Sunday, May 14, 2017

Antonio Neri's Mother

Agnolo di Cosimo 'Bronzino',
"Portrait of Florentine Noblewoman"
(subject unknown , circa. 1540).
The mother of Antonio Neri, the 17th century glassmaker and alchemist,  was named Dianora Parenti. She was the oldest of six children: three girls and three boys. She was born in Florence, on 11 February 1552, with the given name of Dora listed in the city's baptistery register. In all probability by the age of eighteen she was quite accustomed to helping her mother with the other children; Caterina, the youngest, was born less than a year before Dianora's wedding.

Her father and grandfather were prominent lawyers; together they handled much of the personal business of famed artist Michelangelo. On the 20th day of August 1570, Francesco Parenti walked his eldest child down the aisle to be joined, in holy matrimony, to physician Neri Neri. Two years later, their first child Lessandra was born. 

Historians Luigi Zecchin and Enzo Settesoldi identified four of Antonio's brothers, two older and two younger. They were Jacopo (1573), Francesco (1575), a second Jacopo (1577) and Vincenzio (1579). In addition to these five boys, there were at least two more brothers born later, Emilio (1583) and Alessandro (1587). And there were at least three girls, the first-born child Lessandra (1572) and two younger sisters: Maria (1581) and Lucretia (1584). 

In all, there were ten births by Dianora recorded in Florence, occurring almost like clockwork on a fifteen-month schedule. As did many women of the period, she spent a significant portion of her adult life pregnant. In her case, it was a span of sixteen years, carrying one child after another with minimal interruption.

The birth of a child in Renaissance Florence was no small occasion. Patrician families went to considerable expense on decorations, on food and drink for guests and on gifts for the mother and godparents. "The woman who gave birth, like a bride at her wedding, occupied for a passing moment a position of unparalleled honor,"* more than that, while a wedding signaled the transition from daughter to wife, the birth celebration was a rare social recognition of a woman as an individual.

A genealogical record of the eighteenth century, held at the State Archives in Florence (ASF), confirms most of the Neri children's births. It also sets the date of death for their mother Dianora at 1594 when she would have been forty-two years old. This means Antonio lost his mother when he was eighteen and his youngest brother Alessandro was a mere seven.

* Margaret L. King, Women of the Renaissance (Chicago: University of Chicago Press, 1991), p. 4.

This post first appeared on 11 September 2013.

Friday, May 12, 2017

Dear Friends

The library of the University of Leiden (1610)
Christophe Plantin worked here from 1583 to 1585.
One day in July of 1601, in Florence, early in the morning, we imagine two men shaking hands, embracing and saying goodbye. Both knew it might well be the last time they saw each other. The older man climbs into a coach bound for his home in distant Antwerp and signals the driver to begin his journey. That man, Emmanuel Ximenes, had been in Florence to visit his sister, Beatrice, his brother, Niccolò, and several other relatives living in the area. Antonio Neri first met the wealthy banker at the home of Beatrice and her husband, Alamanno Bartolini. The priest lived there after his ordination and, according to nineteenth century historian Francesco Inghirami, functioned as house-master. Both men wished for more time together; they shared a fascination with alchemy and with the work of Swiss-born physician Paracelsus. They had become fast friends and formed a bond that would last until the end of their lives.

As soon as Ximenes arrived home in Flanders he wrote to Neri, on 17 August, 1601, "to the quite magnificent clergyman Mr.Antonio Neri, in the house of Mr. Alamanno Bartolini, in Florence, or where found." He expressed his great pleasure at receiving a booklet of recipes from Neri and declares him "molto caro" [most dear]. He goes on to warn his friend: "With your permission, I will not fail to bother you with my tiresome letters." Over the next two years, the men corresponded frequently. A set of twenty-seven letters written by Ximenes and one by his brother Eduardo, addressed to Neri, survive in the National Library of Florence. The two men discuss a wide variety of subjects including herbal remedies, glassmaking, enameling and in more careful language, the topic for which they were both most passionate: alchemy. They trade information on the results of their experiments and by 5 December, 1602, the banker wrote:

