Zaffer

Antique Apothecary jars,

cobalt blue glass.

As best as I can remember, the first time that I really noticed glass was at four or five years old, at my grandmother's house in Queens, New York. The sunlight filtering through a low window caught my eye with a brilliant blue glint through a small cobalt glass bottle.  My grandmother held it up to the light for me and I was enchanted; transported into a realm of exquisite pure color.

Little did I know that the spell cast on me at such a young age had been cast on Egyptian pharaohs of the eighteenth dynasty and on Persian princesses, two thousands years ago, by their cobalt glass jewelry. In all three cases, the deep rich blue of cobalt oxide glass was responsible. Today, the source of ancient Middle Eastern cobalt is unknown, possibly West Africa, but more recently, in the Renaissance; it was mined in Hungary, in Bohemia and in German Saxony, where it was called "zaffer," after its sapphire color.

Legend tells that sixteenth century silver miners in Germany amassed a hoard of smaltite thinking it was silver ore. When they tried to smelt it, the arsenic which cobalt ores always have, evolved highly toxic fumes that made them sick. Discouraged and maligned, they said the product of their labors was cursed by goblins; they named it "kobald" (cobalt) after the evil spirits. The theme of 'evil spirits' (toxic fumes) was common in mining circles. A mythology persisted from ancient times up until the eighteenth century that divided the spirits into two groups; mischievous, and malevolent. The mischievous spirits played tricks on the miner's perception and equipment, the malevolent spirits could stop a man dead in his tracks, literally. 

Regardless of the difficulties both terestrial and otherwise, a strong market developed for the newly found "kobald" among artists for paint, potters for glazes, and glassmakers. The Saxon miners gained a reputation for producing the finest zaffer.

In his glassmaking book L'Arte Vetraria, Antonio Neri describes his method for purifying and preparing zaffer for use in glass. It is a recipe that would stand the test of time, still quoted by authors into the nineteenth and twentieth century.

To Prepare Zaffer, Which Serves for Many Colors in the Art of Glassmaking

You should get zaffer in large pieces and put it in earthenware oven-pans holding it in the furnace chamber for half a day. Then put it into iron ladles to inflame it in the furnace. Heat it well, then take and sprinkle it with strong vinegar. When cold, grind it finely over a porphyry stone into glazed earthen pots with hot water. Then wash more water over it always leaving the zaffer to settle in the bottom.

Now gently decant, to carry away the sediment and impurities of the zaffer. The good part and pigment of the zaffer will remain in the bottom. The pigment remains are now prepared and purified to be far better than it was at first, which will make clear and limpid pigment. This zaffer should be dried and kept in sealed vessels for use, which will be much improved over the original.

Until the mid 1700s zaffer had been associated with silver and copper mines, and was commonly thought to be a derivative of copper. It was Swedish chemist Georg Brandt who finally isolated the new metal, and gave it the name which honors the miners and the subterranean spirits which still can cast a spell on us through its deep pure blue color in glass.

* This post first appeared here in a slightly different form on 4 April 2014.

Zaffer

Antique Apothecary jars,

cobalt blue glass.

As best as I can remember, the first time that I really noticed glass was at four or five years old, at my grandmother's house in Queens, New York. The sunlight filtering through a low window caught my eye with a brilliant blue glint through a small cobalt glass bottle.  My grandmother held it up to the light for me and I was enchanted; transported into a realm of exquisite pure color.

Little did I know that the spell cast on me at such a young age had been cast on Egyptian pharaohs of the eighteenth dynasty and on Persian princesses, two thousands years ago, by their cobalt glass jewelry. In all three cases, the deep rich blue of cobalt oxide glass was responsible. Today, the source of ancient Middle Eastern cobalt is unknown, possibly West Africa, but more recently, in the Renaissance; it was mined in Hungary, in Bohemia and in German Saxony, where it was called "zaffer," after its sapphire color.

Legend tells that sixteenth century silver miners in Germany amassed a hoard of smaltite thinking it was silver ore. When they tried to smelt it, the arsenic which cobalt ores always have, evolved highly toxic fumes that made them sick. Discouraged and maligned, they said the product of their labors was cursed by goblins; they named it "kobald" (cobalt) after the evil spirits. The theme of 'evil spirits' (toxic fumes) was common in mining circles. A mythology persisted from ancient times up until the eighteenth century that divided the spirits into two groups; mischievous, and malevolent. The mischievous spirits played tricks on the miner's perception and equipment, the malevolent spirits could stop a man dead in his tracks, literally. 

Regardless of the difficulties both terestrial and otherwise, a strong market developed for the newly found "kobald" among artists for paint, potters for glazes, and glassmakers. The Saxon miners gained a reputation for producing the finest zaffer.

In his glassmaking book L'Arte Vetraria, Antonio Neri describes his method for purifying and preparing zaffer for use in glass. It is a recipe that would stand the test of time, still quoted by authors into the nineteenth and twentieth century.

To Prepare Zaffer, Which Serves for Many Colors in the Art of Glassmaking

You should get zaffer in large pieces and put it in earthenware oven-pans holding it in the furnace chamber for half a day. Then put it into iron ladles to inflame it in the furnace. Heat it well, then take and sprinkle it with strong vinegar. When cold, grind it finely over a porphyry stone into glazed earthen pots with hot water. Then wash more water over it always leaving the zaffer to settle in the bottom.

Now gently decant, to carry away the sediment and impurities of the zaffer. The good part and pigment of the zaffer will remain in the bottom. The pigment remains are now prepared and purified to be far better than it was at first, which will make clear and limpid pigment. This zaffer should be dried and kept in sealed vessels for use, which will be much improved over the original.

