Showing posts with label Galileo. Show all posts
Showing posts with label Galileo. Show all posts

Wednesday, February 3, 2021

Alchemist Cardinal

 

Portrait of Francesco Maria del Monte
Ottavio Leoni (1578–1630)
In the early seventeenth century, Cardinal Francesco Maria del Monte served as the unofficial Florentine cultural ambassador in Rome. He regularly entertained visiting dignitaries and represented the Medici family's interests within the Vatican. He was an avid art collector, glass enthusiast and amateur alchemist.  He was a patron to the artist Caravaggio, to the astronomer Galileo and a dear friend to Antonio Neri's employer Don Antonio de' Medici.

The strong bond of affection between Don Antonio and Cardinal Del Monte is clear from their extensive correspondence and gifts to each other.  In addition to their passion for alchemy, the two shared a strong interest in glassmaking technology. There is a chance that the cardinal met glassmaker Antonio Neri in Florence; in 1602 he visited the Casino di San Marco, where the glass foundry was located and he returned in 1608, although by then Neri was in Antwerp. Del Monte's biographer Zygmunt Waźbiński offers, "It is very likely that Cardinal Del Monte, with his interest in glass, had known then (in 1598) the [future] author [Neri] of L'Arte Vetraria." [1]

Del Monte collaborated with Niccolò Sisti, the grand duke's glass foundry master at Pisa, where Neri also worked for a time. Sisti often provided Del Monte with glassware for Medici customers within the College of Cardinals in Rome. The cardinal's patronage also brought many glassmakers in Rome to the appreciation of the papal court.  After his death, Del Monte's will shows that at his main residence, the Palazzo Madama, he maintained an entire room, "gabinetto dei vetri" [cabinet of glasswork] that housed five hundred pieces of glassware. It cannot go without mention that he was also the proud owner of what has become one of most celebrated pieces of ancient glass, now referred to as the Portland Vase.

There are indications in Neri's 1600 manuscript that he visited Rome. If so, it is hard to imagine him not seeking an audience with the cardinal, either at his villa on the Pincio,  overlooking the city or at the Palazzo Madama, now offices of the Italian Senate. The palazzo was appointed in fabulous luxury and arranged to accommodate a constant flow of dignitaries from around the world. The villa, on the other hand, was where the cardinal's alchemy laboratory was located. This was a more secluded retreat where the cardinal could entertain guests with more discretion.
   
Michelangelo Caravaggio, c. 1597
Casino Ludovisi.
As the sixteenth century ended and a new one dawned, Del Monte sheltered the rough-and-tumble painter Michelangelo Caravaggio, whom he set up with an in-house studio and an allowance. However, in 1606, the master of Realism fled Rome after reportedly murdering a tavern waiter over a tennis wager, but not before executing his only known fresco on the vaulted ceiling of Del Monte's own alchemy laboratory. Looking out over Rome, on the panoramic Pincio, in the Villa that later became the Casino Ludovisi and is now known as the Casino dell'Aurora, Caravaggio put his brush to work. 

According to Gian Pietro Bellori, the early biographer of artists, Caravaggio executed the oil painting sometime between 1597 and 1600. [2] Depicted in the mural are the three brothers Jupiter, Neptune and Pluto: the masters of the universe. The image is a double allegory of the three basic chemical substances of Paracelsus (salt sulfur and mercury) and the four Aristotelian elements (air, earth, water and fire). Jupiter with the eagle stands for sulfur and air, Neptune with the seahorse stands for mercury and water and Pluto with the three-headed dog Cerberus stands for salt and earth. Jupiter is reaching out to move the central celestial sphere in which the sun (fire) revolves around the earth. [3] 


The villa was a relatively secluded retreat where the Cardinal could entertain guests discretely, including his friend Galileo–Del Monte and his older brother Guidobaldo helped land Galileo the chair of mathematics at the university in Pisa. This is also where Galileo demonstrated his telescope for interested dignitaries in Rome. It would be interesting to hear the astronomer’s comments on Caravaggio's tribute to heliocentrism.

[1] Neri 1612.
[2] Bellori 1672, pp. 197-216.
[3] Wallach 1975, pp. 101-112.

*The material in this post first appeared in a different form on  27 Nov. 2013 and 4 Jul. 2014.

Wednesday, January 20, 2021

Eyes of a Lynx

 

The seal of the Accademia dei Lincei.
In the spring of 1612, Florentine priest Antonio Neri published his book on glassmaking. L'Arte Vetraria was the first printed book devoted to the formulation of glass from raw materials, but unfortunately for him it did not exactly take the world by storm, at least not at first. Sales were such that a number of copies still exist from the initial printing; they remain in pristine condition, never bound. 

Initially, the book received scant attention, but it was noticed. In fact, within a couple of years word had reached Rome, where Prince Federico Cesi, the founder of a scientific society, asked a Pisan member of his group to obtain a copy. That other member would go on to become one of the most recognized scientists in history. Meanwhile, L'Arte Vetraria gained prestige and readers, slowly but steadily.  By the end of the century, Neri’s book would be translated into English, Latin, German, French and then back into English from the French. It became the bible of glassmakers throughout Europe. 

In 1614, the year of Antonio Neri's death, naturalist Prince Federico Cesi wrote to his good friend Galileo. He complained of the difficulties in getting material from the Roman libraries, urging the astronomer to send him a copy of Antonio Neri's book.
The poor management of these libraries in Rome makes me feel continually thirsty for good books that come to light, which I can use for my study of compositions. They are scarcely giving me the titles, and after a long wait, only a tenth of what I asked. […] now I hear that printed in Florence is L'Arte Vetraria by Priest Antonio Neri, and I think there is some good in it. Please, your lordship, send me a copy, and believe me that I will gladly give them trouble.
 Shortly after, having received the book the prince wrote,
I thank your lordship for the book on glass, which I find very rich in experiments and beautiful artistry.
In 1603, Cesi founded the Accademia dei Lincei (Society of the Lynxes), an early scientific society whose members (with eyes as sharp as a lynx's) eventually included both Galileo Galilei and Giambattista della Porta.[1] Within a few months of Neri's death, his book was already on its way to making history.