I have seen the tender affection which Your Lordship shows me and demonstrates with the hope to see me before death, which is no different from my own hope. I have desired this from the start… because if we were together, we could easily set to work on some small projects, being that our talents, if I am not deceiving myself, are very well suited...
Neri would ultimately make the journey to Antwerp, but not for another year. That winter he became quite ill in Pisa, postponing his planned visit. Finally, on 2 May, his friend wrote: "Praise God that your indisposition has ended." By the following spring the two men were reunited and Neri would spend the next seven years in a city that was in the eye of a storm. The low-countries (what today are the Netherlands and Belgium) were in the midst of a bloody civil war. The port of Antwerp was blockaded by the Dutch fleet and the countryside was being ravaged by troops from Spain and the Holy Roman Empire. The population of Antwerp was a shadow of its former self, but the city was left untouched by both sides, in an accord of political convenience. It had been burned and pillaged as recently as the 1570's, but by the early 1600's Antwerp was simply too valuable a jewel to be sacrificed.

Emmanuel's immediate family was among the wealthiest in Antwerp and strong patrons of the arts. He counted among his close friends humanist printers Christophe Plantin and Jan Moretus. Other branches of the Ximenes family topped the social ranks in Venice, Hamburg, Lisbon and Florence. Their ancient ancestors were kings of Pamplona, Navarre, Castile and Aragon. Emmanuel's father Rodrigo headed the prestigious Ximenes (Jiménez) Bank in Antwerp. By the end of his visit, Neri would present the prince of Orange with vessels of his chalcedony glass.


This post was first published here, on 6 September 2013.
For more on Ximenes, see http://ximenez.unibe.ch/

Wednesday, May 10, 2017

Casino di San Marco

The Casino di San Marco, Florence
Location of Antonio Neri's first glassmaking job
In 1612, Antonio Neri wrote the first book entirely devoted to making glass from raw materials. It was called L’Arte Vetraria, or in English, 'The Art of Glassmaking'. When Neri put pen to paper for his book, he had already been making glass for over a decade. He had the opportunity to learn his craft from some of the experts in the field. At the beginning, his first known experience in glassmaking was at the laboratory palace of Don Antonio de’ Medici, a prince from the ruling family of Tuscany. 

The Palace was called the Casino di San Marco. “Casino”, we might innocently guess indicated some kind of gambling hall, which it was not.  Instead, "Casino" was Italian parlance for a palace that was informally organized like a small country house with the living quarters on the ground floor. It was built by Don Antonio’s father, the former Grand Duke, as a place where Nature’s secrets would be discovered and new inventions would be made. Neri worked at the Casino for a couple of years before moving to Pisa and then to Antwerp, all the while making glass. He returned to Florence to publish his book, and thanked Don Antonio for his long patronage. 

Don Antonio's Casino was as much a grand concept as it was a physical space. Completed to his father’s specifications in 1574, it evolved into a prince's palace par excellence. Within its walls, grand dinners were held, productions were staged and poetry was read. In 1605 Michelangelo Buonarroti the younger staged a play there titled "The Christmas of Hercules." In its chambers, music was performed, philosophy debated and diplomacy conducted. In its laboratories, alchemy was nurtured, and glass was formulated. It was a sort of grand royal conservatory, melding together art, letters, drama, music and science. From its courtyard, hunters set forth into the Tuscan hills in search of unicorns, and within its workshops, artisans explored the territory of new materials and natural secrets.

The Royal Foundry, as it was also called, became a place of pride for Grand Duke Ferdinando. It was a place that visiting dignitaries specifically asked to see and tour. Behind the doors of the Casino di San Marco, Antonio Neri and his associates worked their magic. This is probably where he first learned the secrets of Venetian style glass composition and undoubtedly much more. He assisted the prince in his research, formulated herbal remedies and helped in the production of luxury gifts for visiting dignitaries.


