A Deeper Accomplishment

From Antonio Neri, "Treasure of the World"

MS Ferguson 67, f. 22r.

For the past four centuries, Antonio Neri has been best known as the author of L'Arte Vetraria, the first printed book solely devoted to the art of glass formulation (1612). It is a work committed to the subject of refining raw materials and combining them into a range of glasses, over a rainbow of colors. 'First into print' is a notable distinction, but one that Neri surpasses with ease by a deeper accomplishment. His book provides a rare glimpse of skilled practical knowledge. This was an era when prized techniques were frequently lost to subsequent generations; lost because artisans so often spared the pen. Their precious knowledge went purposely unrecorded, passing in strict confidence from master to apprentice working side by side. Neri preserved the old techniques of glass formulation like no other document has.

That 'first into print' is what we remember him for highlights an age-old problem that dogs historians. It is a simplification that puts a convenient handle on Neri, but at the same time, it de-emphasizes the fact that he was not working alone. It plays into a narrative that history, in general, happens in a parade of discrete jumps due to the brilliant discoveries of individuals working in isolation. This is reinforced by the mythology surrounding Neri – that he was a mysterious lone alchemist, wandering around Europe, evading those who would steal the secret of the philosopher’s stone. A similar narrative is applied to one historical figure after another, a form that is so appealing that it fills many history books of our schoolchildren and dictates the story lines of popular media productions (of a certain ilk) about the history of science and technology.

This is not to deny the limelight to anyone. Neri is a comparatively minor contributor and in my humble opinion definitely deserves recognition and even celebration. The danger is that by reducing history to a list of lone individuals making breakthrough discoveries, we distort the truth of how things are done and more to the point; we miss out on the far richer adventure of what really happens.

Never mind that Neri's book chronicles the work of hundreds or thousands of glassmakers that came before him or that he probably would have been far more grateful to be remembered for his work in alchemy and medicine. What sticks is 'first into print.' The reality is that he had the substantial resources of the Renaissance Medici court at his disposal. There is strong evidence based on his own manuscripts and drawings that he worked among a group of at least a dozen colleagues of both sexes, exchanging ideas, experimenting and urging each other on; a mode that no scientist would deny is far closer to the way discovery and innovation really happen.

This cultural defect in our perception of history is by no means a recent development. Even in Neri's own time, the early seventeenth century, the 'lone man' paradigm was well established. He and his contemporaries thought along similar lines about alchemists Arnold Villanova, Ramon Llull and Paracelsus. likewise for physicians that his father idolized like Galen and Dioscorides.

For the first time in history, we each have a tremendous chunk of the past at our fingertips in the form of the internet. It is a golden opportunity, not to be fed history, but to discover it for yourself and perhaps for the rest of us. There is no shortage of connections yet to be made and libraries around the world are availing their treasures freely to anyone with an interest. For a great adventure and an exercise in critical thinking, pick a discovery attributed to your favorite figure in history and ask the question "on whose shoulders was she standing?"

*This post first appeared here on 21 March 2014.

Sonnet for a Barber

Possible portrait of Lodovico Domenichi,

British Museum, inventory #1867,1012.650

This is a post about a 16th century poet who was best friends with alchemist/glassmaker Antonio Neri's grandfather, Jacopo, and who may even be the inspiration for the glassmaker's middle name: Lodovico. Neri, born in 1576,  is remembered mostly for his book of glass recipes, L'Arte Vetraria, yet he considered himself first and foremost an alchemist. His father was the personal physician to the grand duke of Tuscany, and his grandfather was a barber surgeon, who probably lived in the family house until his death in 1594, when Antonio was an 18-year-old. There can be little question that our glassmaker/alchemist was steeped in chemistry and medicine from a very early age, but perhaps also literature. 

In November of 1554, poet Lodovico Domenichi wrote a sonnet to his friend, Jacopo Neri. Jacopo was from Dicomano in the upper Arno River valley, then living in Florence with his young family. Domenichi was serving a sentence of house arrest in a wretched paper mill in Pescia, in the hills north of Florence. He had been found guilty by the inquisition on charges of translating the heretical writing of John Calvin into vernacular Italian, a crime for which the poet could have easily been executed. Luckily, he had friends in high places and after some nervous time spent in the stockade in Pisa, his sentence was reduced and later commuted by Grand Duke Cosimo I de' Medici.