Until the mid 1700s zaffer had been associated with silver and copper mines, and was commonly thought to be a derivative of copper. It was Swedish chemist Georg Brandt who finally isolated the new metal, and gave it the name which honors the miners and the subterranean spirits which still can cast a spell on us through its deep pure blue color in glass.

* This post first appeared here in a slightly different form on 4 April 2014.

Black is Beautiful

Black glass cameo vase, c. 1900

Thomas Webb.

Antonio Neri was a technical adept, a student of alchemical history and a glassmaker extraordinaire. He was also a gear in the early 17th century Medici innovation machine. The glass recipes he developed were likely put to work in the glass shops sponsored by the ruling family in Florence, Pisa and elsewhere. Making advances in technology gave the region a competitive advantage; encouraging the arts cemented a reputation for creativity that endures to this day throughout Tuscany.

Black is one color that has given glassmakers difficulty ever since the material's invention over four thousand years ago. It is easily approximated for large, heavy objects, but to achieve a true solid black in blown vessels, or thin layers is a challenge even for current technology.

Obsidian is a naturally occurring volcanic glass that was prized in antiquity, most often occurring in black or very dark brown. In prehistoric times, it was coveted for cutting tools and arrowheads. As technology advanced, it was ground and polished for mirrors. Later, obsidian became popular in ornamental objects ranging from dinner plates to jewelry. The production of obsidian, gemstones and other natural materials through artificial means was a quest that kept glassmakers busy.

In many ways, making black glass shows the other side of challenges in making colorless crystal; instead of a formulation that will transmit virtually all the light falling on it, the aim is to produce a glass that will absorb virtually all illumination. In his book, L' Arte Vetraria, Neri presents three recipes for "velvet black" glass (# 51-53), and three recipes for black enamel (#100-102).

His first black glass is made with the discarded broken pieces of "glass of many colors." To this, he adds 'zaffer,' a cobalt ore used to produce deep dark blue, and manganese, which produces a magenta color. He advises that it will be good for bead making cane and other work. For his second black glass, he starts with high quality frit to which he adds lead and tin oxides. This forms an opaque, white lead crystal, which he tints with calcined "steel" (probably bronze) and pulverized iron flake. He claims that after twelve hours "the glass will be a most beautiful velvety black." Neri's ultimate black glass is his simplest. He starts with his 'rocchetta' frit, and adds the dried, pulverized dregs left in red wine casks, advising us to go slowly since it froths up. He allows it to cook on the fire for four full days, and finally "washes" the glass by flinging a ladle-full at a time into clean cold water. He then re-melts it; "You will have a black fit for any job and more marvelous than all the other blacks of which I have written."

* This post first appeared here on 8 November 2013.

Zaffer

Antique Apothecary jars,

cobalt blue glass.

As best as I can remember, the first time that I really noticed glass was at four or five years old, at my grandmother's house in Queens, New York. The sunlight filtering through a low window caught my eye with a brilliant blue glint through a small cobalt glass bottle.  My grandmother held it up to the light for me and I was enchanted; transported into a realm of exquisite pure color.

Little did I know that the spell cast on me at such a young age had been cast on Egyptian pharaohs of the eighteenth dynasty and on Persian princesses, two thousands years ago, by their cobalt glass jewelry. In all three cases, the deep rich blue of cobalt oxide glass was responsible. Today, the source of ancient Middle Eastern cobalt is unknown, possibly West Africa, but more recently, in the Renaissance; it was mined in Hungary, in Bohemia and in German Saxony, where it was called "zaffer," after its sapphire color.

Legend tells that sixteenth century silver miners in Germany amassed a hoard of smaltite thinking it was silver ore. When they tried to smelt it, the arsenic which cobalt ores always have, evolved highly toxic fumes that made them sick. Discouraged and maligned, they said the product of their labors was cursed by goblins; they named it "kobald" (cobalt) after the evil spirits. The theme of 'evil spirits' (toxic fumes) was common in mining circles. A mythology persisted from ancient times up until the eighteenth century that divided the spirits into two groups; mischievous, and malevolent. The mischievous spirits played tricks on the miner's perception and equipment, the malevolent spirits could stop a man dead in his tracks, literally. 

Regardless of the difficulties both terestrial and otherwise, a strong market developed for the newly found "kobald" among artists for paint, potters for glazes, and glassmakers. The Saxon miners gained a reputation for producing the finest zaffer.

In his glassmaking book L'Arte Vetraria, Antonio Neri describes his method for purifying and preparing zaffer for use in glass. It is a recipe that would stand the test of time, still quoted by authors into the nineteenth and twentieth century.

To Prepare Zaffer, Which Serves for Many Colors in the Art of Glassmaking

You should get zaffer in large pieces and put it in earthenware oven-pans holding it in the furnace chamber for half a day. Then put it into iron ladles to inflame it in the furnace. Heat it well, then take and sprinkle it with strong vinegar. When cold, grind it finely over a porphyry stone into glazed earthen pots with hot water. Then wash more water over it always leaving the zaffer to settle in the bottom.

Now gently decant, to carry away the sediment and impurities of the zaffer. The good part and pigment of the zaffer will remain in the bottom. The pigment remains are now prepared and purified to be far better than it was at first, which will make clear and limpid pigment. This zaffer should be dried and kept in sealed vessels for use, which will be much improved over the original.

Until the mid 1700s zaffer had been associated with silver and copper mines, and was commonly thought to be a derivative of copper. It was Swedish chemist Georg Brandt who finally isolated the new metal, and gave it the name which honors the miners and the subterranean spirits which still can cast a spell on us through its deep pure blue color in glass.

* This post first appeared here in a slightly different form on 4 April 2014.

Black is Beautiful

Black glass cameo vase, c. 1900

Thomas Webb.