This was the way that I made chalcedony in the year 1601, in Florence at the Casino, in the glass furnace there. At that time, the task of scheduling furnace-work fell to the outstanding Mr. Niccolò Landi, my close friend and a man of rare talent in enamel work at the oil lamp. I made many pots of chalcedony in the furnace there. I never deviated from the method stated above, I always prepared the materials well and it always came out beautifully in all my proofs.[1] 

[1] L'Arte VetrariaAntonio Neri 1612, p. 41.
* This post first appeared here in a shorter form on 12 August 2012.

Monday, May 8, 2017

Artificial Gems

Pastes (glass) set in silver openwork (Portugal c. 1750)
Victoria and Albert Museum, London.
Acq. nr. M.68-1962
In many ways, the story of artificial gems traces the story of glass technology itself. From ancient times, when glass could only be produced in very small quantities it was regarded and used as a type of stone that was made through art. Alchemists thought the bright colors produced by metallic pigments in glass were a key to the philosopher's stone, and the transmutation of base metals into gold. As the technical prowess of glassmakers expanded, so did the ability to simulate specific stones, most notably coveted gems. Glass went on to be used as material for utilitarian objects like goblets and as an indispensable part of scientific enquiry. All the while, artificial gems have continued to dazzle us with their beauty. 

In the fifth part of Antonio Neri's 1612 book, he teaches the secrets of making artificial gems "of so much grace, and beauty, that they will surpass the natural stones in everything except hardness." It is not a difficult argument to make that this section alone is responsible for much of the lasting popularity of L'Arte Vetraria. It is easy to see why enterprising artisans would want to make glass imitations that could pass for the real thing. It is also perhaps too tempting to jump to the conclusion that Neri intended his recipes to be used in deception, since there is no evidence whatsoever that this was the case.

Neri gives full credit for his innovative methods in paste gems to Dutch alchemist Isaac Hollandus. Hollandus is an enigmatic figure, whose writings survive, but not much is known of the man, his family, or even if he was living in Neri's time. What is known is that Antonio's dear friend Emmanuel Ximenes was the brother-in-law to Baron Simon Rodriguez d'Evora, a famous diamond dealer and jeweler of choice to royalty throughout Europe. He lived and worked on the same street in Antwerp as Ximenes' palace, only a few steps away from Neri's new temporary home. It was a common request of wealthy patrons to have duplicate jewelry made in paste for travel and security reasons. If a fake necklace or jewel could pass for the real thing, it was well worth the added expense, when the genuine article could remain safe under lock and key.

No artificial gem recipes have ever been found among Hollandus' writings, excepting one for ruby which is then crushed up as part of a prescription for the philosopher's stone. It is quite possible that Neri was applying a more general technique from the Dutchman. The basic material for all of Neri's paste gems is a fine lead crystal. The crux of his innovation lay in the form of lead used. Normally, metallic lead sheet was cut into small pieces, and roasted in a kiln such that it would oxidize into powder, but not melt. The powder was then added to the glass melt. In Neri's method the lead was chemically converted into a water-soluble form, which could then be filtered and purified to a much greater extent. The end result was a far better grade of crystal.


In 1697, Jean Haudicquer de Blancourt translated into French and greatly expanded Christopher Merrett's English edition of Neri. Blancourt gave no credit to the Italian for his work, and two years later, when it was translated back into English by Daniel Brown, the connection to Neri was completely lost, but the credit for paste gems remained with Hollandus. In the eighteenth and nineteenth centuries, numerous general encyclopedias of art and craft were published and the so-called 'Hollandus' paste gem recipes turned up many times. Meanwhile, a properly credited French version of L'Arte Vetraria was completed by Holbach in 1752. This edition was more suited to a scientific audience; he faithfully translated the Italian, but also incorporated the full comments of Merrett as well as those of Kunckel who issued his famous German version of Neri in 1679.