Jacopo Neri had taken ill with a grave infirmity and when word reached Domenichi, he took pen to paper and composed seventy stanzas in the style of Petrarch. In so doing he bestowed a precious gift, the only one he could under the circumstances; he immortalized his good friend on paper. The sonnet starts:

      As I have now come to understand your

      Perilous illness and health,

      It is both grief and fondness that I show

      So may merciful God help you,

      Without delay, lest this vile world lose

      So much goodness in you, so much virtue.

In the sonnet, he goes on to extol Jacopo's kindness towards patients, his willingness to forgive and his admiration among scholars. Along the way, Domenichi describes his own predicament; the cruelties of the mill workers, the muddy floors, his desire to flee and trying to sleep on a bed of frozen straw among the work animals. The rain has been falling for weeks and he is miserable. Recalling happier times he evokes the memories of many mutual friends, including a dwarf named Don Gabriello Franceschi, who delivered sermons at the Cestello church, Neri's family church, located a few hundred feet from his front door. Franceschi was from the family into which Jacopo's daughter, Faustina, would later marry. 

      There he is called Don Gabriello 

      Franceschi and I am honored, for good reason,

      A giant of men in a small handsome package.

He goes on to describe his saviors; the men who intervened with the Church on his behalf. One was Pompeo della Barba, educated at Pisa and later called to Rome as the personal physician to Pope Pius IV. In the end, Domenichi was pardoned, allowed to leave the damp mill and return to Florence. Within a short time, he was appointed court historian to Cosimo I. Over his career, he published many volumes; translations of works ranging from Xenophon, to Plutarch, to Pliny's Natural History, to a groundbreaking compilation of poems by contemporary women. At the end of his life, Domenichi suffered devastating debilitation, maybe from a stroke, which robbed him of the ability to speak. Even so, he still received regular visits from his old friend Jacopo Neri the barber surgeon. As we turn away from the subject of Lodovico Domenichi, it is hard to resist speculating that a decade after his death, the poet was remembered with fondness by the Neri family in the christening of our glassmaker, whose full name is Antonio Lodovico Neri.

Lodovico Domenichi, "A Mastro Jacopo di Neri, Cerusico, E Barbiere." in Il Secondo libro dell' Opere Burlesche, di M. Francesco Berni.  (Fiorenza: Apresso li Heredi di Bernardo Giunti, 1555), vv. 2. Reprinted many times. 
*This post first appeared 9 September 2013.

Vitrum Flexile [Flexible Glass]

Roman Emperor Tiberius - Glass paste cameo

 c 20ACE by "Herophilos, Son of Dioskurides"

In the first century CE, references appear in the literature for a malleable form of glass --that is to say flexible-- the method for which is reported as lost. This 'vitrum flexile' was a material that supposedly could be worked with a hammer like metal; not brittle but plastic, yet retaining the other favorable properties of glass. In the ancient world, historians Strabo (c. 63 BCE–24 CE), Pliny (c. 23–79 CE), Petronius (c. 27–66 CE) and others recount the story of a hapless artisan who brought his great discovery to Roman emperor Tiberius. Fearing the devaluation of his wealth, the emperor had the glassmaker executed on the spot and his workshop destroyed. The implication being that the inestimable value of a malleable glass would crash the markets for gold and silver. [1]

Since then, the legend has resurfaced in various forms, notably at periods in history of technological upheaval; times when innovative knowledge threatened to 'disrupt' the established order. One incarnation has the sophy of Persia gifting a set of malleable drinking glasses to the king of Spain, Philip III, around 1610. Just then, new trade deals with the Middle East rattled the European economy and Venetian glass craftsmen fanned out through Europe, disrupting local glass furnaces and guilds with their superior techniques. [2] Another version tells of a French sculptor bringing his malleable glass-work to Cardinal Richelieu (1585-1642), of Dumas' Three Musketeers fame. According to the story, that particular artisan’s reward was life in prison. The tale takes place in a tumultuous political period in French history and appears in print at the dawn of the so-called industrial revolution. [3]

