Alberico Barbini

The island of Murano , circa 1600

attributed to Danckerts

In the early seventeenth century, Antonio Neri began preparing batches of glass for artisans of the royal family in Florence, Italy. This was a specialist vocation undertaken by alchemists, which by schooling, Neri was. His job as “conciatore” involved procuring the ingredients, preparing, mixing and melting them and working with the glass artisans, adjusting the consistency and colors for the work being done. It was a position that carried great prestige, and Neri’s book on glassmaking [1] would cement his name in history. 

Shortly before Neri was born, in 1576, the grand duke of Tuscany, Cosimo I de’ Medici, brokered a special deal with the doge of Venice to have master glass artisans come to Florence and teach their secrets. These men were from the island of Murano; the most famous center of glassmaking anywhere. There is only scant evidence that Neri himself traveled to Venice and perhaps only once, but there is no doubt that he benefited greatly from the knowledge of Muranese workers in Florence, Pisa and Antwerp during his lifetime. 

Over the intervening centuries, the title of the glass batcher changed, but the tradition and prestige of glass formulation continued well into the middle of the twentieth century. In fact, even today, among the small glass manufacturers that compose the studio glass movement, the glass batcher is considered to be something of a modern alchemist; keeper of the arcane knowledge of  the chemicals and amounts necessary to produce special colors and adjust properties of the glass.

Now, fast forward four centuries from Neri's Italy; in the early 1920s, a Milanese lawyer named Paolo Venini partnered with a Venetian-born antique dealer friend, Giacomo Cappellin, to start a new glass factory on Murano. [2] Even as recently as this, the glass batcher still held a respected position both within the factory and the community. Through several incarnations over the next half century Venini grew a world-wide reputation for innovative designs, of which color played an important part. They are specifically associated with the fazzoletto (handkerchief) style vase and the incalmo technique of fusing two or more colors of glass seamlessly in a single furnace-blown piece. 

In 1925, Cappellin split from Venini and took many of the craftsmen with him, in 1933 the new business was acquired by Pauly & C. Again, chemical knowledge and the artistry of reproducing ancient colors made a worldwide reputation. [3] As ownerships changed hands like cards in a game of poker, artisans shuffled between factories. It is easy to lose track of the individual glassworker. Even for a period so recent, many records exist only in the heads of the family members still living on the island. 

In 1956 the Stazione Sperimentale del Vetro (Experimental Station for Glass) was started on Murano with the mandate to preserve and promote the technical aspects of Italy’s glassmaking heritage. [4] The new institution was regarded by some traditionalists with great suspicion, but as we will see, others embraced the resource.

I recently sat down with renowned glass artist Emilio Santini, who today carries on a six-centuries-old family tradition in glasswork. [5] Emilio had recently called home, to Murano, which led to his father’s recollection of an uncle, who worked making color for Venini and Pauly. Here Emilio recounts the conversation:

Alberico Barbini was the uncle of my father, Mario Santini and the man in charge of making the glass batch “partie” (Venetian) “partite” (Italian). He was the brother of my grandmother, Delfina Barbini. He was not the only one [in my family] who worked for Venini in the early days but the most respected. At Venini he worked formulating glass after another great batch maker, [Albino] Carrara. 

In the early to mid [twentieth] century the batch maker still held an important position in the factory, not like now, you know, and he kept his formulations quite secret, although this relative of mine, Alberico, was smart enough to use the most modern technology available at that time. 

He was different from other batch makers in that when the Stazione Sperimentale del Vetro opened, he made extensive use of it in reproducing colors. At that time, and even now to an extent, the institution was not seen as good for traditional Murano glassmaking. 

He later moved on to Pauly where he was in charge of reproducing the glass colors that were in use in the seventeenth, eighteenth and nineteenth centuries. First, he assisted in remaking broken or missing pieces in private collections, then later in making reproduction antique stemware at Pauly that was impossible to distinguish from the originals. 