For more reading on Neri's artificial gems see Glass as Pasta and on the work of later investigators see Marieke Hendriksen at The Medicine Chest
*A shorter version of this post appeared here on 16 September 2003.

Friday, May 5, 2017

Scraping the Barrel

4th century BCE philosopher Diogenes
(supposedly lived in a wine barrel)
by Gaetano Gandolfi (1792)
To seventeenth century glassmaker Antonio Neri, "tartar" was a well-known byproduct of the winemaking process. If we chill wine or grape juice to below 50 degrees (10 deg. C.) crystals of tartar start to form and once they do, then tend not to dissolve back, even at room temperatures. Today, these crystals are commonly found in a powdered form, in kitchen cupboards as "cream of tartar." Bakers and cooks use it to stabilize whipped egg whites, and it has a number of other applications. 

Neri used it in his glass to add sparkle, a trick known to Venetian glassmakers as early as the 1400s. It was obtained from the dregs at the bottom of wine barrels. To understand how this works, it is useful to know that Florentines, Venetians and most southern Europeans made glass from crushed up quartz pebbles or sand mixed with a specific flux known as "glass salt." This salt was rich in sodium carbonates, which greatly reduced the melting point of the quartz. It allowed artisans to work the material at the temperatures easily achieved in their furnaces. Tartar turns out to be very similar, except that it is rich in potassium rather than sodium. 

Potassium atoms are bigger and heavier than sodium atoms and when light passes through a piece of potassium-fluxed glass, it bends and refracts more. This effect is not as pronounced as when adding the even heavier lead to form fine crystal, but it still adds noticeable sparkle to finished pieces. Using all tartar as a flux has the undesirable effect of reducing the workability of the hot glass. Outside the furnace, it becomes stiff quicker and artists have less time to create fancy shapes and forms. The solution to this dilemma is to use a mix of sodium and potassium fluxes together, which is exactly what Neri did. 

In his 1612 book L'Arte Vetraria, he shows how to prepare tartar and then adds it to a number of his glass recipes saying, "The tartar is the secret way to produce more salt and to make cristallo which is whiter and of rare beauty." Here is Neri’s prescription:


To make Purified Tartar Salt you should obtain tartar, which is also called gruma, from barrels of red wine in which it forms large lumps, however do not use powder. Roast it in earthenware pots amongst hot coals until it becomes calcined black and all its sliminess is roasted away. It then will begin to whiten, but do not let it become white, because if you do the salt will be no good.  
Calcine tartar this way: put it in large earthenware pans full of hot common water, or better yet in glazed earthenware pans then made to boil on a slow fire. You should do it in such a way that in two hours the level of the water will slowly decrease to one-quarter, at this point lift it from the fire and leave it to cool and to clarify. Now decant off the liquid, which will be strong lye and refill the pans containing the remains of the tartar with new common water. In the way stated above, boil as before and repeat the procedure until saltiness no longer charges the water. 
At this point, the [decanted] water is impregnated with all the salt. Filter the lye clear and put it in glass chamber pots to evaporate in the ash of the stove over a slow fire. In the bottom, white salt will remain. Dissolve this salt in new hot common water and leave it in the pans, letting it settle for two days. Then filter it and return it to chamber pots to evaporate over a slow fire. In the bottom, a much whiter salt will be left than the previous time. Now dissolve this salt in fresh hot common water and leave it to settle for two days. Evaporate, filter and repeat everything as before. Overall, repeat this procedure four times to dissolve, filter and evaporate the salt of tartar. This will make the salt whiter than snow and purified from the vast majority of its sediment.
When mixed with sifted polverino, or rocchetta, with its doses of tarso [quartz] or sand, this salt will make a frit that in crucibles will produce the most beautiful crystallino and common glass, which one cannot make without the accompaniment of tartar salt. Without it [tartar], good fine crystallino can be made, nevertheless with it, it will be the absolute most beautiful.