Chronologically, this last story aligns nicely with the publication, in southern France, of a Latin book of alchemical recipes by royal physician Pierre-Jean Fabre (1588-1658). Contained in his volume is a prescription for a malleable form of glass, presumably the fabled vitrum flexile. Fabre's book was titled Palladium Spagyricum, 1624. [4] Spagyricum is a reference to spagyrics, the specific brand of chemistry practiced by sixteenth century alchemist-physician Paracelsus. Palladium translates to 'protector' or 'savior'. As an aside, it is interesting to note that Fabre developed an elaborate philosophy which integrated chemistry as a 'sacrament' to Catholic theology, but that is a story for another day.

In 1685, Fabre's recipes were nicely translated into English and tucked into the end of a book otherwise devoted to the art of drawing, by William Salmon [5]. Here is the full recipe "To Make Malleable Glass" as rendered in Salmon's book:

I.        Take oyl of Luna, twenty drachms: oyl of Mercury, or its water seven times rectified, one pound: mix them together and distill them.

II.      Repeat this distillation till the oleum Lunae rises with the water of Mercury in distillation. 

III.     Distill this water again until it is fixed, and converted into a fixed oyl, and this repeat four times. 

IV.     In the fourth time the oyl of Luna is fixed with the oyl of Mercury, so that they render glass malleable; for so great is the viscosity in your oyls, that it removes the brittleness of the glass, and so leaves it of a malleable temper. 

V.      The reason is, because that the radical moisture of the glass is multiplied by the radical moisture of the metals. Which is plentiful and turgent or swelling in the oyls of Luna and Mercury. 

VI.     And if [in] this oyl made volatile, diamonds should be dissolved, and then digested into a fixt oyl, it would transmute all glass into diamonds, only by projecting this oyl onto melted glass. 

VII.   There are also other precious stones comprehended within this oyl, when it is made volatile, and digested, and fixed again by digestion continually for the space of a year. 

VIII.  Also this oyl can turn glass into precious stones of any kind whatsoever, if therein (being made volatile) precious stones of the same kind have been dissolved, and digested with it into a fixed oyl. 

IX.     For as metals are included in their fixed oyls: so are precious stones in theirs, as Raymundus Lullius doth witness in many places; the which thing we shall teach you in the following chapter. 

 Elsewhere in the book, it is explained that 'oyl of Luna' is silver dissolved in acid, and 'oyl of Mercury' is a sublimation of mercury and saltpeter. [6] From a purely technical standpoint, the formula would have been regarded credible by 17th century and earlier practitioners in that both mercury and silver were successfully used as additives to glass and they do integrate into the matrix. Notably, Antonio Neri used both of them in his chalcedony glass. In Neri's case he was using these metals to produce color, although he does not attribute specific tints to the ingredients. Under some circumstances, silver is known to produce an attractive blue. It should also be noted that Renaissance glassmakers used similar silver-mercury formulas to produce the reflective layer on finished glass mirrors, in a process that resembled gilding. They formed what was known as "mercury glass." It is not beyond the pale to speculate that experiments would have been conducted by alchemists to add such concoctions directly to the glass melt. In the end, though, there is no indication that these additives would produce a malleable glass. Last, we should note that prolonged exposure to mercury vapor causes irreversable neurological and organ damage. It undoubetly contributed to the demise of alchemists, gilders, milliners and many others who worked with it throughout history. 

As far as I am aware, this is the first example of a specific recipe for malleable glass uncovered in the literature. If nothing else, it is an important marker for further research into the history of glassmaking.

[1] Strabo: Geography, v. 8; Pliny: Naturalis Historia XXXVI.lxvi.195; Petronius: Satyricon 50.7; Also recounted by Casius Dio (c.150–235 CE): Historia Romana 57.21.7; Isidore of Seville (c. 560–636 CE): Etymologiae XVI.16.6, ‘De vitro’; Suetonius; Ibn Abd Alhokin; John of Sailsbury.

[2] Knolles, Grimstone, Johnson: Richard Knolles' The General Historie of the Turkes (London: Adam Islip, 1621).