[1] In classical Greek mythology Lynceus was the grandson of Perseus, and had preternaturally keen eyesight. See Apollodorus, Bibliotheke I, viii, 2 & ix, 16; III, x, 3 & ix, 2.

* This post first appeared here in a shorter form on 1 August 2013.

Friday, January 8, 2021

Reflections on the Mirror

 

Jan van Eyck
The Arnolfini Portrait (1434)
L’Arte Vetraria, Antonio Neri's 1612 book, would eventually become the glassmakers' bible throughout Europe. By 1900 it had been translated into five different languages besides the original Italian; English, Latin, German, French, and Spanish (and in this century Japanese). Because of its seminal importance in the spread of glass technology, often overlooked are a few recipes at the back of the book, which have only a tenuous connection to the main subject.

Among these is a metallurgical formula for making convex mirrors. Neri gives instructions for producing what we would now call a "white bronze" that may be cast into a rounded form and polished to take on a highly reflective surface finish. This "spherical" form of mirror was popular throughout the Renaissance. It reflected a wide-angle view of the space in which it was hung, but at the cost of distorting the image. Nevertheless, upon looking into such a mirror, objects are still quite recognizable. 

Here is Neri's prescription:
A Mixture to Make [Mirror] Spheres:
Have 3 lbs of well-purified tin, and 1 lb of copper also purified. Melt these two metals, first the copper, then the tin. When they fuse thoroughly, throw onto them 6 oz of just singed red wine tartar, and 1½ oz of saltpeter, then ¼ oz of alum, and 2 oz of arsenic. Leave these all to vaporize, and then cast [the metal] into the form of a sphere. You will have good material, which when you burnish and polish, will look most fine. This mixture is called acciaio and is used to make spherical mirrors.
Of note is the fact that the word Neri uses for this alloy, acciaio, translates to "steel." Over the intervening four centuries, the meaning of this term has been refined so that today it denotes not simply a hard white metal, but a specific range of alloys containing iron and carbon, which Neri's alloy does not. 

This recipe and a few others in the book show the breadth of Neri's experience in arts other than glassmaking. It is a conclusion greatly amplified by a perusal of his other manuscripts on alchemy and medicine. There is good evidence that our priest was a voracious reader, however he was also quite cautious about repeating techniques only after he had verified them personally. Besides, artisans never wrote down much of this knowledge – only passed in confidence between trusted parties – since, in a very concrete way, superior knowledge represented a competitive advantage over ones rivals. Even if Neri was in the business of divulging secrets, it is safe to assume that many of the artisans and craftsmen he interacted with were decidedly not. Apparently, Neri was not familiar with the process of mirroring glass directly with mercury/tin amalgam; a process for which Venetian glassmakers had already become famous for perfecting. It is an interesting omission from his book, since he almost certainly would have seen examples in Florence and in Antwerp.

Two centuries before Neri, the beginning of the fifteenth century saw the invention of moveable type printing in Germany, but also the mastery of perspective illustration in Italy. The contribution of printing to early modern science is well documented, less obvious is the role playerd by artists and perspective illustration. Moveable type made possible the mass production of books; what did get committed to paper now stood a much better chance of survival and transmission. Perspective illustration played a more nuanced role, one that ultimately brings the convex mirror back into the discussion.
Jan van Eyck
The Arnolfini Portrait (detail).

In Venice and especially in Florence (Neri's hometown), perspective drawing became the rage among artists, largely due to the Italian translation of a book entitled Deli Aspecti, or "Alhazen's Book of Optics." Suddenly, paintings were made to look three-dimensional, with a realistic sense of depth to them. The new techniques were largely kept in Italy, but interest spread across Europe. Patrons placed great value on work depicting scenes in correct perspective, and in excruciatingly accurate detail. 


In Flanders, in 1434, Jan van Eyck produced "The Arnolfini Portrait," (above). Behind the main subjects, hanging on the wall is a convex mirror. The reflection in the mirror shows the backs of the two subjects, but also two other figures further back, one of which is thought to be the artist himself, and beyond him a strong light source. The image in the mirror is distorted exactly as one would experience in real life. 

There is growing speculation that among the secrets of "realist" (or naturalist) painters was a growing arsenal of optical tools and lenses used to map out and understand the attributes of perspective. The mirror, in the Arnolfini Portrait was a sort of boast of the artist's proficiency in recreating reality on the canvas.

The point is that here is a case where art led science into new realms. Painters started to take great pains in reproducing reality "as it is" on canvas. Soon minor experimenters like Neri and major luminaries like Galileo were taking great pains to do the same. They strove to observe nature "as it is," not as was prescribed in ancient texts, or dictated by authority. Once that process started, awareness of the world grew and there was no turning back.

Finally, it is amusing to note that in his many manuscript illustrations, Antonio Neri himself never quite mastered perspective drawing, although he did try.

* This post first appeared here 17 January 2014.

Friday, November 20, 2020

Torricelli and Glass


Evangelista Torricelli
by Lorenzo Lippi, circa 1647
Evangelista Torricelli (1608–1647) is remembered as the inventor of the mercury barometer. Lesser known are a number of significant contributions he made to mathematics, astronomy and physics. There is no direct connection to the Florentine alchemist and glassmaker Antonio Neri—Torricelli was only a boy of six when Neri died—yet there are unmistakable echoes left by Neri that are amplified when we examine Torricelli’s time in Florence.   

In 1632, Torricelli wrote a letter to Galileo, which began a friendship that lasted until the famous astronomer died a decade later. In fact, Galileo invited Torricelli to stay at his house where they spent the last three months of Galileo’s life working together. If Torricelli had not heard of Neri before, perhaps he became acquainted through the copy of his book, L’Arte Vetraria that Galileo had on his bookshelf. Afterward, while preparing to return to Rome, Torricelli was intercepted by the Grand Duke of Tuscany, Ferdinando II de' Medici, who asked him to succeed Galileo as the chair of mathematics at Pisa. He was given a good salary and quarters at the fabulous palace in the center of Florence, that is now called the Medici-Riccardi.  