Antonio Neri was a technical adept, a student of alchemical history and a glassmaker extraordinaire. He was also a gear in the Medici innovation machine. The glass recipes he developed were likely put to work in the glass shops sponsored by the ruling family in Florence, Pisa and elsewhere. Making advances in technology gave the region a competitive advantage; encouraging the arts cemented a reputation for creativity that endures to this day throughout Tuscany.

Black is one color that has given glassmakers difficulty ever since the material's invention over four thousand years ago. It is easily approximated for large, heavy objects, but to achieve a true solid black in blown vessels, or thin layers is a challenge even for current technology.

Obsidian is a naturally occurring volcanic glass that was prized in antiquity, most often occurring in black or very dark brown. In prehistoric times, it was coveted for cutting tools and arrowheads. As technology advanced, it was ground and polished for mirrors. Later, obsidian became popular in ornamental objects ranging from dinner plates to jewelry. The production of obsidian, gemstones and other natural materials through artificial means was a quest that kept glassmakers busy.

In many ways, making black glass shows the other side of challenges in making colorless crystal; instead of a formulation that will transmit virtually all the light falling on it, the aim is to produce a glass that will absorb virtually all illumination. In his book, L' Arte Vetraria, Neri presents three recipes for "velvet black" glass (# 51-53), and three recipes for black enamel (#100-102).

His first black glass is made with the discarded broken pieces of "glass of many colors." To this, he adds 'zaffer,' a cobalt ore used to produce deep dark blue, and manganese, which produces a magenta color. He advises that it will be good for bead making cane and other work. For his second black glass, he starts with high quality frit to which he adds lead and tin oxides. This forms an opaque, white lead crystal, which he tints with calcined "steel" (probably bronze) and pulverized iron flake. He claims that after twelve hours "the glass will be a most beautiful velvety black." Neri's ultimate black glass is his simplest. He starts with his 'rocchetta' frit, and adds the dried, pulverized dregs left in red wine casks, advising us to go slowly since it froths up. He allows it to cook on the fire for four full days, and finally "washes" the glass by flinging a ladle-full at a time into clean cold water. He then re-melts it; "You will have a black fit for any job and more marvelous than all the other blacks of which I have written."

* This post first appeared here on 8 November 2013.

Zaffer

Antique Apothecary jars,

cobalt blue glass.

As best as I can remember, the first time that I really noticed glass was at four or five years old, at my grandmother's house in Queens, New York. The sunlight filtering through a low window caught my eye with a brilliant blue glint through a small cobalt glass bottle.  My grandmother held it up to the light for me and I was enchanted; transported into a realm of exquisite pure color.

Little did I know that the spell cast on me at such a young age had been cast on Egyptian pharaohs of the eighteenth dynasty and on Persian princesses, two thousands years ago, by their cobalt glass jewelry. In all three cases, the deep rich blue of cobalt oxide glass was responsible. Today, the source of ancient Middle Eastern cobalt is unknown, possibly West Africa, but more recently, in the Renaissance; it was mined in Hungary, in Bohemia and in German Saxony, where it was called "zaffer," after its sapphire color.

Legend tells that sixteenth century silver miners in Germany amassed a hoard of smaltite thinking it was silver ore. When they tried to smelt it, the arsenic which cobalt ores always have, evolved highly toxic fumes that made them sick. Discouraged and maligned, they said the product of their labors was cursed by goblins; they named it "kobald" (cobalt) after the evil spirits. The theme of 'evil spirits' (toxic fumes) was common in mining circles. A mythology persisted from ancient times up until the eighteenth century that divided the spirits into two groups; mischievous, and malevolent. The mischievous spirits played tricks on the miner's perception and equipment, the malevolent spirits could stop a man dead in his tracks, literally. 

Regardless of the difficulties both terestrial and otherwise, a strong market developed for the newly found "kobald" among artists for paint, potters for glazes, and glassmakers. The Saxon miners gained a reputation for producing the finest zaffer.

In his glassmaking book L'Arte Vetraria, Antonio Neri describes his method for purifying and preparing zaffer for use in glass. It is a recipe that would stand the test of time, still quoted by authors into the nineteenth and twentieth century.

To Prepare Zaffer, Which Serves for Many Colors in the Art of Glassmaking

You should get zaffer in large pieces and put it in earthenware oven-pans holding it in the furnace chamber for half a day. Then put it into iron ladles to inflame it in the furnace. Heat it well, then take and sprinkle it with strong vinegar. When cold, grind it finely over a porphyry stone into glazed earthen pots with hot water. Then wash more water over it always leaving the zaffer to settle in the bottom.

Now gently decant, to carry away the sediment and impurities of the zaffer. The good part and pigment of the zaffer will remain in the bottom. The pigment remains are now prepared and purified to be far better than it was at first, which will make clear and limpid pigment. This zaffer should be dried and kept in sealed vessels for use, which will be much improved over the original.

Until the mid 1700s zaffer had been associated with silver and copper mines, and was commonly thought to be a derivative of copper. It was Swedish chemist Georg Brandt who finally isolated the new metal, and gave it the name which honors the miners and the subterranean spirits which still can cast a spell on us through its deep pure blue color in glass.

* This post first appeared here in a slightly different form on 4 April 2014.

Black is Beautiful

Black glass cameo vase, c. 1900

Thomas Webb.

Antonio Neri was a technical adept, a student of alchemical history and a glassmaker extraordinaire. He was also a gear in the Medici innovation machine. The glass recipes he developed were likely put to work in the glass shops sponsored by the ruling family in Florence, Pisa and elsewhere. Making advances in technology gave the region a competitive advantage; encouraging the arts cemented a reputation for creativity that endures to this day throughout Tuscany.