[3] Neri 1697 (Introduction). A French translation of Florentine glassmaker Antonio Neri’s 1612 book L’Arte Vetraria [The art of making glass] by Jean Haudicquer de Blancourt. Also see my earlier post here http://www.conciatore.org/2014/07/flexible-glass-reprise.html .

[4] Pierre-Jean Fabre: Palladium spagyricum Petri Ioannis Fabri doctoris medici Monspeliensis ... (Toulouse: Bosc, 1624), p. 276. Later translated into several English editions, see note [5].

[5] William Salmon: Polygraphice: Or the Arts of Drawing, Engraving, Etching, Limming, Painting … (London: T. Passenger & T. Sawbridge, 1685), pp. 598, 599.

[6] To more adventurous readers: DO NOT TRY THIS AT HOME, or anywhere else, ever. Vaporized mercury is a powerful neurotoxin. Small amounts can cause permanent brain damage and multiple organ failure. Furthermore, this recipe uses powerful acids and nitrates, which are extremely dangerous even in a controlled laboratory setting. Even if you have little regard for your own health and safety, consider those around you; this includes loved ones, family, children, pets, neighbors and the emergency workers who will inevitably be left to clean up your mess.

The Glass of Montpellier

Montpellier, France, in the seventeenth century.

(Attribution unknown)

Montpellier is an old city in southern France. It stands about halfway between Marseille and the Spanish border along the Mediterranean Sea (strategically located slightly inland to avoid pirates). First documented in the tenth century, it is one of very few French cities that developed without the influence of ancient Roman occupation; it is a pure product of the local region. It became a center of intellectual learning and attracted students from throughout Europe. Around it sprung a number of supporting arts not the least of which was glassmaking. Once famous for its fine glassware, today this centuries long heritage is all but forgotten, yet when we dig into the literature, we find a surprise connection to one of the oldest legends in the history of glass.

Since before the Renaissance, Montpellier was an established center for medical and legal education, a strong tradition that continues at the university there; today, it houses the oldest running medical school in the world. This prestigious institution "was founded perhaps by people trained in the Spanish medical schools; it is certain that, as early as 1137, there were excellent physicians at Montpellier University." [1] In 1529, Nostradamus entered to study for a doctorate in medicine, but shortly thereafter, he was expelled when it was discovered that he previously worked as an apothecary; a 'manual' skill that was banned by the school's rules of conduct.

Paradoxically, these impugned 'manual' arts account for some the region's more intriguing activity. Along with medicine, the area became known for the production of paint pigments, for glassmaking and finally for the practice of alchemy. All of these turn out to be closely related to each other, but perhaps not obviously so. Throughout the Renaissance, apothecaries were responsible for a wide range of distillations and extracts used by physicians to treat disease. They were also the de facto suppliers of pigments and other fine art supplies and even sourced some of the materials for glassmaking. Glassmakers often relied on painters to embellish their products, painters used ground glass in their pigments and apothecaries needed glassmakers to produce the flasks, beakers and other alchemical equipment required for their profession.

An anonymous Montpellier manuscript of the fourteenth century, called the Liber diversarum arcium [Book of Various Arts], offers us one of the most complete guides to the production of pigments to have survived from that period. [2] Another, later writing of the sixteenth century offers an extensive collection of glassmaking recipies brought to Montpellier from Venice. This one is titled Recette per fare vetri colorati et smalti d’ogni sorte havute in Murano 1536 [Recipes to make colored glasses and enamels of every kind as in Murano, 1536]. [3]

Local history points to the town of Claret just north of Montpellier as the seat of regional glassmaking. Beginning in 1290, the oak forests on the Causse de l'Orthus attracted glassmakers and their families. "So maybe the oaks got used for fuel. (A 'causse' is a geological term for a limestone plateau.) [also a material of glassmaking] At any rate, the glassmakers were ennobled by the King and formed a guild of premium glassmakers whose wares were sold all over Europe from the market at Sommières." [4]

In the early seventeenth century, Pierre-Jean Fabre (1588-1658) studied medicine at Montpellier where he discovered the works of Paracelsus, to which he became a devotee. [5] After securing a medical degree, he returned to the nearby town of his birth, Castelnaudary, to work as a doctor. Eventually, he was awarded the status of "Royal Physician" by Louis XIII, probably for his work on treating victims of the plague with chemical preparations. [6]

Fabre's first book, of a total canon numbering sixteen volumes, was on the subject of alchemy and medicine titled "Palladium spagyricum" 1624. [7] The book, written in Latin, contains advice on the transmutation of metals, turning water into "good wine" and elixirs to cure all disease. It contains one recipe that is of particular interest on the subject of glassmaking; a malleable form of glass, known in legend since the Roman Empire as Vitrum Flexile.