You must realize that all this does not come from documents but from the memory, still very sharp and lucid, of my father.

[1] L’Arte Vetraria, (Neri 1612).
[2] Paolo Venini http://en.wikipedia.org/wiki/Paolo_Venini also see https://www.facebook.com/pages/Venini/198475426829887
[3] Pauly & C. Compagnia Venezia Murano http://en.wikipedia.org/wiki/Pauly_%26_C._%E2%80%93_Compagnia_Venezia_Murano
[4] Stazione Sperimentale del Vetro  http://www.spevetro.it/indexENG.htm
[5] Emilio Santini http://www.cmog.org/bio/emilio-santini
* This post first appeared here on 25 Feb 2015.

Incalmo

Incalmo vessels by Tapio Wirkkala for Venini.

In this post, we will explore one of the classical techniques of glass art. Along with filigrana, latticino, reticello and pezzato, incalmo is a classical Venetian technique well established in the art, even if poorly understood by many outsiders. 

‘Incalmo’, in Venetian dialect literally means “graft” as in joining two plants. That is a pretty good description of how this effect is achieved; think of a vase whose bottom-half is one color and top is another. The glass artist blows two separate bubbles of glass, opens them and joins them together to form a single bubble. It is a difficult operation because the two open lips must be exactly the same size to join properly. The process can be continued to add more colors; virtuoso pieces may include several sections, each a different color. In addition, the position of the iron rod that the artist uses to hold the bubble can be changed while the piece is under construction, leading to asymmetrical effects.

16th century incalmo plate,
unknown artist.

The above description is the classical way of achieving incalmo, but modern materials and equipment allow artists to achieve a similar effect with considerably less skill. For instance, precise diameter glass tubing is now available in a wide variety of colors. This can be cut into rings with a saw, then stacked in a kiln and fused together. From there, this “prefabricated incalmo tube can be worked by traditional methods. Whether or not this meets the definition of true incalmo depends entirely on whether one focuses on the method or on the end result.

9-10th century incalmo vase,
Syria or Iraq.

The name ‘incalmo’, was applied to glass in the first half of the twentieth century by the Venini factory on Murano, in Venice. [1] However, both the word and the method are much older. The Venini artisans revived the technique to great acclaim, but Venetian examples date from the sixteenth century and Islamic examples from ninth century Syria have also survived. It is not hard to imagine that this joining technique was experimented with shortly after glassblowing became common around the first century BCE. However, what is truly amazing is that any of these early examples survived to be sold to customers without breaking in the cooling process. The reason for this is a technical issue that we have not discussed yet.

All glass expands a little when it is heated and shrinks when it cools. Different formulations of glass generally expand by differing amounts. When a single piece incorporates more than one type of glass, and the thermal expansions differ significantly, the result is disaster. After the piece is finished it is placed in a kiln where it slowly cools back to room temperature. Because of the mismatch, one area wants to shrink more than the adjacent area and the glass cracks along the join. The expansion and contraction is microscopic, but it is enough to ruin hours and hours of work, leading to much gnashing of teeth the morning after, when the finished work is inspected. 

The Venini glass masters had the benefit of this knowledge, but for earlier artisans, trial and error must have played a big role in determining which formulas were compatible. Different colors mean different metallic additives and to match expansion other ingredients would need to be adjusted. Today, manufacturers produce glass in a series based on expansion; artists can be relatively sure that two different colors from the same series can be “grafted” and not self-destruct when cooled.

[1] I have not absolutely confirmed this, but authoritative secondary references credit Venini, and I can find no mention to "incalmo" as a glass technique prior to the twentieth century.

Iron Into Copper

The recovery of copper from vitriolated waters,

from De Re Metallica, 1556, by Agricola (Georg Bauer).

In Discorso, one of the last manuscripts written by Antonio Neri before his death, he reveals several transmutation recipes. One describes turning iron into copper; it is instructive because it uses common materials that we can identify and because the chemistry is now well understood.