Black is one color that has given glassmakers difficulty ever since the material's invention over four thousand years ago. It is easily approximated for large, heavy objects, but to achieve a true solid black in blown vessels, or thin layers is a challenge even for current technology.

Obsidian is a naturally occurring volcanic glass that was prized in antiquity, most often occurring in black or very dark brown. In prehistoric times, it was coveted for cutting tools and arrowheads. As technology advanced, it was ground and polished for mirrors. Later, obsidian became popular in ornamental objects ranging from dinner plates to jewelry. The production of obsidian, gemstones and other natural materials through artificial means was a quest that kept glassmakers busy.

In many ways, making black glass shows the other side of challenges in making colorless crystal; instead of a formulation that will transmit virtually all the light falling on it, the aim is to produce a glass that will absorb virtually all illumination. In his book, L' Arte Vetraria, Neri presents three recipes for "velvet black" glass (# 51-53), and three recipes for black enamel (#100-102).

His first black glass is made with the discarded broken pieces of "glass of many colors." To this, he adds 'zaffer,' a cobalt ore used to produce deep dark blue, and manganese, which produces a magenta color. He advises that it will be good for bead making cane and other work. For his second black glass, he starts with high quality frit to which he adds lead and tin oxides. This forms an opaque, white lead crystal, which he tints with calcined "steel" (probably bronze) and pulverized iron flake. He claims that after twelve hours "the glass will be a most beautiful velvety black." Neri's ultimate black glass is his simplest. He starts with his 'rocchetta' frit, and adds the dried, pulverized dregs left in red wine casks, advising us to go slowly since it froths up. He allows it to cook on the fire for four full days, and finally "washes" the glass by flinging a ladle-full at a time into clean cold water. He then re-melts it; "You will have a black fit for any job and more marvelous than all the other blacks of which I have written."

* This post first appeared here on 8 November 2013.

The Art of Metals

Fig. 1: Antonio Neri, "Ars Preparatio Metallor[um]"

in Tesoro del Mondo, f. 8r.

Recently we examined another of a set of four illustrations drawn by priest Antonio Neri in a manuscript started in 1598.[1] They show various "arts" being practiced involving items found in nature; plants, animals, stone and today's subject: metals. 

Metals and their chemical manipulation concern Neri's work both as a glassmaker and as an alchemist. Most of the colorful pigments he uses in his glassmaking derive from metals; white from tin, green from iron, red from copper and gold, blue from cobalt, although Neri knew this last one only as a mineral called "zaffer." As an alchemist, metals were the subject of medicinal cures and of course were the focus of transmutation—the quest to turn one metal into another. In another manuscript written towards the end of his life, he indicates that he spent time in mines, where it was thought that metals "grew" underground as "veins" which nourished the earth. [2]

After an examination of Neri's "Art of Preparing Metals" we will take a look at another picture on the same subject, this time a painting titled the "Goldsmith's Workshop" by Alessandro Fei. It was executed a few years before Antonio was born, but bears some remarkable similarities in subject matter.

First, the manuscript illustration (fig. 1): At center left, we see a special furnace construction which the label tells us is for "reverberation and calcination." Two crucibles sit inside, exposed to the heat. These are both procedures with which Neri was quite familiar. In the recipes of his glassmaking book, L'Arte Vetraria, [3] he speaks numerous times about what was called "calcination"—the conversion of a metal into what is usually a powdered oxide form. [4] This was a fundamental operation in producing the pigments for glass. "Reverberation" was exposing a material to secondary heat reflected from the inner walls of the furnace chamber; it was a more even heat than that produced by a direct flame.

Above the reverberation furnace is a foundry furnace, used for melting metals. Because of the high temperatures that needed to be achieved, it has a large bellows attached to force air into the fire causing a "blast" effect, which causes the fire to burn faster and hotter. Resting on the hearth is a long pair of pincers used to insert and remove crucibles of molten metal.

To the right, we see a curious arrangement of two glass retorts, each feeding into the other. They sit on purpose built stoves. The chimneys are capped by dome shaped dampers to control the draft and paddle mechanisms in front regulate heat under the glassware. A worker tends the apparatus, and the caption below reads "for extraction of the quintessence." Neri's other writing makes plain that this "quintessence" was a material that exhibits such a harmonious blending of the four essences: air, water, fire and earth that a new fifth essence (supposedly) emerged with extraordinary properties. To the right is a similar stove set-up with a single retort which is labeled "distilling." This station might have been used in preparation of the acids needed to purify metals.

At lower right, a blacksmith is hammering a piece of iron into a sword on an anvil. High-carbon "steel" was being made and used in the Medici court at the time, and that may well be what the smith is working with. Around him are several examples of his art, including two finished swords, a large copper bowl or cauldron, and a covered drinking stein made of tin.

To his left, we find a goldsmith, also hammering on an anvil, fashioning a silver platter. Displayed behind him are a variety of his handiwork, including more platters, gold necklaces and crosses and other ornamentation. A number of tools hang along the bottom of the anvil station, and behind it a small dog is curled up on the floor. 

Fig 2: Alessandro Fei (Barbieri)
"Goldsmith's Workshop" c. 1572.

About twenty-five years before Neri wrote his manuscript, Alessandro Fei painted a similar picture (fig. 2). Here we are treated to a view of a royal foundry housed in the yet to be completed Uffizi palace. [5] There is a remarkable concordance between this painting and Neri's illustration, right down to a small dog, hanging around the goldsmith's bench. 