See my next post to take a closer look at Fabre's specific recipe for a glass that is malleable at room temperature and trace a bit of the legend's history.

[1] Wikipedia, “University of Montpellier” https://en.wikipedia.org/wiki/University_of_Montpellier.

[2] Mark Clarke: Mediaeval Painters' Materials and Techniques: The Montpellier Liber diversarum arcium (London: Archetype Publications, 2011).

[3] Montpellier 1536, MS. H. 486: Recette per fare vetri colorati et smalti d’ogni sorte havute in Murano 1536, Bibliothèque de l'Ecole de Médecine de Montpellier, see also Zecchin 1987, v.1 p 247-276. Although the manuscript is dated 1536 it is probably copied from much earlier Venetian sources.

 [4] Ed Ward, Blog: City on a Hill, 1 Nov. 2010 post “Where the Glass-Blowers Were.” http://wardinfrance.blogspot.com/2010/11/where-glass-blowers-were.html . Also see Halle du Verre regional glass museum website http://www.cc-grandpicsaintloup.fr/-Halle-du-verre-.html .

[5] Paracelsus (1493-1541) was a Swiss born physician and alchemist who looked to nature rather than ancient texts for remedies to disease. He was widely condemned durring his lifetime but became very popular after his manuscripts were printed in the late sixteenth century.

[6] The definitive reference on Fabre is Bernard Joly: La rationalité de l'alchimie au XVIIe siècle (France: Vrin, 1992), pp. 35-50. A good English treatment can be found in Allen George Debus: The French Paracelsians: The Chemical Challenge to Medical and Scientific Tradition in Early Modern France (Cambridge: Cambridge University Press, 2002) pp, 75, 76.

[7] Pierre-Jean Fabre: Palladium spagyricum Petri Ioannis Fabri doctoris medici Monspeliensis ... (Toulouse: Bosc, 1624), p. 276. Later translated into several English editions, notably by William Salmon: Polygraphice: Or the Arts of Drawing, Engraving, Etching, Limming, Painting … (London: T. Passenger & T. Sawbridge, 1685), pp. 598, 599.

Alchemist's Assistant

Spine of volume 3 of Della Casa's notebooks,

Biblioteca Nationale Centrale Firenze.

At the turn of the seventeenth century, when Priest Antonio Neri was employed in Florence by the Medici prince Don Antonio, he worked closely with another alchemist by the name of Agnolo della Casa. Casa chronicled Neri's work and after his colleague's death in 1614, he undertook a special mission for Don Antonio to interview Neri's other associates and uncover the priest's recipe for the philosopher's stone. Don Antonio went as far as consulting a medium in Venice to contact Neri in the afterlife, but that is a story for another time. 

Thousands of pages of notes relating to Antonio Neri's work in Florence were recorded by fellow alchemist Agnolo della Casa. A significant portion of this nineteen-volume manuscript is devoted to Neri's work on transmutation and specifically on the fabled philosopher's stone. The trouble is that he wrote much of it in obscure language, which renders it among the most cryptic in the entire canon of alchemy. Other sections of Della Casa's notebooks contain copies of the works of various adepts including Geber, Ramon Llull and Arnold Villanova. Neri took a keen interest in all of them.

In 1597, Prince Don Antonio de' Medici occupied the dormant Casino di San Marco and made it his new home. His father, the former grand duke, built this combination palace and laboratory on the north side of the city to indulge his own fascination with natural secrets. Don Antonio began to assemble a team that included Neri and Della Casa. The three men were all about the same age, in their early twenties, ready to do great things; ready to reveal nature and change the world.

