurine calls for the addition of copper, iron and tin oxides, to a base that was a hybrid of soda, potash and lead glass. Neri’s recipe #128 is titled "A Proven Way to Make Rosichiero" [6] and provides for all of these ingredients, albeit in lower concentrations. Rosichiero was a transparent tawny red colored glass that was a staple of furnaces throughout Italy. 

The secret to producing the reflective "spangles" was to mix the glass and heat it in the furnace in a normal way, but then to slowly reduce the heat while creating a low oxygen “reducing” atmosphere. The furnace draught was shut; the glass pot was fitted with a tight lid and then covered with ashes and allowed to cool very slowly.  

Initially, the batch is saturated with copper oxide. This means the glass has dissolved as much copper, iron and tin as it can and any further addition of these powders will simply float to the bottom of the pot.  The exact amount of powdered metals able to dissolve is a function of temperature; the hotter the glass the more that will dissolve and the cooler the glass the less that will dissolve. The key concept here is that as the glass slowly cools, the metals start to come out of solution and crystals start to form. There is some complex chemistry happening at the same time; the reducing atmosphere encourage the metals to stay in a pure un-oxidized form,  Furthermore any oxygen or sulfur  that happens to be present will preferentially combine with the iron, leaving the copper crystals pristine. Once cooled to room temperature, a successful batch would be broken away from the glass pot by workers and divided into smaller pieces. Glass artisans wanting to incorporate the aventurine into their work needed to work quickly. They carefully reheated an appropriate nugget and coated (encase) it in a layer of clear glass; once molten, direct exposure to the air would destroy the glittery effect. 

Over time, it was discovered that various colors could be produced with the addition of different chemicals, but the central principal of growing tiny metallic crystals is the same.


[1]  The earliest instance of this story in print that I can find is fairly late;  Faustino Corsi, Delle pietre antiche: libri quattro (Rome: Salviuccio e figlio, 1828)  pp. 166-167.  
[2] Cesare Moretti (†), Bernard Gratuze and Sandro Hreglich,  “Le verre aventurine (‘ avventurina ‘) : son histoire, les recettes, les analyses, sa fabrication”, ArcheoSciences, 37 | 2013, 135-154.
[3] For instance see  Giulio Salviati, “Venetian Glass” Journal of the Society of Arts (Proceedings), Volume 37 (7 June,1889), p. 630
[4] Neolithic Quartz Aventurine Pendant - 7 Cm/ 2. 76 ", green - 6500 To 2000 Bp – Sahara. Item Id: 106549,  Weight: 83 gm. Sahara - Mauritania - Tagant country.
http://ancientpoint.com/inf/106549-neolithic_quartz_aventurine_pendant___7_cm_2___76____6500_to_2000_bp___sahara.html
[5] Dizionario del cittadino, o sia Ristretto storico, teorico e ..., Volume 1 pp. 38-39.
[6] Antonio Neri, L'Arte Vetraria (Firenze: Giunti, 1612).
[7] Sauzay, A. (1870) Marvels of Glassmaking in All Ages. London, 1870 pp. 173 - 175.