The central figure of the painting is  Francesco de' Medici, seated in the foreground, inspecting his father's gold crown at a workbench. The dog is playfully engaging with the future Grand Duke, while on the opposite side of the bench, two other men are amiably discussing their work, perhaps silver chasing.To the left of Francesco, a younger man examines a gold ewer in the company of an older goldsmith seated across the table. The artisan is wearing spectacles and (although it is hard to see) he holds a small hammer in his hand. A worker to Francesco’s right is also intently engaged in his work. In the right mid-ground we find a small furnace with a tall chimney leading upward. On the mantle are displayed a number of gold and silver items, including platters, vessels and chains or necklaces. To the left, four men are busy seated around a large workbench. Behind that group, toward the center of the picture, are two men working at an anvil and three more at another bench on the right, accompanied by a second small dog. In an enclosed area in the background we see two large open furnace hearths, with their fireboxes glowing from underneath and men working in close proximity. In the far left background is a group entering the work area, including a figure in a yellow cape accompanied by a third dog.

The one element present in Neri's illustration that is missing in the painting is the glassware. Metalwork was a venerated and mature art long before Neri's era, which is underlined by the similarity of the two scenes, even though they are a quarter century apart, the tools, equipment and work methods are identical for all intents and purposes. There is no doubt that chemistry and distillation apparatus were used by the earlier metals artisans, the fact that Neri chose to emphasize this aspect of the work is a clear indication of his own interest and a foreshadowing of his future involvement in the production of the glass itself.

[1] Neri 1598-1600.
[2] Neri 1613, Grazzini 2012. 
[3] Neri 1612.
[4] In several of Neri's glass recipes the result of "calcination" is a sulfide.
[5] Beretta, 2014.

(Bibliography)
*This post first appeared here on 17 September 2014.

The Material of All Enamels

Léonard Limosin, Allegory of Catherine de' Medici as Juno,

French, 1573, Polychrome enamel  on copper and silver.

In L'Arte Vetraria, Antonio Neri's recipe book on glassmaking, he devotes the sixth chapter to making enamel. For Neri, this was a tinted form of opaque glass favored by jewelers and goldsmiths. The material was ground into a fine powder, added to a binder and painted onto glass or metals, usually copper, gold or silver. Once dry, the item was fired over a flame or in a kiln so the enamel would fuse to form a durable glossy coating. Talented workers could use various colors to paint entire scenes.

“We see ornate enameled metals in many colors and they make a pleasant and noble sight; they entice others to look and take notice.”

Neri begins by showing how to produce what he calls “the material to make all enamels.” This is a neutral-white base to which he then adds various metal oxide pigments to produce color.

He starts by mixing together thirty pounds of pure lead and thirty-three pounds of pure tin, both in a finely divided state. He heats them in a low temperature kiln that has a wide, accessible hearth. He roasts or "calcines" the metals, raking the powders around with special iron tools for many hours. This has the effect of oxidizing the metals without melting them.

He sifts the mixture and boils it in a kettle of pure clean water. The kettle is removed from the heat and the contents are allowed to settle for a while. The water is then carefully poured off, carrying with it only the finest particles still in suspension. This liquid is saved, while the sediment at the bottom of the kettle is sent back for reprocessing in the kiln. He repeats the "decanting" procedure many times, and then carefully evaporates the accumulated liquid over a low fire. What remains is an extremely fine powdered tin and lead oxide mixture.

Neri tells us that fifty pounds of this oxide is to be mixed with an equal weight of powdered cristallo frit. Cristallo was the coveted glass perfected by the Venetians on the island of Murano. "Frit" is the granulated glass before it is put into the furnace and melted. The recipe for cristallo had remained a state secret for over a century. It was the clearest, finest glass that money could buy and items made from it commanded top dollar among the richest families in Europe. Even after production methods became known to outsiders, Venice still controlled many of the raw materials through exclusive trade agreements around the Mediterranean. Neri was first to actually publish the recipes for making cristallo, in this very same book. It was made with pure white quartz pebbles from Pavia, mixed with purified salts derived from the Levantine kali plant, and decolorized with manganese from Piedmont.

In order to complete the enamel base material, Neri adds eight ounces of white tartar salt (made from the dregs of wine), sifts the mix and carefully heats it in terracotta pots for ten hours. The result is ground again and stored in a in a dry place, in a sealed container for future use.

The rest of the chapter is devoted to coloring this enamel base material; he always starts with a batch of either four or six pounds. He uses a large furnace pot to melt the enamel because even though the amount is relatively small, some of the pigments cause the batch to froth and swell violently. After adding the pigments, he lets the glass cook for a while, adjusts the color as necessary and then "washes" it several times. In this process, he throws ladlefuls of molten glass from the furnace-pot into large vats of cold clean water. The effect is to remove excess plant salts from the glass, which would ultimately foul the enamel. Finally, he forms the glass into individual dollops of about five ounces each; a size to which the goldsmiths were accustomed.

For green enamel, Neri uses copper and iron oxides in various proportions, for blues he uses "zaffer," which is a cobalt oxide. He mixes green and blue pigments to obtain turquoise colors. Manganese produced a red wine color, for yellow, he adds the unrefined dregs of red wine (potassium) with a pinch of manganese. Violet is a mix of manganese and copper oxides.

Finally, a word to the wise: Do not attempt to duplicate these recipes; fine lead powder is dangerous enough, molten lead enamel will evolve fumes that cause heavy metal poisoning. Remember that Antonio Neri was dead by age thirty-eight.

* This post first appeared here 11 July 2014.

Zaffer

Antique Apothecary jars,

cobalt blue glass.

As best as I can remember, the first time that I really noticed glass was at four or five years old, at my grandmother's house in Queens, New York. The sunlight filtering through a low window caught my eye with a brilliant blue glint through a small cobalt glass bottle.  My grandmother held it up to the light for me and I was enchanted; transported into a realm of exquisite pure color.