Take some iron sheets and lay them in vitriol water, being immersed in that, they will rust. Scrape off this rust, which will be a red powder, melt it in a crucible, and you will have perfect copper. The same effect can be had from various waters that are naturally vitriolated, because they flow through mines of vitriol, such as those of a source some distance from Leiden, and another below the fortress of Smolnik, [now in Slovakia].

Vitriol is an acidic sulfate dissolved in water, it could be made in the laboratory, but it also occurred naturally around mining operations where sulfurous minerals were present. Alchemists knew this solution as "oil of vitriol" and "spirit of vitriol." The mine that Neri references in Smolnik became famous for transmutation. As late as the eighteenth century, scientists and experimenters from around Europe made the pilgrimage to see the effect for themselves and tried to figure out what was happening. It may be a surprise to some readers, but following the above instructions will, in fact, produce copper just as Neri claimed. There is no deception or sleight of hand involved; the explanation is straightforward, but first, Neri treats us to a rare glimpse of his own reasoning on the subject:

Some estimate and not without reason, that this experiment, being used to prove the transmutation of metals, is not suitable for this purpose. They say that the vitriolated waters become such because they are already heavy with the corrosive spirits of sulfur, having passed through the copper or iron mine, these waters corrode copper in the same way aqua fortis corrodes silver. So that really the substance of the copper remains in the water, which attacks the surface of the iron, which always remains iron. However, if that were true then the iron would not get consumed, or if it were consumed it would mix with the substance of the corroded copper in the water, and if it were fused, it would remain a mixture of iron and copper. And yet in this experiment, all the iron is consumed; it is reduced by the vitriolated water into powder, […] which in the fusion is still pure copper, so there should remain no doubt that this is a true transmutation.[1]

Given the state of chemistry at the time, Neri's reasoning is clear and rational. The iron disappears and a copper coating materializes in its place. What better evidence of transmutation could one ask for?

The key to what was actually happening is in the criticism leveled by skeptics. It turns out that they were on the right track, but neither they nor Neri had the full picture. Today, we understand it as a simple ion exchange reaction; blue vitriol water is a transparent saturated solution of copper sulfate (CuSO₄), in the presence of solid iron, the liquid dissolves the iron; copper from the vitriol is deposited in its place. The two metals, copper and iron, change places: the iron dissolves, forming green vitriol (FeSO₄) and copper is expelled from the solution. The result is a reduction in the amount of the iron, which is replaced by a proportional deposit of pure copper.

On a physical level, this chemical reaction is no different today than it was in the seventeenth century. What has changed is our interpretation of the experiment. What Neri viewed as a transformation of iron into copper, we now see as an exchange. There is, however, a deeper lesson in all this. As an alchemist, Antonio Neri was not being delusional or dishonest; he was careful, observant and applied his knowledge as best he could. This is no different from the way science works today. Both then and now, to be successful in unraveling nature’s secrets, one must become accustomed to a very uncomfortable situation: In the past, careful reasoning by brilliant thinkers has led to utterly wrong conclusions. The fact that much of our world is a mystery is unsettling; that the very process we use to understand it can be so flawed is harder to accept. Even more difficult is that the faculty we all rely on for survival—our own wits—can lead us so far astray.[2]

[1] For more, see Discorso sopra la Chimica: The Paracelsian Philosophy of Antonio Neri”, M.G. Grazzini / Nuncius 27 (2012).
[2] This post first appeared here on 31 January 2014.

The Golden Sun

The Sun, Robert Fludd

from Utriusque Cosmi (1617),v. 2, p. 19.

Today, Antonio Neri is best known for his 1612 book, L'Arte Vetraria, in which he exposes the secrets of the art of making glass. In publishing his volume, he helped to fuel new discoveries in chemistry and medicine simply by making glass apparatus more available to experimenters. A 1662 translation of his book into English was one of the first acts undertaken by the newly formed Royal Society in London, at the behest of Robert Boyle. Neri himself lived for only two years after his book went to press, in his native Florence, and never saw the seeds of his labor come to fruition. If he had lived, he might well be surprised that his legacy is in glassmaking, and not in the subjects that he himself held most dear.