Historian Mario Gliozzi writes: “Torricelli remained in Florence until his death; these years, the happiest of his life, were filled with the greatest scientific activity. Esteemed for his polished, brilliant, and witty conversation, he soon formed friendships with the outstanding representatives of Florentine culture.” [1]  The ancient palace itself was largely empty in this period, inhabited by a handful of relatives, officials, intellectuals and artists connected with the Grand Ducal court. [2]

Among Torricelli’s companions at the palace were the three sons of Don Antonio de’ Medici, Antonio Neri’s long time benefactor. The boys, Paolo (1616-1656), Giulio (1617-1670) and Antonfrancesco (1618-1659) moved there in 1646. None of the brothers had personally met Neri, as they were all born shortly after his death, but they must have heard plenty about him growing up. As children, they had the run of the Casino di San Marco, the palace where Neri had made glass and pursued the secrets of alchemy. After Neri’s death, their father, Don Antonio spent significant time trying to hunt down Neri’s secret recipe for transmutation. Years later, when Giulio died in 1670, among his possessions were found a box of elixirs and “a booklet, entitled: Material of all the compounds of Priest Antonio Neri; there is a red dustcover, which says ‘experiments.’” [3] The materials were handed over to Jacinto Talducci, the Grand Duke’s chief chemist, and master of the new glassworks established in the Boboli Gardens, a man whom Torricelli depended on for glass. Talducci was also a veteran of the Casino di San Marco Laboratory; according to legend, as a boy he personally witnessed Neri’s transmutation of gold. Curiously, at Giulio’s death he was listed as living on Borgo Pinti in Florence, the same street on which Antonio Neri grew up. Also the same street where Galileo was tutored in  mathematics as a boy -- at the monastery where Neri's family attended church.

While in Florence, Torricelli took a great interest in optics. Again quoting Gliozzi:
[T]here is very good evidence of his technical ability in working telescope lenses, a skill almost certainly acquired during his stay in Florence. By the autumn of 1642 he was already capable of making lenses that were in no way mediocre, although they did not attain the excellence of those made by Francesco Fontana, at that time the most renowned Italian telescope maker. Torricelli had set out to emulate and surpass Fontana. By 1643 he was already able to obtain lenses equal to Fontana’s or perhaps even better, but above all he had come to understand that what is really important for the efficiency of a lens is the perfectly spherical machining of the surface, which he carried out with refined techniques. The efficiency of Torricelli’s lenses was recognized by the grand duke, who in 1644 presented Torricelli with a gold necklace bearing a medal with the motto “Virtutis praemia.” 
The fame of Torricelli’s excellent lenses quickly became widespread and he received many requests, which he fulfilled at a good profit. He attributed the efficiency of telescopes fitted with his lenses to a machining process that was kept secret at the time but was described in certain papers passed at Torricelli’s death to the grand duke, who gave them to Viviani, after which they were lost.
Gliozzi continues to describe that in 1924 one of Torricelli’s lenses was examined optically using the diffraction grating. “It was found to be of exquisite workmanship, so much so that one face was seen to have been machined better than the mirror taken as reference surface, and was constructed with the most advanced technique of the period.”

In addition to precision glass for lenses, Torricelli depended on Talducci and the grand duke’s furnace for scientific glassware; his experiments that demonstrated the measurement of air pressure required glass tubes, sealed at one end, two ‘cubits’ long (about four feet). They needed to be strong enough to be filled with mercury (which is very heavy) without breaking. It took his colleague Mersenne a couple of years (until 1646) to match the Florentines and obtain an acceptable tube from the French glassworks. 

Torricelli worked with former employees of the Casino di San Marco laboratory who knew Neri, he lived with Don Antonio’s three sons and he took a keen interest in glass; it seems impossible for him to be unaware of Neri and the echoes of his work in Florence.

[1] Mario Gliozzi "Torricelli, Evangelista" in Complete Dictionary of Scientific Biography. 2008. Encyclopedia.com.  http://www.encyclopedia.com/doc/1G2-2830904345.html

[2] 1609-1659 - The last inhabitants of Palazzo Medici http://www.palazzo-medici.it/mediateca/en/Scheda_1609-1659_-_Ultimi_abitanti_di_Palazzo_Medici_

[3] Covoni 1892, p. 193.

Monday, September 7, 2020

1600s Glass Furnace

 

From "De re metallica" 
Agricola (Georg Bauer) 1556.
In the seventeenth century, glass furnaces represented a pinnacle of technology. True, the ability to achieve the high temperatures required to melt glass had been around for centuries – high enough to melt gold, silver and copper as well. What made the glass furnace remarkable was its refinement. It made efficient use of its hardwood fuel and was able to maintain a controlled, even temperature long before any thermometer could measure it. In fact, in the early seventeenth century, Galileo was only just beginning to use glass bulbs and tubes to measure differences in ambient room temperatures.

In Florence, the construction used was typical of the time throughout Europe, called a "beehive" furnace because its shape resembled the classic elongated dome of a beehive. A double wall, built of fire resistant bricks, provided further insulation, trapping heat inside. Vertically, the furnace was divided into three levels, each forming a wide open chamber. The bottom space was used to build the fire, and had one or two openings to the outside, used to add wood fuel, rake the coals, or shovel out ash. The second, central level was where the pots of glass resided. A central hole or "eye" on the floor directly exposed the fire pit below. The space directly next to the eye was the hottest, and temperature could be further controlled by moving the crucibles farther away or closer to the eye. A number of openings in the wall allowed gaffers access to the glass pots, and at least one larger opening was used to place new crucibles, or rearrange the existing ones. The upper chamber was used to control the draft, and sometimes for annealing. Again, a central hole in the floor of this (top) level allowed exhaust gasses to leave the glass chamber and an opening to one side vented the exhaust.

In his 1612 book, L’Arte Vetraria, Neri is careful to stress that only dry oak or other hardwood should be used because it burns cleanly, and will not deposit ash or creosote in the glass.
The furnace should have dry wood, hard wood of oak because soft wood tinges the furnace and does no good. Stoke it steadily and continuously so that the flame is always clear, and there is never any smoke, which is very important in order to make a beautiful cristallo.
Once a finished piece of glassware is made, it must be allowed to cool slowly, over a period of many hours. This was often accomplished by building a long enclosed horizontal trough that connected to the furnace. A draft opening at the far end allowed heat from the furnace to be drawn in, and finished pieces were placed in a pan at the furnace end and then slowly pulled by a chain further and further down the trough toward the cooler end. This "annealing" process ensured the glass would not develop stresses and crack as it cooled.