Little did I know that the spell cast on me at such a young age had been cast on Egyptian pharaohs of the eighteenth dynasty and on Persian princesses, two thousands years ago, by their cobalt glass jewelry. In all three cases, the deep rich blue of cobalt oxide glass was responsible. Today, the source of ancient Middle Eastern cobalt is unknown, possibly West Africa, but more recently, in the Renaissance; it was mined in Hungary, in Bohemia and in German Saxony, where it was called "zaffer," after its sapphire color.

Legend tells that sixteenth century silver miners in Germany amassed a hoard of smaltite thinking it was silver ore. When they tried to smelt it, the arsenic which cobalt ores always have, evolved highly toxic fumes that made them sick. Discouraged and maligned, they said the product of their labors was cursed by goblins; they named it "kobald" (cobalt) after the evil spirits. The theme of 'evil spirits' (toxic fumes) was common in mining circles. A mythology persisted from ancient times up until the eighteenth century that divided the spirits into two groups; mischievous, and malevolent. The mischievous spirits played tricks on the miner's perception and equipment, the malevolent spirits could stop a man dead in his tracks, literally. 

Regardless of the difficulties both terestrial and otherwise, a strong market developed for the newly found "kobald" among artists for paint, potters for glazes, and glassmakers. The Saxon miners gained a reputation for producing the finest zaffer.

In his glassmaking book L'Arte Vetraria, Antonio Neri describes his method for purifying and preparing zaffer for use in glass. It is a recipe that would stand the test of time, still quoted by authors into the nineteenth and twentieth century.

To Prepare Zaffer, Which Serves for Many Colors in the Art of Glassmaking

You should get zaffer in large pieces and put it in earthenware oven-pans holding it in the furnace chamber for half a day. Then put it into iron ladles to inflame it in the furnace. Heat it well, then take and sprinkle it with strong vinegar. When cold, grind it finely over a porphyry stone into glazed earthen pots with hot water. Then wash more water over it always leaving the zaffer to settle in the bottom.

Now gently decant, to carry away the sediment and impurities of the zaffer. The good part and pigment of the zaffer will remain in the bottom. The pigment remains are now prepared and purified to be far better than it was at first, which will make clear and limpid pigment. This zaffer should be dried and kept in sealed vessels for use, which will be much improved over the original.

Until the mid 1700s zaffer had been associated with silver and copper mines, and was commonly thought to be a derivative of copper. It was Swedish chemist Georg Brandt who finally isolated the new metal, and gave it the name which honors the miners and the subterranean spirits which still can cast a spell on us through its deep pure blue color in glass.

* This post first appeared here in a slightly different form on 4 April 2014.

Black is Beautiful

Black glass cameo vase, c. 1900
Thomas Webb.

Antonio Neri was a technical adept, a student of alchemical history and a glassmaker extraordinaire. He was also a gear in the Medici innovation machine. The glass recipes he developed were likely put to work in the glass shops sponsored by the ruling family in Florence, Pisa and elsewhere. Making advances in technology gave the region a competitive advantage; encouraging the arts cemented a reputation for creativity that endures to this day throughout Tuscany.

Black is one color that has given glassmakers difficulty ever since the material's invention over four thousand years ago. It is easily approximated for large, heavy objects, but to achieve a true solid black in blown vessels, or thin layers is a challenge even for current technology.

Obsidian is a naturally occurring volcanic glass that was prized in antiquity, most often occurring in black or very dark brown. In prehistoric times, it was coveted for cutting tools and arrowheads. As technology advanced, it was ground and polished for mirrors. Later, obsidian became popular in ornamental objects ranging from dinner plates to jewelry. The production of obsidian, gemstones and other natural materials through artificial means was a quest that kept glassmakers busy.

In many ways, making black glass shows the other side of challenges in making colorless crystal; instead of a formulation that will transmit virtually all the light falling on it, the aim is to produce a glass that will absorb virtually all illumination. In his book, L' Arte Vetraria, Neri presents three recipes for "velvet black" glass (# 51-53), and three recipes for black enamel (#100-102).

His first black glass is made with the discarded broken pieces of "glass of many colors." To this, he adds 'zaffer,' a cobalt ore used to produce deep dark blue, and manganese, which produces a magenta color. He advises that it will be good for bead making cane and other work. For his second black glass, he starts with high quality frit to which he adds lead and tin oxides. This forms an opaque, white lead crystal, which he tints with calcined "steel" (probably bronze) and pulverized iron flake. He claims that after twelve hours "the glass will be a most beautiful velvety black." Neri's ultimate black glass is his simplest. He starts with his 'rocchetta' frit, and adds the dried, pulverized dregs left in red wine casks, advising us to go slowly since it froths up. He allows it to cook on the fire for four full days, and finally "washes" the glass by flinging a ladle-full at a time into clean cold water. He then re-melts it; "You will have a black fit for any job and more marvelous than all the other blacks of which I have written."

* This post first appeared here on 8 November 2013.

The Art of Metals

Fig. 1: Antonio Neri, "Ars Preparatio Metallor[um]"

in Tesoro del Mondo, f. 8r.
(click to enlarge)

Recently we examined another of a set of four illustrations drawn by priest Antonio Neri in a manuscript started in 1598.[1] They show various "arts" being practiced involving items found in nature; plants, animals, stone and today's subject: metals. 

Metals and their chemical manipulation concern Neri's work both as a glassmaker and as an alchemist. Most of the colorful pigments he uses in his glassmaking derive from metals; white from tin, green from iron, red from copper and gold, blue from cobalt, although Neri knew this last one only as a mineral called "zaffer." As an alchemist, metals were the subject of medicinal cures and of course were the focus of transmutation—the quest to turn one metal into another. In another manuscript written towards the end of his life, he indicates that he spent time in mines, where it was thought that metals "grew" underground as "veins" which nourished the earth. [2]

After an examination of Neri's "Art of Preparing Metals" we will take a look at another picture on the same subject, this time a painting titled the "Goldsmith's Workshop" by Alessandro Fei. It was executed a few years before Antonio was born, but bears some remarkable similarities in subject matter.