In their time, it was reasonable to think that one metal could be 'purified' into another and that a single medicine could cure all disease or counteract any poison. These notions had been around since ancient times. In this realm, a skeptical eye was an absolute necessity, but there was no specific evidence that disproved the old stories. Don Antonio reportedly spent a fortune collecting recipes and testing them; he and his men worked to separate the real from the bogus. Swindlers and con men were in plentiful supply; they hawked miracle cures in public squares throughout Europe. Without a firm grasp of the underlying chemistry, the task of understanding a particular compound or chemical reaction could be quite difficult. Even to experienced, careful researchers, there was no guarantee that conclusions were correct.

Don Antonio was convinced that the glassmaking priest had indeed discovered the secret of transmutation. He put Della Casa to work interviewing Neri's acquaintances to see what could be learned. An expert gold refiner, Guido Antonio Milani, reported to Della Casa that in July 1596, Neri had performed before his eyes a transmutation of base metal into "twenty-four carat" gold. He said he pressed the 20-year-old, who in reluctance, confided that he had learned the secret from a German, who performed the gold transmutation with a "tablet of medicine." The German told Neri the medicine was nothing but the simple quintessence of green vitriol and the method to produce it was described by Paracelsus.

* This post first appeared here in a shorter form on 2 Sept 2013.

Artificial Gems

Pastes (glass) set in silver openwork (Portugal c. 1750)

Victoria and Albert Museum, London.

Acq. nr. M.68-1962

In many ways, the story of artificial gems traces the story of glass technology itself. From ancient times, when glass could only be produced in very small quantities it was regarded and used as a type of stone that was made through art. Alchemists thought the bright colors produced by metallic pigments in glass were a key to the philosopher's stone, and the transmutation of base metals into gold. As the technical prowess of glassmakers expanded, so did the ability to simulate specific stones, most notably coveted gems. Glass went on to be used as material for utilitarian objects like goblets and as an indispensable part of scientific enquiry. All the while, artificial gems have continued to dazzle us with their beauty. 

In the fifth part of Antonio Neri's 1612 book, he teaches the secrets of making artificial gems "of so much grace, and beauty, that they will surpass the natural stones in everything except hardness." It is not a difficult argument to make that this section alone is responsible for much of the lasting popularity of L'Arte Vetraria. It is easy to see why enterprising artisans would want to make glass imitations that could pass for the real thing. It is also perhaps tempting to jump to the conclusion that Neri intended his recipes to be used in deception, but there is no evidence whatsoever that this was the case.

Neri gives full credit for his innovative methods in paste gems to Dutch alchemist Isaac Hollandus. Hollandus is an enigmatic figure, whose writings survive, but not much is known of the man, his family, or even if he was living in Neri's time. What is known is that Antonio's dear friend Emmanuel Ximenes was the brother-in-law to Baron Simon Rodriguez d'Evora, a famous diamond dealer and jeweler of choice to royalty throughout Europe. He lived and worked on the same street in Antwerp as Ximenes' palace, only a few steps away from Neri's new temporary home. It was a common request of wealthy patrons to have duplicate jewelry made in paste for travel and security reasons. If a fake necklace or jewel could pass for the real thing, it was well worth the added expense, when the genuine article could remain safe under lock and key.

No artificial gem recipes have ever been found among Hollandus' writings, excepting one for ruby which is then crushed up as part of a prescription for the philosopher's stone. It is quite possible that Neri was applying a more general technique from the Dutchman. The basic material for all of Neri's paste gems is a fine lead crystal. The crux of his innovation lay in the form of lead used. Normally, metallic lead sheet was cut into small pieces, and roasted in a kiln such that it would oxidize into powder, but not melt. The powder was then added to the glass melt. In Neri's method the lead was chemically converted into a water-soluble form, which could then be filtered and purified to a much greater extent. The end result was a far better grade of crystal.

In 1697, Jean Haudicquer de Blancourt translated into French and greatly expanded Christopher Merrett's English edition of Neri. Blancourt gave no credit to the Italian for his work, and two years later, when it was translated back into English by Daniel Brown, the connection to Neri was completely lost, but the credit for paste gems remained with Hollandus. In the eighteenth and nineteenth centuries, numerous general encyclopedias of art and craft were published and the so-called 'Hollandus' paste gem recipes turned up many times. Meanwhile, a properly credited French version of L'Arte Vetraria was completed by Holbach in 1752. This edition was more suited to a scientific audience; he faithfully translated the Italian, but also incorporated the full comments of Merrett as well as those of Kunckel who issued his famous German version of Neri in 1679.