Although Neri does not concern himself with the vagaries of furnace construction in the book, it is clear that he did possess considerable knowledge on the subject. Several of his unconventional methods for making pigments for glass involve taking bricks out of the furnace wall to stash chemicals for long term exposure to the heat.
Take small pieces of copper and put them inside the arches of the furnace. In that place, they will be within the walls. Leave them that way until each piece of copper is well calcined, using a simple fire.
While it is true that artisans of the early seventeenth century did not possess the same understanding of nature that we now enjoy, they did have a working knowledge that served them very well. It was backed by a theoretical framework that was quite sophisticated and was consistent with what could be observed and measured at the time. This is no different from our own modern understanding of nature: sophisticated and consistent with what we can observe and measure.

*This post first appeared here 24 January 2014

Friday, August 7, 2020

The Man Who Liked Books Too Much

Broadway Tower, Worcestershire.
The home of Phillipps' Middle Hill Press
In 1612, Antonio Neri published his famous book on glassmaking, L'Arte Vetraria. [1] The venture was bankrolled by Medici prince Don Antonio for whom Neri had worked as an alchemist and glassmaker in 1601 and possibly a couple of years earlier. The printer was Giunti, the venerated Florentine family of typographers who set up their first press in Venice a century and a half earlier. In Neri's era, they operated as the de facto press for the grand dukes in Florence and they are still in business today.

Neri's book was noticed almost immediately; in a 1614 letter addressed to Galileo, Roman Prince Federico Cesi practically begged his astronomer friend to send a copy. [2] Cesi was the founder of the "Accademia dei Lincei" [Society of Lynxes] a group of naturalists who formed an early version of what would later be called 'scientific societies.' The book was tailor made for such groups who were interested in performing their own experiments, however, sales did not exactly catch fire among the public. 

A few decades later, another scientific society was formed in London, with a charter signed by no less than King Charles II. The Royal Society really gave Neri's book a major boost when in 1662; founding member Robert Boyle commissioned Christopher Merrett to translate the work into English. [3] A year earlier, a second edition had been printed in Florence and a year later, another Italian edition appeared in Venice. [4]

From there, the book took off, sprouting multiple new translations in the Netherlands, Germany, France and Spain. There are many interesting stories of how the book spread across Europe; one of the most fascinating deals not with the book itself but with a publisher. Without any doubt, Sir Thomas Phillipps was the most colorful of any of Neri's printers. In 1826, Phillipps' press issued a reprint of Merrett's original English translation, which was by then over a century and a half old. [5]

By the 19th century, L'Arte Vetraria, or "The Art of Glass" as it was dubbed in English, had passed its prime as the bible of glassmakers. As one would expect, methods and technology had matured considerably over the intervening two centuries. Nevertheless, Phillipps recognized its importance. He was also a bit eccentric. As a child, by his sixth birthday, he already owned over a hundred books; his grand ambition was to own one copy of every book ever printed, a quest he carried into adulthood. He was born in Manchester, the product of a clandestine relationship between a textile baron and a woman other than the one to whom his father was married. Nevertheless, he appears to have been well cared for and inherited what Wikipedia reports was a "substantial estate." [6] A fortune that he promptly started to whittle away, spending lavishly on books and manuscripts. He attended University College Oxford and within a few years, he was made a fellow of the above-mentioned Royal Society. 

Depending on where you stand, Phillipps was a classic example of British eccentricity, a brilliant and dedicated preservationist or a completely obsessed crazy-man. Possibly all three. By the end of his life, he had amassed an estimated sixty thousand manuscripts and forty thousand books. At the time it was the largest such private collection in the world. He housed his treasure in a castle that he had built for the purpose, Broadway Tower, in Worcestershire (see photo above). It is said that he would walk into various bookstores and buy the entire stock; his agents around Europe provided a steady stream of new material. Apparently, he himself possessed a sense of humor about his odd obsession, coining the term "vello-maniac" (referring to the vellum bindings common to many books of that period).

The story does have a darker side, albeit with a silver lining. In 1842, Phillipps started collaborating in research with James Halliwell, then an undergraduate at Cambridge studying Shakespeare. Halliwell became romantically involved with Phillipps eldest daughter Harriett, but Phillipps refused consent for them to marry (which they did anyway). Meanwhile, Phillipps had run through the family fortune and started to borrow heavily. He developed paranoia against Halliwell and vowed that he would never gain control of the collection. He entered negotiations to donate the books and manuscripts to the British Library, but his conditions were unpalatable and a deal was never reached. He wanted to stipulate that the order of books should never be reshuffled and that no Roman Catholic, especially his son-in-law, ever be permitted to touch or view the collection. He became so fearful  about Halliwell that he hired 250 men to move the collection, which took two years, at which point the abandoned castle started to fall into ruins. 

In the end, Phillipps died at the age of 79 in 1872. After a court decision, Harriett did inherit her father's collection and Halliwell did gain control. The silver lining is that the two undertook to carefully disperse the collection to some of the most prestigious libraries in Europe. This project took multiple generations to finish. In fact, the final parcel of books from the Phillipps collection sold at auction in 2006, at Christie's.

[1] Neri 1612.
[2] Cesi 1614a, 1614b.
[3] Neri 1662.
[4] Neri 1661, Neri 1663.
[5] Neri 1826.
[6] "Thomas Phillipps" Wikipedia, http://en.wikipedia.org/wiki/Thomas_Phillipps 
* This post first appeared here on 5 Oct 2014.

Monday, June 8, 2020

Reflections on the Mirror

Jan van Eyck
The Arnolfini Portrait (1434)
L’Arte Vetraria, Antonio Neri's 1612 book, would eventually become the glassmakers' bible throughout Europe. By 1900 it had been translated into five different languages besides the original Italian; English, Latin, German, French, and Spanish (and in this century Japanese). Because of its seminal importance in the spread of glass technology, often overlooked are a few recipes at the back of the book, which have only a tenuous connection to the main subject.