In his death at the age of thirty-eight, Neri missed a rapid advancement in our basic understanding of nature. In the space of only a few decades the face of science and medicine would start to change irrevocably. Soon, experimenters were finding new chemical elements and began to map out the periodic table, often with apparatus made of glass. For centuries, the ancient Aristotelian concept of air, earth, water and fire as the basic building blocks of the universe had endured. By the end of the seventeenth century, the inadequacies of the old model were becoming clear. 

But Neri was not privy to any of this. In his time, any cracks in the Aristotelian model were minor. Like his sponsor, Medici prince Don Antonio, Neri was an adherent of new doctrines of the physician Paracelsus, who rebelled against the old system, but was still very much a product of it. First and foremost, Neri thought of himself as an alchemist. While history has not generally been kind to his ilk, a true understanding of early modern science rests on the methods and reasoning developed by alchemists like Neri. 

Although alchemy covered a wide range of activities, it will forever be associated most closely with the mistaken notion that base metals such as lead or iron could be transmuted into gold. Once science had established this idea as specious, the race was on to separate "new science" from the old. It became fashionable to cast alchemists into the mold of charlatans, tricksters and self-deceived fools. While many such characters did exist, Neri was not one of them; his work was based on careful reasoning and experimentation. The final irony is that through the kind of advancements that he himself helped to pioneer, the majority of his life's work has fallen by the wayside. What has endured the test of modern science is his treatise on glassmaking.

As early as the age of twenty, Neri was demonstrating transmutation to expert gold refiners. As late as the year before his death he was writing authoritatively and coherently on the subject. To understand how this is possible – to be rational and methodical, and at the same time completely wrong – is to get a sense of the true difficulties involved in science. Based on what he was taught, what he read, and his own experimentation, Neri thought metals and other materials "matured" over time. He thought that more "imperfect" metals like lead and iron were part of a continuum that ended with the "perfect" metal gold. Furthermore, he thought that primordial "seeds of gold" left over from the creation of the earth could be mined and isolated. Like wheat and other plants, given the correct nurturing, and conditions, this seed material could be encouraged to mature into vast quantities of gold. Writing in his 1613 manuscript Discorso, he says,

The response is that the chemical art lets the gold proceed from that present and immediate cause, because this is the seed of gold, which acts naturally when art cooperates. The chemist does nothing but extract the seed from gold and apply it to suitable bodies, with which it is united to render the fruit multiplied in the same way that the farmer does. He does not produce the fruit, but provides and prepares the earth and the seed, uniting them in such a way so that they bear fruit.*

Neri thought that ultimately, for gold transmutation to be successful one needed the blessing of the Creator. He documented his process in a heavily coded (and incomprehensible) recipe he called "Donum Dei" (the most precious gift of God). This name traces to alchemical writings from as early as the fifteenth century. He maintained that those who might harm society with this knowledge or wished to profit personally or swindle others would be denied the blessing and therefore be unsuccessful. 

The remarkable thing here is that Neri's understanding of chemistry was supported at every turn by experimentation. His recorded methods, for transforming lesser metals into one-another, were repeatable and stood the test of scrutiny by contemporary experts. In the light of modern chemistry, these transformations depended on subtle physical processes and chemical reactions that would not be understood for another century or more. By performing these experiments under controlled conditions, he was taking the first steps in what would become modern science. Eventually, it would be understood that while chemical compounds can be created and destroyed by various manipulations, individual elements cannot. Today we know that iron, lead and gold were formed in the cores of ancient stars, not too different from our sun. Lighter elements are successively transformed into heavier ones under a star's "nurturing" conditions. While he lived in a period in which he had no chance of getting the particular details correct, in a poetic sense Neri was not far from the truth.