*This post first appeared here on 16 May 2014.

Wednesday, May 3, 2017

Pebbles from Pavia

A Bridge on the River Ticino, near Polleggio,
William Pars (1742‑1782).
In the sixteenth and seventeenth century, a type of glass known as 'cristallo' was the absolute pinnacle of the art. Its recipe was invented in Venice and guarded there as a state secret. Its name derived from the mineral it was designed to mimic: rock crystal. As clear as water, rock crystal was valued since ancient times for carving into cups, vessels and other objects of art. Today we know it as a form of quartz, but in Roman times it was thought to be a type of frozen or coagulated water.

In the early 1600s, when Antonio Neri started making glass in Florence, the grand duke's craftsmen were routinely carving this hard and brittle rock crystal into complex thin shapes, a process that took great skill and effort. Due to the expense involved in producing a piece, this art was the exclusive province of extremely wealthy individuals. Thus, objects made from rock crystal were considered markers of status. The recipe for cristallo was a very great secret indeed, but its real value lay in the specific materials used. Even if the recipe found its way out of Murano, which it inevitably did, the Venetian's tight trade network ensured a monopoly on many of the ingredients. It is said that even the furnace crucibles for cristallo were made from a specific clay gathered in Constantinople.

Cristallo was not only exceptionally clear, but for the artist it had working properties like no other glass. Thin, complex shapes were possible in cristallo that could never be duplicated in common glass. The secret for making cristallo came to Florence in the late 1560's, only a few years before the birth of Antonio Neri, who would learn the techniques and go on to publish the recipe for the first time anywhere.

 After protracted overtures, which involved diplomats, spies and the archbishop of Florence, Grand Duke Cosimo I managed to negotiate with the Venetian Doge and Senate for a Muranese master and two assistants to come to Florence and teach the way to make cristallo. It is likely that the raw materials were all purchased through the Venetians, at least initially. By the time Neri wrote his book, L'Arte Vetraria, in 1612, the Florentines were already finding alternate sources. In Venice, the ingredients of cristallo were prescribed and controlled by strict laws. The Florentines did not have this constraint and were free to experiment.

In the second recipe of Neri's book, he spills the beans on where the Venetians procured the single most important ingredient for cristallo, the pure quartz stones which account for the material's clarity. Notice in the following excerpt that Neri mistakenly thinks that the white river stones are a form of marble and also notice the alchemical language he uses to describe the process in which the stone is "transmuted" into glass.
When you want to a make cristallo that is beautiful and fully perfect, see that you have the very whitest tarso. At Murano they use pebbles from Ticino [Pavia], a stone abundant in the Ticino River. Tarso, then is a species of very white hard marble [quartz]. 
In Tuscany, it is found at the foot of Mount Veruca in Pisa, at Seravezza, at Massa near Carrara, and in the Arno River both above and below Florence. In other places as well, common stone is often recognized, which is seen to have the same qualities as tarso; it is very white and does not have dark veins, or the yellowish appearance of rust, but is spotless and pure. Take note that any stones that will spark with a piece of steel or strike plate, are apt to vitrify and will make glass and cristallo. All those stones that do not make sparks with a piece of steel or striker as above will never vitrify. This serves as advice for being able to distinguish stones that have the ability to transmute their form, from those that cannot be transmuted. 
Start with this same tarso, as fair and as white as possible. Grind it finely into powder in stone mortars. Do not use bronze or any other metal for this purpose or the stone will take in the color of the metal, which then would tinge the glass or cristallo, and make it imperfect. The pestle must be iron by necessity but at least the other materials will not have the possibility of causing any effect. Pulverize the tarso well and sift with a fine sieve. It is important that the tarso is ground as finely as flour, so that it will all pass through a fine sieve.
* This post first appeared here on 30 May 2014. 