Among these is a metallurgical formula for making convex mirrors. Neri gives instructions for producing what we would now call a "white bronze" that may be cast into a rounded form and polished to take on a highly reflective surface finish. This "spherical" form of mirror was popular throughout the Renaissance. It reflected a wide-angle view of the space in which it was hung, but at the cost of distorting the image. Nevertheless, upon looking into such a mirror, objects are still quite recognizable. 

Here is Neri's prescription:
A Mixture to Make [Mirror] Spheres:
Have 3 lbs of well-purified tin, and 1 lb of copper also purified. Melt these two metals, first the copper, then the tin. When they fuse thoroughly, throw onto them 6 oz of just singed red wine tartar, and 1½ oz of saltpeter, then ¼ oz of alum, and 2 oz of arsenic. Leave these all to vaporize, and then cast [the metal] into the form of a sphere. You will have good material, which when you burnish and polish, will look most fine. This mixture is called acciaio and is used to make spherical mirrors.
Of note is the fact that the word Neri uses for this alloy, acciaio, translates to "steel." Over the intervening four centuries, the meaning of this term has been refined so that today it denotes not simply a hard white metal, but a specific range of alloys containing iron and carbon, which Neri's alloy does not. 

This recipe and a few others in the book show the breadth of Neri's experience in arts other than glassmaking. It is a conclusion greatly amplified by a perusal of his other manuscripts on alchemy and medicine. There is good evidence that our priest was a voracious reader, however he was also quite cautious about repeating techniques only after he had verified them personally. Besides, artisans never wrote down much of this knowledge – only passed in confidence between trusted parties – since, in a very concrete way, superior knowledge represented a competitive advantage over ones rivals. Even if Neri was in the business of divulging secrets, it is safe to assume that many of the artisans and craftsmen he interacted with were decidedly not. Apparently, Neri was not familiar with the process of mirroring glass directly with mercury/tin amalgam; a process for which Venetian glassmakers had already become famous for perfecting. It is an interesting omission from his book, since he almost certainly would have seen examples in Florence and in Antwerp.

Two centuries before Neri, the beginning of the fifteenth century saw the invention of moveable type printing in Germany, but also the mastery of perspective illustration in Italy. The contribution of printing to early modern science is well documented, less obvious is the role playerd by artists and perspective illustration. Moveable type made possible the mass production of books; what did get committed to paper now stood a much better chance of survival and transmission. Perspective illustration played a more nuanced role, one that ultimately brings the convex mirror back into the discussion.
Jan van Eyck
The Arnolfini Portrait (detail).

In Venice and especially in Florence (Neri's hometown), perspective drawing became the rage among artists, largely due to the Italian translation of a book entitled Deli Aspecti, or "Alhazen's Book of Optics." Suddenly, paintings were made to look three-dimensional, with a realistic sense of depth to them. The new techniques were largely kept in Italy, but interest spread across Europe. Patrons placed great value on work depicting scenes in correct perspective, and in excruciatingly accurate detail. 


In Flanders, in 1434, Jan van Eyck produced "The Arnolfini Portrait," (above). Behind the main subjects, hanging on the wall is a convex mirror. The reflection in the mirror shows the backs of the two subjects, but also two other figures further back, one of which is thought to be the artist himself, and beyond him a strong light source. The image in the mirror is distorted exactly as one would experience in real life. 

There is growing speculation that among the secrets of "realist" (or naturalist) painters was a growing arsenal of optical tools and lenses used to map out and understand the attributes of perspective. The mirror, in the Arnolfini Portrait was a sort of boast of the artist's proficiency in recreating reality on the canvas.

The point is that here is a case where art led science into new realms. Painters started to take great pains in reproducing reality "as it is" on canvas. Soon minor experimenters like Neri and major luminaries like Galileo were taking great pains to do the same. They strove to observe nature "as it is," not as was prescribed in ancient texts, or dictated by authority. Once that process started, awareness of the world grew and there was no turning back.

Finally, it is amusing to note that in his many manuscript illustrations, Antonio Neri himself never quite mastered perspective drawing, although he did try.

* This post first appeared here 17 January 2014.

Friday, April 3, 2020

Eyes of a Lynx

The seal of the Accademia dei Lincei.
In the spring of 1612, Florentine priest Antonio Neri published his book on glassmaking. L'Arte Vetraria was the first printed book devoted to the formulation of glass from raw materials, but unfortunately for him it did not exactly take the world by storm, at least not at first. Sales were such that a number of copies still exist from the initial printing; they remain in pristine condition, never bound. 

Initially, the book received scant attention, but it was noticed. In fact, within a couple of years word had reached Rome, where Prince Federico Cesi, the founder of a scientific society, asked a Pisan member of his group to obtain a copy. That other member would go on to become one of the most recognized scientists in history. Meanwhile, L'Arte Vetraria gained prestige and readers, slowly but steadily.  By the end of the century, Neri’s book would be translated into English, Latin, German, French and then back into English from the French. It became the bible of glassmakers throughout Europe. 

In 1614, the year of Antonio Neri's death, naturalist Prince Federico Cesi wrote to his good friend Galileo. He complained of the difficulties in getting material from the Roman libraries, urging the astronomer to send him a copy of Antonio Neri's book.
The poor management of these libraries in Rome makes me feel continually thirsty for good books that come to light, which I can use for my study of compositions. They are scarcely giving me the titles, and after a long wait, only a tenth of what I asked. […] now I hear that printed in Florence is L'Arte Vetraria by Priest Antonio Neri, and I think there is some good in it. Please, your lordship, send me a copy, and believe me that I will gladly give them trouble.
 Shortly after, having received the book the prince wrote,
I thank your lordship for the book on glass, which I find very rich in experiments and beautiful artistry.
In 1603, Cesi founded the Accademia dei Lincei (Society of the Lynxes), an early scientific society whose members (with eyes as sharp as a lynx's) eventually included both Galileo Galilei and Giambattista della Porta.[1] Within a few months of Neri's death, his book was already on its way to making history.

[1] In classical Greek mythology Lynceus was the grandson of Perseus, and had preternaturally keen eyesight. See Apollodorus, Bibliotheke I, viii, 2 & ix, 16; III, x, 3 & ix, 2.