* See Maria Grazia Grazzini, “Discorso sopra la Chimica: The Paracelsian Philosophy of Antonio Neri” Nuncius 27 (2012) 311–367.

What Goes Around Comes Around

The German city of Ulm in the 16th century
Georg Braun, Franz Hogenberg 1570-78
(Click either image to enlarge.)

In the spring and summer of 1525, peasants and farmers throughout German speaking Europe staged a popular revolt now called the Deutscher Bauernkrieg. [1] At the heart of the matter was an oppressive system of taxation run by the Roman Catholic Church, in which little or none of the revenue was used to improve life locally. Often, action was lead by Protestant clergy, but to little effect against the mercenary armies hired by the aristocracy. In the end, up to 100,000 of the poorly armed and organized peasants were slaughtered.

Along the banks of the Danube River in southern Germany lies the ancient city of Ulm. Besides being the birthplace of Albert Einstein, Ulm was, in the sixteenth century, near the center of the Peasant’s Revolt, which brings us to a curious story which traces the migration of a technical recipe from Ulm over the alps to Venice, then to Sienna and finally Florence. The recipe is for the metal alloy to make mirrors, and it is told from one friend to another while chatting amiably in Venice.

Among other things, he said that he had made one [concave mirror] almost half a braccio across [about 13 inches], which extended the clear rays of its brightness more than a quarter of a German league when he caught the sun with it. One day, when for amusement he was standing in a window to watch a review of armed men in the city of Ulm, he bore with the sphere of his mirror for a quarter of an hour on the back of the shoulder armor of one of those soldiers. This not only caused so much heat that it became almost unbearable to the soldier, but it inflamed so that it kindled his jacket  underneath and burned it for him, cooking his flesh to his very great torment. Since he did not understand who caused this, he said that God had miraculously sent that fire on him for his great sins. [2]

The story was told to Vannoccio Biringuccio, who recalls it in 1540 in his Pirotechnia, the first printed book devoted to metallurgy. Specifically, the recipe is a variant of what today we would call white bronze, which as Biringuccio states is similar to the metal used to cast bells. He recites ancient formulations that used three parts copper and one part tin. To this was added 1/18th part of antimony and optionally 1/24th part of fine silver to give it a neutral color. Indeed, other ancient formulations for what was known as speculum metal specify a 3:1 ratio of copper to tin. He continues,

But nowadays most of the masters who make them take three parts of tin and one of copper, and melt these together. When they are melted, for every pound of this material, they throw in one ounce of tartar and half an ounce of powdered arsenic, and let them fume and melt and incorporate well. 

Biringuccio’s version reverses the copper and tin ratio from the classical composition. Compare it with Antonio Neri’s prescription which appears half a century later, it is almost identical:

Have 3 lbs of well-purified tin, and 1 lb of copper also purified. Melt these two metals, first the copper, then the tin. When they fuse thoroughly, throw onto them 6 oz of just singed red wine tartar, and 1½ oz of saltpeter, then ¼ oz of alum, and 2 oz of arsenic. Leave these all to vaporize, and then cast [the metal] into the form of a sphere. You will have good material, which when you burnish and polish, will look most fine. This mixture is called acciaio and is used to make spherical mirrors.

To be clear, the tartar, saltpeter and alum act as a surface flux - they form a layer that floats on the liquid metal, preventing oxides from forming, which can foul the melt.  their addition does not change the base alloy composition.

The similarity of the two recipes alone is not enough to draw any conclusions. Biringuccio himself reports that the contemporary artisans favored the tin rich formulation. However, there are other details to consider. The Sienese born Biringuccio was something of a hero in Florence where Antonio Neri was raised. The famous metallurgist helped cast cannons, mortars and guns for the Florentines to defend themselves in the late 1520s, when the city was under siege, just a few years after Biringuccio’s conversation in Venice with his German Friend from Ulm.