First, the manuscript illustration (fig. 1): At center left, we see a special furnace construction which the label tells us is for "reverberation and calcination." Two crucibles sit inside, exposed to the heat. These are both procedures with which Neri was quite familiar. In the recipes of his glassmaking book, L'Arte Vetraria, [3] he speaks numerous times about what was called "calcination"—the reduction of a metal into what is usually a powdered oxide form. [4] This was a fundamental operation in producing the pigments for glass. "Reverberation" was exposing a material to secondary heat reflected from the inner walls of the furnace chamber; it was a more even heat than that produced by a direct flame.

Above the reverberation furnace is a foundry furnace, used for melting metals. Because of the high temperatures that needed to be achieved, it has a large bellows attached to force air into the fire causing a "blast" effect, which causes the fire to burn faster and hotter. Resting on the hearth is a long pair of pincers used to insert and remove crucibles of molten metal.

To the right, we see a curious arrangement of two glass retorts, each feeding into the other. They sit on purpose built stoves. The chimneys are capped by dome shaped dampers to control the draft and paddle mechanisms in front regulate heat under the glassware. A worker tends the apparatus, and the caption below reads "for extraction of the quintessence." Neri's other writing makes plain that this "quintessence" was a material that exhibits such a harmonious blending of the four essences: air, water, fire and earth that a new fifth essence (supposedly) emerged with extraordinary properties. To the right is a similar stove set-up with a single retort which is labeled "distilling." This station might have been used in preparation of the acids needed to purify metals.

At lower right, a blacksmith is hammering a piece of iron into a sword on an anvil. High-carbon "steel" was being made and used in the Medici court at the time, and that may well be what the smith is working with. Around him are several examples of his art, including two finished swords, a large copper bowl or cauldron, and a covered drinking stein made of tin.

To his left, we find a goldsmith, also hammering on an anvil, fashioning a silver platter. Displayed behind him are a variety of his handiwork, including more platters, gold necklaces and crosses and other ornamentation. A number of tools hang along the bottom of the anvil station, and behind it a small dog is curled up on the floor. 

Fig 2: Alessandro Fei (Barbieri)
"Goldsmith's Workshop" c. 1572.

About twenty-five years before Neri wrote his manuscript, Alessandro Fei painted a similar picture (fig. 2). Here we are treated to a view of a royal foundry housed in the yet to be completed Uffizi palace. [5] There is a remarkable concordance between this painting and Neri's illustration, right down to a small dog, hanging around the goldsmith's bench. 

The central figure of the painting is  Francesco de' Medici, seated in the foreground, inspecting his father's gold crown at a workbench. The dog is playfully engaging with the future Grand Duke, while on the opposite side of the bench, two other men are amiably discussing their work, perhaps silver chasing.To the left of Francesco, a younger man examines a gold ewer in the company of an older goldsmith seated across the table. The artisan is wearing spectacles and (although it is hard to see) he holds a small hammer in his hand. A worker to Francesco’s right is also intently engaged in his work. In the right mid-ground we find a small furnace with a tall chimney leading upward. On the mantle are displayed a number of gold and silver items, including platters, vessels and chains or necklaces. To the left, four men are busy seated around a large workbench. Behind that group, toward the center of the picture, are two men working at an anvil and three more at another bench on the right, accompanied by a second small dog. In an enclosed area in the background we see two large open furnace hearths, with their fireboxes glowing from underneath and men working in close proximity. In the far left background is a group entering the work area, including a figure in a yellow cape accompanied by a third dog.

The one element present in Neri's illustration that is missing in the painting is the glassware. Metalwork was a venerated and mature art long before Neri's era, which is underlined by the similarity of the two scenes, even though they are a quarter century apart, the tools, equipment and work methods are identical for all intents and purposes. There is no doubt that chemistry and distillation apparatus were used by the earlier metals artisans, the fact that Neri chose to emphasize this aspect of the work is a clear indication of his own interest and a foreshadowing of his future involvement in the production of the glass itself.

[1] Neri 1598-1600.
[2] Neri 1613, Grazzini 2012. 
[3] Neri 1612.
[4] In several of Neri's glass recipes the result of "calcination" is a sulfide.
[5] Beretta, 2014.

(Bibliography)
*This post first appeared here on 17 September 2014.

The Material of All Enamels

Léonard Limosin, Allegory of Catherine de' Medici as Juno,

French, 1573, Polychrome enamel  on copper and silver.

In L'Arte Vetraria, Antonio Neri's recipe book on glassmaking, he devotes the sixth chapter to making enamel. For Neri, this was a tinted form of opaque glass favored by jewelers and goldsmiths. The material was ground into a fine powder, added to a binder and painted onto glass or metals, usually copper, gold or silver. Once dry, the item was fired over a flame or in a kiln so the enamel would fuse to form a durable glossy coating. Talented workers could use various colors to paint entire scenes.

“We see ornate enameled metals in many colors and they make a pleasant and noble sight; they entice others to look and take notice.”

Neri begins by showing how to produce what he calls “the material to make all enamels.” This is a neutral-white base to which he then adds various metal oxide pigments to produce color.

He starts by mixing together thirty pounds of pure lead and thirty-three pounds of pure tin, both in a finely divided state. He heats them in a low temperature kiln that has a wide, accessible hearth. He roasts or "calcines" the metals, raking the powders around with special iron tools for many hours. This has the effect of oxidizing the metals without melting them.