* This post first appeared here in a shorter form on 1 August 2013.

Wednesday, February 26, 2020

Early Modern Glass Furnace

From "De re metallica" 
Agricola (Georg Bauer) 1556.
In the seventeenth century, glass furnaces represented a pinnacle of technology. True, the ability to achieve the high temperatures required to melt glass had been around for centuries – high enough to melt gold, silver and copper as well. What made the glass furnace remarkable was its refinement. It made efficient use of its hardwood fuel and was able to maintain a controlled, even temperature long before any thermometer could measure it. In fact, in the early seventeenth century, Galileo was only just beginning to use glass bulbs and tubes to measure differences in ambient room temperatures.

In Florence, the construction used was typical of the time throughout Europe, called a "beehive" furnace because its shape resembled the classic elongated dome of a beehive. A double wall, built of fire resistant bricks, provided further insulation, trapping heat inside. Vertically, the furnace was divided into three levels, each forming a wide open chamber. The bottom space was used to build the fire, and had one or two openings to the outside, used to add wood fuel, rake the coals, or shovel out ash. The second, central level was where the pots of glass resided. A central hole or "eye" on the floor directly exposed the fire pit below. The space directly next to the eye was the hottest, and temperature could be further controlled by moving the crucibles farther away or closer to the eye. A number of openings in the wall allowed gaffers access to the glass pots, and at least one larger opening was used to place new crucibles, or rearrange the existing ones. The upper chamber was used to control the draft, and sometimes for annealing. Again, a central hole in the floor of this (top) level allowed exhaust gasses to leave the glass chamber and an opening to one side vented the exhaust.

In his 1612 book, L’Arte Vetraria, Neri is careful to stress that only dry oak or other hardwood should be used because it burns cleanly, and will not deposit ash or creosote in the glass.
The furnace should have dry wood, hard wood of oak because soft wood tinges the furnace and does no good. Stoke it steadily and continuously so that the flame is always clear, and there is never any smoke, which is very important in order to make a beautiful cristallo.
Once a finished piece of glassware is made, it must be allowed to cool slowly, over a period of many hours. This was often accomplished by building a long enclosed horizontal trough that connected to the furnace. A draft opening at the far end allowed heat from the furnace to be drawn in, and finished pieces were placed in a pan at the furnace end and then slowly pulled by a chain further and further down the trough toward the cooler end. This "annealing" process ensured the glass would not develop stresses and crack as it cooled.

Although Neri does not concern himself with the vagaries of furnace construction in the book, it is clear that he did possess considerable knowledge on the subject. Several of his unconventional methods for making pigments for glass involve taking bricks out of the furnace wall to stash chemicals for long term exposure to the heat.
Take small pieces of copper and put them inside the arches of the furnace. In that place, they will be within the walls. Leave them that way until each piece of copper is well calcined, using a simple fire.
While it is true that artisans of the early seventeenth century did not possess the same understanding of nature that we now enjoy, they did have a working knowledge that served them very well. It was backed by a theoretical framework that was quite sophisticated and was consistent with what could be observed and measured at the time. This is no different from our own modern understanding of nature: sophisticated and consistent with what we can observe and measure.

*This post first appeared here 24 January 2014

Friday, February 14, 2020

Torricelli and Glass

Evangelista Torricelli
by Lorenzo Lippi, circa 1647
Evangelista Torricelli (1608–1647) is remembered as the inventor of the mercury barometer. Lesser known are a number of significant contributions he made to mathematics, astronomy and physics. There is no direct connection to the Florentine alchemist and glassmaker Antonio Neri—Torricelli was only a boy of six when Neri died—yet there are unmistakable echoes left by Neri that are amplified when we examine Torricelli’s time in Florence.   

In 1632, Torricelli wrote a letter to Galileo, which began a friendship that lasted until the famous astronomer died a decade later. In fact, Galileo invited Torricelli to stay at his house where they spent the last three months of Galileo’s life working together. If Torricelli had not heard of Neri before, perhaps he became acquainted through the copy of his book, L’Arte Vetraria that Galileo had on his bookshelf. Afterward, while preparing to return to Rome, Torricelli was intercepted by the Grand Duke of Tuscany, Ferdinando II de' Medici, who asked him to succeed Galileo as the chair of mathematics at Pisa. He was given a good salary and quarters at the fabulous palace in the center of Florence, that is now called the Medici-Riccardi.  

Historian Mario Gliozzi writes: “Torricelli remained in Florence until his death; these years, the happiest of his life, were filled with the greatest scientific activity. Esteemed for his polished, brilliant, and witty conversation, he soon formed friendships with the outstanding representatives of Florentine culture.” [1]  The ancient palace itself was largely empty in this period, inhabited by a handful of relatives, officials, intellectuals and artists connected with the Grand Ducal court. [2]

Among Torricelli’s companions at the palace were the three sons of Don Antonio de’ Medici, Antonio Neri’s long time benefactor. The boys, Paolo (1616-1656), Giulio (1617-1670) and Antonfrancesco (1618-1659) moved there in 1646. None of the brothers had personally met Neri, as they were all born shortly after his death, but they must have heard plenty about him growing up. As children, they had the run of the Casino di San Marco, the palace where Neri had made glass and pursued the secrets of alchemy. After Neri’s death, their father, Don Antonio spent significant time trying to hunt down Neri’s secret recipe for transmutation. Years later, when Giulio died in 1670, among his possessions were found a box of elixirs and “a booklet, entitled: Material of all the compounds of Priest Antonio Neri; there is a red dustcover, which says ‘experiments.’” [3] The materials were handed over to Jacinto Talducci, the Grand Duke’s chief chemist, and master of the new glassworks established in the Boboli Gardens, a man whom Torricelli depended on for glass. Talducci was also a veteran of the Casino di San Marco Laboratory; according to legend, as a boy he personally witnessed Neri’s transmutation of gold. Curiously, at Giulio’s death he was listed as living on Borgo Pinti in Florence, the same street on which Antonio Neri grew up. Also the same street where Galileo was tutored in  mathematics as a boy -- at the monastery where Neri's family attended church.