Neri was definitely familiar with Biringuccio’s book Pirotechnia. In fact, the introduction to Neri’s own book L’Arte Vetraria is patterned after the metallurgist’s survey of glassmaking.  In his chapter 14, book 2 Biringuccio wrote:

… it [glass] is one of the effects and real fruits of the art of fire, because every product found in the interior of the earth is either stone, metal, or one of the semi-minerals.  Glass is seen to resemble all of them, although in all respects it depends on art. [3]

And here is the opening to Neri’s introduction a half century later in 1612,

Without a doubt, glass is a true fruit of the art of fire, as it can so closely resemble all kinds of rocks and minerals, yet it is a compound, and made by art. [4]

Both passages go on to cover much of the same ground, albeit with a change in focus reflective of new thinking about chemistry and nature. In one sense, Neri is paying homage to his distinguished predecessor, and there can be little doubt that he read Biringuccio’s book and its technical recipes closely. 

In the years leading to the publication of Neri’s book, he left his home in Florence and traveled to visit a friend in Antwerp. If he had read the book on metallurgy early, perhaps as part of his education, then he was already familiar with the mirror alloy recipe. If he followed the route suggested by his friend, he would have taken the recipe back to Venice, and then over the Alps and likely through Ulm on his way north to the Low Countries, where he would spend the next seven years before returning to Italy. [5]

[1] For more on the German peasant wars of 1524-25 see https://en.wikipedia.org/wiki/German_Peasants%27_War
[2] Vannoccio Biringuccio, Pirotechnia. Ed., Tr. Cyril Stanley Smith, Martha Teach Gnudi (New York: Basic Books, 1959), pp. 385-390. (Original Italian published in 1540.)
[4] Ibid,  p.126 (in original, ff.41r-44v).
[3] Antonio Neri, L’Arte Vetraria (Florence: Giunti, 1612). p. iv.
[5] Special thanks to Jamie Hall (@PrimitiveMethod) for inspiring this post.

CONCIATORE Book Excerpt

CONCIATORE, The Life and Times of 17th
Century Glassmaker Antonio Neri, By Paul Engle

From the Introduction:

"Under the cover of Antonio Neri's glassmaking book, L'Arte Vetraria, lays an alchemist's treasure. Centuries-old pages invite us to share in his secrets and plumb the glassmaker's art. Unfamiliar methods and ingredients discussed in his book at first may puzzle the modern reader, but soon the pieces fall into place. A careful ear will hear echoes of ancient technique, whispers that speak to the very essence of craftsmanship. A clear eye will see the hands of a master artisan manipulating raw ingredients into new materials. To read his most famous treatise is to join Antonio Neri's odyssey with nature and walk his path of discovery. Through his work, he offers a clear window into not only the world of Renaissance glassmaking but also into the upper echelons of society and into the deepest mysteries of alchemy. We can even catch a glimpse into the birth of modern science. 

A look into his personal life reveals a man who was born into the comfortable home of a royal physician. His family's circle included famous lawyers, wealthy merchants, archbishops, Vatican officials and perhaps a future saint. In his alchemical pursuits, Neri did not lead a solitary life; he sought out collaborations with others. He made friends among his technical coworkers, but also with princes and powerful international bankers. He cultivated recipes of herbal remedies and worked to cure disease among the infirmed. He came to serve a royal prince in a premier laboratory of its time, yet he worried about the social implications of his specialized knowledge.
In the pages of his book, Neri, an ordained Catholic priest, invites us into the secretive world of Renaissance glass formulation. He shows us cristallo, the coveted Venetian glass famously crafted by artisans in the style called façon de Venise. [1] This fabled creation, invented and perfected on the island of Murano, was the toast of European royalty for its finery, a tool of experimenters for its utility and the marvel of commoners for practical items like spectacles. For the first time in print anywhere, Neri revealed to the world the materials and recipes for cristallo and many other rare glasses. He detailed the secrets of color in glass from the delicate blush of peach blossom lattimo to the intense saturation of cobalt blue.