Monday, May 1, 2017

Glass From Tinsel

From Diderot's Encyclopedia, machinery to hammer brass into thin sheets
Which were then used as decorative tinsel, in glassmaking and more 
(click image to enlarge).
To this day in the field of glassmaking, color is still a subject about which manufacturers hold their cards very close to the breast. It is very unusual to coax anyone in this trade to speak freely about exactly what materials are used to produce a specific color and for good reason – competitive advantage. In this respect, attitudes have not changed very much from the early seventeenth century when Antonio Neri blew the doors open with his 1612 book of glass recipes. L'Arte Vetraria, discussed, for the first time in print, a whole rainbow of different shades in terms of specific materials and amounts. 

Since then, a number of his formulations have become obsolete or fallen into disuse. This has happened for various reasons, typically because the raw ingredients he used fell out of favor. Many are not easily obtainable or reproducible today. Since the state of industrial chemistry is far ahead of where it was in his time, the basic metal oxides are now simply ordered from a catalog and mixed to produce the maker's specific color palate their customers expect. The result is that many of the shades of color Neri produced have not graced the end of a gaffer's blowpipe for centuries; they certainly could be duplicated today, but there is simply no call to do so.

One of the interesting raw ingredients that he used four hundred years ago is tinsel. Yes, this is the ancient relative of what we still use for holiday decoration. Neri advises, "Take orpiment, also known as tinsel and to save money purchase some that has already been used for decorative wreaths and garland." Tremolante is the specific word he uses; it has the same root as the English "tremulous" and "tremble." In modern Italian, it means to flicker or shimmer. The groundbreaking early dictionary first published by the Florentine Accademia della Crusca in the seventeenth century gives Neri credit for the first use of the term in this context, but if it was a common product, the word must certainly have been in use earlier. To confuse matters, Neri describes tinsel as a kind of "orpiment." (orpello) This term was also used to refer to arsenic sulfide, a highly toxic mineral used as a golden paint pigment, but in this recipe he uses the word only to refer to the golden color of tinsel.  

Neri's tinsel was made of brass, which is an alloy of copper and zinc. While zinc had been isolated as a pure metal, notably by Paracelsus, Neri knew it only by its oxide which he called zelamina. He cut the tinsel into tiny pieces with a scissors and then 'calcined' it, heating it in a covered crucible among live coals for four days. He was careful not to let it reach a temperature that will melt the metal. He removes it from the fire, grinds it into a black powder, then reheats it for another four days. By the end of Neri’s process both the metals would be oxidized. This product, he tells us, makes a blue color in glass reminiscent of the feathers of the "gazzera marina" bird, "holding the middle between aquamarine and the color of the sky when it is very clear and serene" There are several possibilities for the identity of the gazzera marina, the most likely seems to be the European Roller (Coracias garrulus). It is a species that is known for its striking appearance in flight; its brilliant blue breast contrasts against black flight feathers. 

In a second brass recipe (# 21), the snippings are mixed with powdered sulfur and heated in the live coals of the furnace firebox for a day. He then grinds it as before and reheats it for a protracted period of ten days in the hottest part of the furnace "near the eye." Neri advises that the product can be used for transparent red, yellow and in chalcedony glass. He uses calcined tinsel in two of his chalcedony recipes but we never see a further mention in the book for transparent red or yellow glass. In the first part of this recipe, the sulfur likely reacts with the zinc-copper alloy in the tinsel to form sulfides of the metals. In the second part, the sulfides are decomposed by the high heat to form oxides and most or all of the sulfur is driven off as noxious sulfur dioxide gas. This method could well produce better oxidation of the metals and therefore a better quality colorant. If the sulfides do not completely decompose, some interesting possibilities arise in the melt. Copper sulfides have the potential to be reduced to pure metal in a reheating maneuver done by the glass artist called 'striking.' This might produce the wonderful transparent red known as copper ruby glass. Zinc sulfides in glass, produces a white or opaline glass. The only way to know for sure what the old recipes would do is to make a batch and put it in the hands of an artist.

* This post first appeared here 23 May 2014.