While in Florence, Torricelli took a great interest in optics. Again quoting Gliozzi:
[T]here is very good evidence of his technical ability in working telescope lenses, a skill almost certainly acquired during his stay in Florence. By the autumn of 1642 he was already capable of making lenses that were in no way mediocre, although they did not attain the excellence of those made by Francesco Fontana, at that time the most renowned Italian telescope maker. Torricelli had set out to emulate and surpass Fontana. By 1643 he was already able to obtain lenses equal to Fontana’s or perhaps even better, but above all he had come to understand that what is really important for the efficiency of a lens is the perfectly spherical machining of the surface, which he carried out with refined techniques. The efficiency of Torricelli’s lenses was recognized by the grand duke, who in 1644 presented Torricelli with a gold necklace bearing a medal with the motto “Virtutis praemia.” 
The fame of Torricelli’s excellent lenses quickly became widespread and he received many requests, which he fulfilled at a good profit. He attributed the efficiency of telescopes fitted with his lenses to a machining process that was kept secret at the time but was described in certain papers passed at Torricelli’s death to the grand duke, who gave them to Viviani, after which they were lost.
Gliozzi continues to describe that in 1924 one of Torricelli’s lenses was examined optically using the diffraction grating. “It was found to be of exquisite workmanship, so much so that one face was seen to have been machined better than the mirror taken as reference surface, and was constructed with the most advanced technique of the period.”

In addition to precision glass for lenses, Torricelli depended on Talducci and the grand duke’s furnace for scientific glassware; his experiments that demonstrated the measurement of air pressure required glass tubes, sealed at one end, two ‘cubits’ long (about four feet). They needed to be strong enough to be filled with mercury (which is very heavy) without breaking. It took his colleague Mersenne a couple of years (until 1646) to match the Florentines and obtain an acceptable tube from the French glassworks. 

Torricelli worked with former employees of the Casino di San Marco laboratory who knew Neri, he lived with Don Antonio’s three sons and he took a keen interest in glass; it seems impossible for him to be unaware of Neri and the echoes of his work in Florence.

[1] Mario Gliozzi "Torricelli, Evangelista" in Complete Dictionary of Scientific Biography. 2008. Encyclopedia.com.  http://www.encyclopedia.com/doc/1G2-2830904345.html

[2] 1609-1659 - The last inhabitants of Palazzo Medici http://www.palazzo-medici.it/mediateca/en/Scheda_1609-1659_-_Ultimi_abitanti_di_Palazzo_Medici_

[3] Covoni 1892, p. 193.

Friday, January 10, 2020

Eyes of a Lynx

The seal of the Accademia dei Lincei.
In the spring of 1612, Florentine priest Antonio Neri published his book on glassmaking. L'Arte Vetraria was the first printed book devoted to the formulation of glass from raw materials, but unfortunately for him it did not exactly take the world by storm, at least not at first. Sales were such that a number of copies still exist from the initial printing; they remain in pristine condition, never bound. 

Initially, the book received scant attention, but it was noticed. In fact, within a couple of years word had reached Rome, where Prince Federico Cesi, the founder of a scientific society, asked a Pisan member of his group to obtain a copy. That other member would go on to become one of the most recognized scientists in history. Meanwhile, L'Arte Vetraria gained prestige and readers, slowly but steadily.  By the end of the century, Neri’s book would be translated into English, Latin, German, French and then back into English from the French. It became the bible of glassmakers throughout Europe. 

In 1614, the year of Antonio Neri's death, naturalist Prince Federico Cesi wrote to his good friend Galileo. He complained of the difficulties in getting material from the Roman libraries, urging the astronomer to send him a copy of Antonio Neri's book.
The poor management of these libraries in Rome makes me feel continually thirsty for good books that come to light, which I can use for my study of compositions. They are scarcely giving me the titles, and after a long wait, only a tenth of what I asked. […] now I hear that printed in Florence is L'Arte Vetraria by Priest Antonio Neri, and I think there is some good in it. Please, your lordship, send me a copy, and believe me that I will gladly give them trouble.
 Shortly after, having received the book the prince wrote,
I thank your lordship for the book on glass, which I find very rich in experiments and beautiful artistry.
In 1603, Cesi founded the Accademia dei Lincei (Society of the Lynxes), an early scientific society whose members (with eyes as sharp as a lynx's) eventually included both Galileo Galilei and Giambattista della Porta.[1] Within a few months of Neri's death, his book was already on its way to making history.

[1] In classical Greek mythology Lynceus was the grandson of Perseus, and had preternaturally keen eyesight. See Apollodorus, Bibliotheke I, viii, 2 ; ix, 16; III, x, 3; ix, 2.

* This post first appeared here in a shorter form on 1 August 2013.

Friday, October 4, 2019

Reflections on the Mirror

Jan van Eyck
The Arnolfini Portrait (1434)
L’Arte Vetraria, Antonio Neri's 1612 book, would eventually become the glassmakers' bible throughout Europe. By 1900 it had been translated into five different languages besides the original Italian; English, Latin, German, French, and Spanish (and in this century Japanese). Because of its seminal importance in the spread of glass technology, often overlooked are a few recipes at the back of the book, which have only a tenuous connection to the main subject.

Among these is a metallurgical formula for making convex mirrors. Neri gives instructions for producing what we would now call a "white bronze" that may be cast into a rounded form and polished to take on a highly reflective surface finish. This "spherical" form of mirror was popular throughout the Renaissance. It reflected a wide-angle view of the space in which it was hung, but at the cost of distorting the image. Nevertheless, upon looking into such a mirror, objects are still quite recognizable. 

Here is Neri's prescription:
A Mixture to Make [Mirror] Spheres:
Have 3 lbs of well-purified tin, and 1 lb of copper also purified. Melt these two metals, first the copper, then the tin. When they fuse thoroughly, throw onto them 6 oz of just singed red wine tartar, and 1½ oz of saltpeter, then ¼ oz of alum, and 2 oz of arsenic. Leave these all to vaporize, and then cast [the metal] into the form of a sphere. You will have good material, which when you burnish and polish, will look most fine. This mixture is called acciaio and is used to make spherical mirrors.
Of note is the fact that the word Neri uses for this alloy, acciaio, translates to "steel." Over the intervening four centuries, the meaning of this term has been refined so that today it denotes not simply a hard white metal, but a specific range of alloys containing iron and carbon, which Neri's alloy does not. 