Like a fine artist, Neri conducted his craft with a deep regard for process. He tried variations and permutations of recipes that would result in the final product he was after. He took risks with expensive ingredients and he applied his experience to new areas. He helped to shine a spotlight on Tuscan glass and bring it to the attention of greater Europe. He devoted his mind to the creation of dazzling colors and his hands to the perfection of refined ingredients. 

Just as a great painter relies on the quality of pigments at hand, so must a master glass artisan depend upon the materials of the melt. For the glassblowers and furnace workers who shaped hot glass, a superior batch was crucial to superior results. A great piece of glasswork owes its form to the talent of the artist, but its substance is the province of the craftsmen who make the glass. This pairing put artistry at both sides of the furnace and made virtuoso glass world-renowned. In the early 1600s, Antonio Neri specialized in the glassmaking end of that partnership in Florence at the celebrated Medici court. This alchemist priest supplied a prince's royal artisans with the finest glass that money could buy. The quality of his work showed through the consistency and texture of his melts and through the clarity and brilliance of his colors. 

As his work spoke to the state of Florentine glass technology, it spoke as well to the state of artisanal craft (fig.1). [2] In Neri's hands, a technical recipe is akin to a composition of poetry. Each ingredient is cleaned, weighed and combined. Conditions are set, containers sealed, the fire lit and a secret of nature is revealed. Neri found his métier not in the creation of finished pieces, nor in the construction of furnaces or the forging of tools. Rather, his passion lay in the concoction of formulas, the roasting and purification of chemicals. He challenged Nature at her own game of creation. The recipes he perfected offer a chance to explore the work of a master Renaissance artisan at a time when art and science were indistinguishable. They illustrate craft practiced with all five senses.

[1] For examples, see Page, Doménech 2004.
[2] Ilardi 1993.

Like Snow From Heaven

28th December 2005 in Florence
Photo by Marco De La Pierre

In its simplest incarnation, glass is nothing more than crushed quartz or sand mixed with 'glass salt'. This salt is the alkali carbonates of sodium or potassium. Essentially, the ash of certain plants that reduces to oxide in the furnace and dramatically lowers the melting point of the sand.

In Pliny's ancient account of the discovery of glass, the process takes place in a single step. The ingredients came together accidentally in a fire and "glass trickled out." The problem is that pure quartz does not react with the salt until it gets very hot and even then, it does so reluctantly. In a wood-fired furnace, quartz stones, even small pebbles or sand would melt with excruciating slowness. As Neri advises, "... this would only succeed after a protracted period of time and a great amount of trouble." 

'Fritting' is an intermediate step that speeds the process considerably. Glassmakers reduce the quartz to a fine powder and then mix it with the alkali salt. In the heat of a kiln, the entire content of each stone is thus exposed to the salt right from the beginning. This roasting process starts a chemical reaction between the ingredients. In the late Renaissance, the combination was then cooled and 'aged' for several months before use. When made from pure quartz river stones and the best Levantine ash, the result was what Neri calls 'bollito,' "white and pure like snow from heaven."

A third ingredient of glass, critical to its long-term stability is lime, or calcium oxide. Without the lime, glass is susceptible to attack by water. The water actually dissolves the glass, or less dramatically makes it subject to 'glass disease' or 'crizzling', a condition where the glass slowly decomposes due to humidity in the air. Waterglass is a product made without the lime. On Murano and elsewhere, it was dissolved in water and painted onto the shells of eggs to seal and preserve them. In Neri's era, lime was produced by roasting seashells. It was a key ingredient of cement, and as such was readily available. It had been a major commodity throughout the Mediterranean since the Roman Empire. Neri advises to add lime to all his glass recipes, but it is not so clear that he himself understood why it was so important.

*This post first appeared here on 11 October 2013.