For more reading on Neri's artificial gems see Glass as Pasta and on the work of later investigators see Marieke Hendriksen at The Medicine Chest

Scraping the Barrel

4th century BCE philosopher Diogenes

(supposedly lived in a wine barrel)

by Gaetano Gandolfi (1792)

To seventeenth century glassmaker Antonio Neri, "tartar" was a well-known byproduct of the winemaking process. If we chill wine or grape juice to below 50 degrees (10 deg. C.) crystals of tartar start to form and once they do, then tend not to dissolve back, even at room temperatures. Today, these crystals are commonly found in a powdered form, in kitchen cupboards as "cream of tartar." Bakers and cooks use it to stabilize whipped egg whites, and it has a number of other applications. 

Neri used tartar in his glass to add sparkle, a trick known to Venetian glassmakers as early as the 1400s. It was obtained from the dregs at the bottom of wine barrels. To understand how this works, it is useful to know that Florentines, Venetians and most southern Europeans made glass from crushed up quartz pebbles or sand mixed with a specific flux known as "glass salt." This salt was rich in sodium carbonates, which greatly reduced the melting point of the quartz. It allowed artisans to work the material at the temperatures easily achieved in their furnaces. Tartar turns out to be very similar, except that it is rich in potassium rather than sodium. 

Potassium atoms are larger and heavier than sodium atoms and when light passes through a piece of potassium-fluxed glass, it bends and refracts more. This effect is not as pronounced as when adding the even heavier lead to form fine crystal, but it still adds noticeable sparkle to finished pieces. Using all tartar as a flux has the undesirable effect of reducing the workability of the hot glass. Outside the furnace, it becomes stiff quicker and artists have less time to create fancy shapes and forms. The solution to this dilemma is to use a mix of sodium and potassium fluxes together, which is exactly what Neri did. 

In his 1612 book L'Arte Vetraria, he shows how to prepare tartar and then adds it to a number of his glass recipes saying, "The tartar is the secret way to produce more salt and to make cristallo which is whiter and of rare beauty." Here is Neri’s prescription:

To make Purified Tartar Salt you should obtain tartar, which is also called gruma, from barrels of red wine in which it forms large lumps, however do not use powder. Roast it in earthenware pots amongst hot coals until it becomes calcined black and all its sliminess is roasted away. It then will begin to whiten, but do not let it become white, because if you do the salt will be no good.  

Calcine tartar this way: put it in large earthenware pans full of hot common water, or better yet in glazed earthenware pans then made to boil on a slow fire. You should do it in such a way that in two hours the level of the water will slowly decrease to one-quarter, at this point lift it from the fire and leave it to cool and to clarify. Now decant off the liquid, which will be strong lye and refill the pans containing the remains of the tartar with new common water. In the way stated above, boil as before and repeat the procedure until saltiness no longer charges the water. 

At this point, the [decanted] water is impregnated with all the salt. Filter the lye clear and put it in glass chamber pots to evaporate in the ash of the stove over a slow fire. In the bottom, white salt will remain. Dissolve this salt in new hot common water and leave it in the pans, letting it settle for two days. Then filter it and return it to chamber pots to evaporate over a slow fire. In the bottom, a much whiter salt will be left than the previous time. Now dissolve this salt in fresh hot common water and leave it to settle for two days. Evaporate, filter and repeat everything as before. Overall, repeat this procedure four times to dissolve, filter and evaporate the salt of tartar. This will make the salt whiter than snow and purified from the vast majority of its sediment.

When mixed with sifted polverino, or rocchetta, with its doses of tarso [quartz] or sand, this salt will make a frit that in crucibles will produce the most beautiful crystallino and common glass, which one cannot make without the accompaniment of tartar salt. Without it [tartar], good fine crystallino can be made, nevertheless with it, it will be the absolute most beautiful.

*This post first appeared here on 16 May 2014.