This recipe and a few others in the book show the breadth of Neri's experience in arts other than glassmaking. It is a conclusion greatly amplified by a perusal of his other manuscripts on alchemy and medicine. There is good evidence that our priest was a voracious reader, however he was also quite cautious about repeating techniques only after he had verified them personally. Besides, artisans never wrote down much of this knowledge – only passed in confidence between trusted parties – since, in a very concrete way, superior knowledge represented a competitive advantage over ones rivals. Even if Neri was in the business of divulging secrets, it is safe to assume that many of the artisans and craftsmen he interacted with were decidedly not. Apparently, Neri was not familiar with the process of mirroring glass directly with mercury/tin amalgam; a process for which Venetian glassmakers had already become famous for perfecting. It is an interesting omission from his book, since he almost certainly would have seen examples in Florence and in Antwerp.

Two centuries before Neri, the beginning of the fifteenth century saw the invention of moveable type printing in Germany, but also the mastery of perspective illustration in Italy. The contribution of printing to early modern science is well documented, less obvious is the role playerd by artists and perspective illustration. Moveable type made possible the mass production of books; what did get committed to paper now stood a much better chance of survival and transmission. Perspective illustration played a more nuanced role, one that ultimately brings the convex mirror back into the discussion.
Jan van Eyck
The Arnolfini Portrait (detail).

In Venice and especially in Florence (Neri's hometown), perspective drawing became the rage among artists, largely due to the Italian translation of a book entitled Deli Aspecti, or "Alhazen's Book of Optics." Suddenly, paintings were made to look three-dimensional, with a realistic sense of depth to them. The new techniques were largely kept in Italy, but interest spread across Europe. Patrons placed great value on work depicting scenes in correct perspective, and in excruciatingly accurate detail. 


In Flanders, in 1434, Jan van Eyck produced "The Arnolfini Portrait," (above). Behind the main subjects, hanging on the wall is a convex mirror. The reflection in the mirror shows the backs of the two subjects, but also two other figures further back, one of which is thought to be the artist himself, and beyond him a strong light source. The image in the mirror is distorted exactly as one would experience in real life. 

There is growing speculation that among the secrets of "realist" (or naturalist) painters was a growing arsenal of optical tools and lenses used to map out and understand the attributes of perspective. The mirror, in the Arnolfini Portrait was a sort of boast of the artist's proficiency in recreating reality on the canvas.

The point is that here is a case where art led science into new realms. Painters started to take great pains in reproducing reality "as it is" on canvas. Soon minor experimenters like Neri and major luminaries like Galileo were taking great pains to do the same. They strove to observe nature "as it is," not as was prescribed in ancient texts, or dictated by authority. Once that process started, awareness of the world grew and there was no turning back.

Finally, it is amusing to note that in his many manuscript illustrations, Antonio Neri himself never quite mastered perspective drawing, although he did try.

* This post first appeared here 17 January 2014.

Monday, August 5, 2019

1600s Glass Furnace

From "De re metallica" 
Agricola (Georg Bauer) 1556.
In the seventeenth century, glass furnaces represented a pinnacle of technology. True, the ability to achieve the high temperatures required to melt glass had been around for centuries – high enough to melt gold, silver and copper as well. What made the glass furnace remarkable was its refinement. It made efficient use of its hardwood fuel and was able to maintain a controlled, even temperature long before any thermometer could measure it. In fact, in the early seventeenth century, Galileo was only just beginning to use glass bulbs and tubes to measure differences in ambient room temperatures.

In Florence, the construction used was typical of the time throughout Europe, called a "beehive" furnace because its shape resembled the classic elongated dome of a beehive. A double wall, built of fire resistant bricks, provided further insulation, trapping heat inside. Vertically, the furnace was divided into three levels, each forming a wide open chamber. The bottom space was used to build the fire, and had one or two openings to the outside, used to add wood fuel, rake the coals, or shovel out ash. The second, central level was where the pots of glass resided. A central hole or "eye" on the floor directly exposed the fire pit below. The space directly next to the eye was the hottest, and temperature could be further controlled by moving the crucibles farther away or closer to the eye. A number of openings in the wall allowed gaffers access to the glass pots, and at least one larger opening was used to place new crucibles, or rearrange the existing ones. The upper chamber was used to control the draft, and sometimes for annealing. Again, a central hole in the floor of this (top) level allowed exhaust gasses to leave the glass chamber and an opening to one side vented the exhaust.

In his 1612 book, L’Arte Vetraria, Neri is careful to stress that only dry oak or other hardwood should be used because it burns cleanly, and will not deposit ash or creosote in the glass.
The furnace should have dry wood, hard wood of oak because soft wood tinges the furnace and does no good. Stoke it steadily and continuously so that the flame is always clear, and there is never any smoke, which is very important in order to make a beautiful cristallo.
Once a finished piece of glassware is made, it must be allowed to cool slowly, over a period of many hours. This was often accomplished by building a long enclosed horizontal trough that connected to the furnace. A draft opening at the far end allowed heat from the furnace to be drawn in, and finished pieces were placed in a pan at the furnace end and then slowly pulled by a chain further and further down the trough toward the cooler end. This "annealing" process ensured the glass would not develop stresses and crack as it cooled.

Although Neri does not concern himself with the vagaries of furnace construction in the book, it is clear that he did possess considerable knowledge on the subject. Several of his unconventional methods for making pigments for glass involve taking bricks out of the furnace wall to stash chemicals for long term exposure to the heat.
Take small pieces of copper and put them inside the arches of the furnace. In that place, they will be within the walls. Leave them that way until each piece of copper is well calcined, using a simple fire.
While it is true that artisans of the early seventeenth century did not possess the same understanding of nature that we now enjoy, they did have a working knowledge that served them very well. It was backed by a theoretical framework that was quite sophisticated and was consistent with what could be observed and measured at the time. This is no different from our own modern understanding of nature: sophisticated and consistent with what we can observe and measure.

*This post first appeared here 24 January 2014