He sifts the mixture and boils it in a kettle of pure clean water. The kettle is removed from the heat and the contents are allowed to settle for a while. The water is then carefully poured off, carrying with it only the finest particles still in suspension. This liquid is saved, while the sediment at the bottom of the kettle is sent back for reprocessing in the kiln. He repeats the "decanting" procedure many times, and then carefully evaporates the accumulated liquid over a low fire. What remains is an extremely fine powdered tin and lead oxide mixture.

Neri tells us that fifty pounds of this oxide is to be mixed with an equal weight of powdered cristallo frit. Cristallo was the coveted glass perfected by the Venetians on the island of Murano. "Frit" is the granulated glass before it is put into the furnace and melted. The recipe for cristallo had remained a state secret for over a century. It was the clearest, finest glass that money could buy and items made from it commanded top dollar among the richest families in Europe. Even after production methods became known to outsiders, Venice still controlled many of the raw materials through exclusive trade agreements around the Mediterranean. Neri was first to actually publish the recipes for making cristallo, in this very same book. It was made with pure white quartz pebbles from Pavia, mixed with purified salts derived from the Levantine kali plant, and decolorized with manganese from Piedmont.

In order to complete the enamel base material, Neri adds eight ounces of white tartar salt (made from the dregs of wine), sifts the mix and carefully heats it in terracotta pots for ten hours. The result is ground again and stored in a in a dry place, in a sealed container for future use.

The rest of the chapter is devoted to coloring this enamel base material; he always starts with a batch of either four or six pounds. He uses a large furnace pot to melt the enamel because even though the amount is relatively small, some of the pigments cause the batch to froth and swell violently. After adding the pigments, he lets the glass cook for a while, adjusts the color as necessary and then "washes" it several times. In this process, he throws ladlefuls of molten glass from the furnace-pot into large vats of cold clean water. The effect is to remove excess plant salts from the glass, which would ultimately foul the enamel. Finally, he forms the glass into individual dollops of about five ounces each; a size to which the goldsmiths were accustomed.

For green enamel, Neri uses copper and iron oxides in various proportions, for blues he uses "zaffer," which is a cobalt oxide. He mixes green and blue pigments to obtain turquoise colors. Manganese produced a red wine color, for yellow, he adds the unrefined dregs of red wine (potassium) with a pinch of manganese. Violet is a mix of manganese and copper oxides.

Finally, a word to the wise: Do not attempt to duplicate these recipes; fine lead powder is dangerous enough, molten lead enamel will evolve fumes that cause heavy metal poisoning. Remember that Antonio Neri was dead by age thirty-eight.

* This post first appeared here 11 July 2014.

Zaffer

Antique Apothecary jars,
cobalt blue glass.

As best as I can remember, the first time that I really noticed glass was at four or five years old, at my grandmother's house in Queens, New York. The sunlight filtering through a low window caught my eye with a brilliant blue glint through a small cobalt glass bottle.  My grandmother held it up to the light for me and I was enchanted; transported into a realm of exquisite pure color.

Little did I know that the spell cast on me at such a young age had been cast on Egyptian pharaohs of the eighteenth dynasty and on Persian princesses, two thousands years ago, by their cobalt glass jewelry. In all three cases, the deep rich blue of cobalt oxide glass was responsible. Today, the source of ancient Middle Eastern cobalt is unknown, possibly West Africa, but more recently, in the Renaissance; it was mined in Hungary, in Bohemia and in German Saxony, where it was called "zaffer," after its sapphire color.

Legend tells that sixteenth century silver miners in Germany amassed a hoard of smaltite thinking it was silver ore. When they tried to smelt it, the arsenic which cobalt ores always have, evolved highly toxic fumes that made them sick. Discouraged and maligned, they said the product of their labors was cursed by goblins; they named it "kobald" (cobalt) after the evil spirits. The theme of 'evil spirits' (toxic fumes) was common in mining circles. A mythology persisted from ancient times up until the eighteenth century that divided the spirits into two groups; mischievous, and malevolent. The mischievous spirits played tricks on the miner's perception and equipment, the malevolent spirits could stop a man dead in his tracks, literally. 

Regardless of the difficulties both terestrial and otherwise, a strong market developed for the newly found "kobald" among artists for paint, potters for glazes, and glassmakers. The Saxon miners gained a reputation for producing the finest zaffer.

In his glassmaking book L'Arte Vetraria, Antonio Neri describes his method for purifying and preparing zaffer for use in glass. It is a recipe that would stand the test of time, still quoted by authors into the nineteenth and twentieth century.

To Prepare Zaffer, Which Serves for Many Colors in the Art of Glassmaking

You should get zaffer in large pieces and put it in earthenware oven-pans holding it in the furnace chamber for half a day. Then put it into iron ladles to inflame it in the furnace. Heat it well, then take and sprinkle it with strong vinegar. When cold, grind it finely over a porphyry stone into glazed earthen pots with hot water. Then wash more water over it always leaving the zaffer to settle in the bottom.

Now gently decant, to carry away the sediment and impurities of the zaffer. The good part and pigment of the zaffer will remain in the bottom. The pigment remains are now prepared and purified to be far better than it was at first, which will make clear and limpid pigment. This zaffer should be dried and kept in sealed vessels for use, which will be much improved over the original.

Until the mid 1700s zaffer had been associated with silver and copper mines, and was commonly thought to be a derivative of copper. It was Swedish chemist Georg Brandt who finally isolated the new metal, and gave it the name which honors the miners and the subterranean spirits which still can cast a spell on us through its deep pure blue color in glass.

* This post first appeared here in a slightly different form on 4 April 2014.